Dicobalt copper bis[orthophosphate(V)] monohydrate, Co2.39Cu0.61(PO4)2·H2O
Identifieur interne : 000164 ( Ncbi/Curation ); précédent : 000163; suivant : 000165Dicobalt copper bis[orthophosphate(V)] monohydrate, Co2.39Cu0.61(PO4)2·H2O
Auteurs : Abderrazzak Assani [Maroc] ; Mohamed Saadi [Maroc] ; Lahcen El Ammari [Maroc]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2010.
Abstract
In an attempt to hydrothermally synthesize a phase with composition Co2Cu(PO4)2·H2O, we obtained the title compound, Co2.39Cu0.61(PO4)2·H2O instead. Chemical analysis confirmed the presence of copper in the crystal. The crystal structure of the title compound can be described as a three- dimensional network constructed from the stacking of two types of layers extending parallel to (010). These layers are made up from more or less deformed polyhedra: CoO6 octahedra, (Cu/Co)O5 square pyramids and PO4 tetrahedra. The first layer is formed by pairs of edge-sharing (Cu/Co)O5 square pyramids linked
Url:
DOI: 10.1107/S1600536810015382
PubMed: 21578990
PubMed Central: 2979060
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PMC:2979060Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Dicobalt copper bis[orthophosphate(V)] monohydrate, Co<sub>2.39</sub>
Cu<sub>0.61</sub>
(PO<sub>4</sub>
)<sub>2</sub>
·H<sub>2</sub>
O</title>
<author><name sortKey="Assani, Abderrazzak" sort="Assani, Abderrazzak" uniqKey="Assani A" first="Abderrazzak" last="Assani">Abderrazzak Assani</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country>
</nlm:aff>
<country xml:lang="fr">Maroc</country>
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<author><name sortKey="Saadi, Mohamed" sort="Saadi, Mohamed" uniqKey="Saadi M" first="Mohamed" last="Saadi">Mohamed Saadi</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country>
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<country xml:lang="fr">Maroc</country>
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</affiliation>
</author>
<author><name sortKey="El Ammari, Lahcen" sort="El Ammari, Lahcen" uniqKey="El Ammari L" first="Lahcen" last="El Ammari">Lahcen El Ammari</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Dicobalt copper bis[orthophosphate(V)] monohydrate, Co<sub>2.39</sub>
Cu<sub>0.61</sub>
(PO<sub>4</sub>
)<sub>2</sub>
·H<sub>2</sub>
O</title>
<author><name sortKey="Assani, Abderrazzak" sort="Assani, Abderrazzak" uniqKey="Assani A" first="Abderrazzak" last="Assani">Abderrazzak Assani</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country>
</nlm:aff>
<country xml:lang="fr">Maroc</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Saadi, Mohamed" sort="Saadi, Mohamed" uniqKey="Saadi M" first="Mohamed" last="Saadi">Mohamed Saadi</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country>
</nlm:aff>
<country xml:lang="fr">Maroc</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="El Ammari, Lahcen" sort="El Ammari, Lahcen" uniqKey="El Ammari L" first="Lahcen" last="El Ammari">Lahcen El Ammari</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V-Agdal, Avenue Ibn Battouta, BP 1014, Rabat,<country>Morocco</country>
</nlm:aff>
<country xml:lang="fr">Maroc</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
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<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2010">2010</date>
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<front><div type="abstract" xml:lang="en"><p>In an attempt to hydrothermally synthesize a phase with composition Co<sub>2</sub>
Cu(PO<sub>4</sub>
)<sub>2</sub>
·H<sub>2</sub>
O, we obtained the title compound, Co<sub>2.39</sub>
Cu<sub>0.61</sub>
(PO<sub>4</sub>
)<sub>2</sub>
·H<sub>2</sub>
O instead. Chemical analysis confirmed the presence of copper in the crystal. The crystal structure of the title compound can be described as a three- dimensional network constructed from the stacking of two types of layers extending parallel to (010). These layers are made up from more or less deformed polyhedra: CoO<sub>6</sub>
octahedra, (Cu/Co)O<sub>5</sub>
square pyramids and PO<sub>4</sub>
tetrahedra. The first layer is formed by pairs of edge-sharing (Cu/Co)O<sub>5</sub>
square pyramids linked <italic>via</italic>
a common edge of each end of the (Cu/Co)<sub>2</sub>
O<sub>8</sub>
dimer to PO<sub>4</sub>
tetrahedra. The second layer is undulating and is built up from edge-sharing CoO<sub>6</sub>
octahedra. The linkage between the two layers is accomplished by PO<sub>4</sub>
tetrahedra. The presence of water molecules in the CoO<sub>4</sub>
(H<sub>2</sub>
O)<sub>2</sub>
octahedron also contributes to the cohesion of the layers through O—H⋯O hydrogen bonding.</p>
</div>
</front>
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