Re-building Daniell Cell with a Li-ion exchange Film
Identifieur interne : 000130 ( Main/Merge ); précédent : 000129; suivant : 000131Re-building Daniell Cell with a Li-ion exchange Film
Auteurs : Xiaoli Dong [République populaire de Chine] ; Yonggang Wang [République populaire de Chine] ; Yongyao Xia [République populaire de Chine]Source :
- Scientific Reports [ 2045-2322 ] ; 2014.
Abstract
Daniell cell (i.e. Zn-Cu battery) is widely used in chemistry curricula to illustrate how batteries work, although it has been supplanted in the late 19th century by more modern battery designs because of Cu2+-crossover-induced self-discharge and un-rechargeable characteristic. Herein, it is re-built by using a ceramic Li-ion exchange film to separate Cu and Zn electrodes for preventing Cu2+-crossover between two electrodes. The re-built Zn-Cu battery can be cycled for 150 times without capacity attenuation and self-discharge, and displays a theoretical energy density of 68.3 Wh kg−1. It is more important that both electrodes of the battery are renewable, reusable, low toxicity and environmentally friendly. Owing to these advantages mentioned above, the re-built Daniell cell can be considered as a promising and green stationary power source for large-scale energy storage.
Url:
DOI: 10.1038/srep06916
PubMed: 25369833
PubMed Central: 4220274
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<author><name sortKey="Dong, Xiaoli" sort="Dong, Xiaoli" uniqKey="Dong X" first="Xiaoli" last="Dong">Xiaoli Dong</name>
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, Shanghai 200433,<country>China</country>
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<country xml:lang="fr">République populaire de Chine</country>
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<author><name sortKey="Wang, Yonggang" sort="Wang, Yonggang" uniqKey="Wang Y" first="Yonggang" last="Wang">Yonggang Wang</name>
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, Shanghai 200433,<country>China</country>
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<country xml:lang="fr">République populaire de Chine</country>
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<author><name sortKey="Xia, Yongyao" sort="Xia, Yongyao" uniqKey="Xia Y" first="Yongyao" last="Xia">Yongyao Xia</name>
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<author><name sortKey="Wang, Yonggang" sort="Wang, Yonggang" uniqKey="Wang Y" first="Yonggang" last="Wang">Yonggang Wang</name>
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<front><div type="abstract" xml:lang="en"><p>Daniell cell (i.e. Zn-Cu battery) is widely used in chemistry curricula to illustrate how batteries work, although it has been supplanted in the late 19th century by more modern battery designs because of Cu<sup>2+</sup>
-crossover-induced self-discharge and un-rechargeable characteristic. Herein, it is re-built by using a ceramic Li-ion exchange film to separate Cu and Zn electrodes for preventing Cu<sup>2+</sup>
-crossover between two electrodes. The re-built Zn-Cu battery can be cycled for 150 times without capacity attenuation and self-discharge, and displays a theoretical energy density of 68.3 Wh kg<sup>−1</sup>
. It is more important that both electrodes of the battery are renewable, reusable, low toxicity and environmentally friendly. Owing to these advantages mentioned above, the re-built Daniell cell can be considered as a promising and green stationary power source for large-scale energy storage.</p>
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