Re-building Daniell Cell with a Li-ion exchange Film
Identifieur interne : 000119 ( Pmc/Checkpoint ); précédent : 000118; suivant : 000120Re-building Daniell Cell with a Li-ion exchange Film
Auteurs : Xiaoli Dong [République populaire de Chine] ; Yonggang Wang [République populaire de Chine] ; Yongyao Xia [République populaire de Chine]Source :
- Scientific Reports [ 2045-2322 ] ; 2014.
Abstract
Daniell cell (i.e. Zn-Cu battery) is widely used in chemistry curricula to illustrate how batteries work, although it has been supplanted in the late 19th century by more modern battery designs because of Cu2+-crossover-induced self-discharge and un-rechargeable characteristic. Herein, it is re-built by using a ceramic Li-ion exchange film to separate Cu and Zn electrodes for preventing Cu2+-crossover between two electrodes. The re-built Zn-Cu battery can be cycled for 150 times without capacity attenuation and self-discharge, and displays a theoretical energy density of 68.3 Wh kg−1. It is more important that both electrodes of the battery are renewable, reusable, low toxicity and environmentally friendly. Owing to these advantages mentioned above, the re-built Daniell cell can be considered as a promising and green stationary power source for large-scale energy storage.
Url:
DOI: 10.1038/srep06916
PubMed: 25369833
PubMed Central: 4220274
Affiliations:
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Re-building Daniell Cell with a Li-ion exchange Film</title><author><name sortKey="Dong, Xiaoli" sort="Dong, Xiaoli" uniqKey="Dong X" first="Xiaoli" last="Dong">Xiaoli Dong</name><affiliation wicri:level="1"><nlm:aff id="a1"><institution>Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University</institution>, Shanghai 200433,<country>China</country></nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Wang, Yonggang" sort="Wang, Yonggang" uniqKey="Wang Y" first="Yonggang" last="Wang">Yonggang Wang</name><affiliation wicri:level="1"><nlm:aff id="a1"><institution>Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University</institution>, Shanghai 200433,<country>China</country></nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Xia, Yongyao" sort="Xia, Yongyao" uniqKey="Xia Y" first="Yongyao" last="Xia">Yongyao Xia</name><affiliation wicri:level="1"><nlm:aff id="a1"><institution>Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University</institution>, Shanghai 200433,<country>China</country></nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">25369833</idno><idno type="pmc">4220274</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4220274</idno><idno type="RBID">PMC:4220274</idno><idno type="doi">10.1038/srep06916</idno><date when="2014">2014</date><idno type="wicri:Area/Pmc/Corpus">000001</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000001</idno><idno type="wicri:Area/Pmc/Curation">000001</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000001</idno><idno type="wicri:Area/Pmc/Checkpoint">000119</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">000119</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Re-building Daniell Cell with a Li-ion exchange Film</title><author><name sortKey="Dong, Xiaoli" sort="Dong, Xiaoli" uniqKey="Dong X" first="Xiaoli" last="Dong">Xiaoli Dong</name><affiliation wicri:level="1"><nlm:aff id="a1"><institution>Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University</institution>, Shanghai 200433,<country>China</country></nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Wang, Yonggang" sort="Wang, Yonggang" uniqKey="Wang Y" first="Yonggang" last="Wang">Yonggang Wang</name><affiliation wicri:level="1"><nlm:aff id="a1"><institution>Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University</institution>, Shanghai 200433,<country>China</country></nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Xia, Yongyao" sort="Xia, Yongyao" uniqKey="Xia Y" first="Yongyao" last="Xia">Yongyao Xia</name><affiliation wicri:level="1"><nlm:aff id="a1"><institution>Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University</institution>, Shanghai 200433,<country>China</country></nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Scientific Reports</title><idno type="eISSN">2045-2322</idno><imprint><date when="2014">2014</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>Daniell cell (i.e. Zn-Cu battery) is widely used in chemistry curricula to illustrate how batteries work, although it has been supplanted in the late 19th century by more modern battery designs because of Cu<sup>2+</sup>-crossover-induced self-discharge and un-rechargeable characteristic. Herein, it is re-built by using a ceramic Li-ion exchange film to separate Cu and Zn electrodes for preventing Cu<sup>2+</sup>-crossover between two electrodes. The re-built Zn-Cu battery can be cycled for 150 times without capacity attenuation and self-discharge, and displays a theoretical energy density of 68.3 Wh kg<sup>−1</sup>. It is more important that both electrodes of the battery are renewable, reusable, low toxicity and environmentally friendly. Owing to these advantages mentioned above, the re-built Daniell cell can be considered as a promising and green stationary power source for large-scale energy storage.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct><analytic><author><name sortKey="Boulabiar, A" uniqKey="Boulabiar A">A. Boulabiar</name></author><author><name sortKey="Bouraoui, K" uniqKey="Bouraoui K">K. Bouraoui</name></author><author><name sortKey="Chastrette, M" uniqKey="Chastrette M">M. Chastrette</name></author><author><name sortKey="Abderrabba, M" uniqKey="Abderrabba M">M. Abderrabba</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Martins, G F" uniqKey="Martins G">G. F. Martins</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Armand, M" uniqKey="Armand M">M. Armand</name></author><author><name sortKey="Tarascon, J M" uniqKey="Tarascon J">J. M. Tarascon</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Bruce, P G" uniqKey="Bruce P">P. G. Bruce</name></author><author><name sortKey="Scrosati, B" uniqKey="Scrosati B">B. Scrosati</name></author><author><name sortKey="Tarascon, J M" uniqKey="Tarascon J">J. M. Tarascon</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Luo, J Y" uniqKey="Luo J">J. Y. Luo</name></author><author><name sortKey="Cui, W J" uniqKey="Cui W">W. J. Cui</name></author><author><name sortKey="He, P" uniqKey="He P">P. He</name></author><author><name sortKey="Xia, Y Y" uniqKey="Xia Y">Y. Y. Xia</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Wang, Y G" uniqKey="Wang Y">Y. G. Wang</name></author><author><name sortKey="Yi, J" uniqKey="Yi J">J. Yi</name></author><author><name sortKey="Xia, Y Y" uniqKey="Xia Y">Y. Y. Xia</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Li, L J" uniqKey="Li L">L. J. Li</name></author><author><name sortKey="Zhao, X S" uniqKey="Zhao X">X. S. Zhao</name></author><author><name sortKey="Manthiram, A" uniqKey="Manthiram A">A. Manthiram</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Li, L J" uniqKey="Li L">L. J. Li</name></author><author><name sortKey="Zhao, X S" uniqKey="Zhao X">X. S. Zhao</name></author><author><name sortKey="Fu, Y Z" uniqKey="Fu Y">Y. Z. Fu</name></author><author><name sortKey="Manthiram, A" uniqKey="Manthiram A">A. Manthiram</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Lu, Y H" uniqKey="Lu Y">Y. H. Lu</name></author><author><name sortKey="Goodenough, J B" uniqKey="Goodenough J">J. B. Goodenough</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Lu, Y H" uniqKey="Lu Y">Y. H. Lu</name></author><author><name sortKey="Goodenough, J B" uniqKey="Goodenough J">J. B. Goodenough</name></author><author><name sortKey="Kim, Y" uniqKey="Kim Y">Y. Kim</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Zhang, T" uniqKey="Zhang T">T. Zhang</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Zhang, T" uniqKey="Zhang T">T. Zhang</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Zhao, Y" uniqKey="Zhao Y">Y. Zhao</name></author><author><name sortKey="Wang, L N" uniqKey="Wang L">L. N. Wang</name></author><author><name sortKey="Byon, H R" uniqKey="Byon H">H. R. Byon</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Zhao, Y" uniqKey="Zhao Y">Y. Zhao</name></author><author><name sortKey="Byon, H R" uniqKey="Byon H">H. R. Byon</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Zhao, Y" uniqKey="Zhao Y">Y. Zhao</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Zhou, H S" uniqKey="Zhou H">H. S. Zhou</name></author><author><name sortKey="Wang, Y G" uniqKey="Wang Y">Y. G. Wang</name></author><author><name sortKey="Li, H Q" uniqKey="Li H">H. Q. Li</name></author><author><name sortKey="He, P" uniqKey="He P">P. He</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="He, P" uniqKey="He P">P. He</name></author><author><name sortKey="Wang, Y G" uniqKey="Wang Y">Y. G. Wang</name></author><author><name sortKey="Zhou, H S" uniqKey="Zhou H">H. S. Zhou</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Wang, Y G" uniqKey="Wang Y">Y. G. Wang</name></author><author><name sortKey="Zhou, H S" uniqKey="Zhou H">H. S. Zhou</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Wang, Y G" uniqKey="Wang Y">Y. G. Wang</name></author><author><name sortKey="Zhou, H S" uniqKey="Zhou H">H. S. Zhou</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Wang, Y G" uniqKey="Wang Y">Y. G. Wang</name></author><author><name sortKey="Zhou, H S" uniqKey="Zhou H">H. S. Zhou</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Wang, Y G" uniqKey="Wang Y">Y. G. Wang</name></author><author><name sortKey="He, P" uniqKey="He P">P. He</name></author><author><name sortKey="Zhou, H S" uniqKey="Zhou H">H. S. Zhou</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Wang, Y R" uniqKey="Wang Y">Y. R. Wang</name></author><author><name sortKey="He, P" uniqKey="He P">P. He</name></author><author><name sortKey="Zhou, H S" uniqKey="Zhou H">H. S. Zhou</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Lim, H D" uniqKey="Lim H">H. D. Lim</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Dunn, B" uniqKey="Dunn B">B. Dunn</name></author><author><name sortKey="Kamath, H" uniqKey="Kamath H">H. Kamath</name></author><author><name sortKey="Tarascon, J M" uniqKey="Tarascon J">J. M. Tarascon</name></author></analytic></biblStruct></listBibl></div1></back></TEI><pmc article-type="research-article"><pmc-dir>properties open_access</pmc-dir>
<front><journal-meta><journal-id journal-id-type="nlm-ta">Sci Rep</journal-id><journal-id journal-id-type="iso-abbrev">Sci Rep</journal-id><journal-title-group><journal-title>Scientific Reports</journal-title></journal-title-group><issn pub-type="epub">2045-2322</issn><publisher><publisher-name>Nature Publishing Group</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="pmid">25369833</article-id><article-id pub-id-type="pmc">4220274</article-id><article-id pub-id-type="pii">srep06916</article-id><article-id pub-id-type="doi">10.1038/srep06916</article-id><article-categories><subj-group subj-group-type="heading"><subject>Article</subject></subj-group></article-categories><title-group><article-title>Re-building Daniell Cell with a Li-ion exchange Film</article-title></title-group><contrib-group><contrib contrib-type="author"><name><surname>Dong</surname><given-names>Xiaoli</given-names></name><xref ref-type="aff" rid="a1">1</xref></contrib><contrib contrib-type="author"><name><surname>Wang</surname><given-names>Yonggang</given-names></name><xref ref-type="corresp" rid="c1">a</xref><xref ref-type="aff" rid="a1">1</xref></contrib><contrib contrib-type="author"><name><surname>Xia</surname><given-names>Yongyao</given-names></name><xref ref-type="aff" rid="a1">1</xref></contrib><aff id="a1"><label>1</label><institution>Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University</institution>, Shanghai 200433,<country>China</country></aff></contrib-group><author-notes><corresp id="c1"><label>a</label><email>ygwang@fudan.edu.cn</email></corresp></author-notes><pub-date pub-type="epub"><day>05</day><month>11</month><year>2014</year></pub-date><pub-date pub-type="collection"><year>2014</year></pub-date><volume>4</volume><elocation-id>6916</elocation-id><history><date date-type="received"><day>06</day><month>09</month><year>2014</year></date><date date-type="accepted"><day>15</day><month>10</month><year>2014</year></date></history><permissions><copyright-statement>Copyright © 2014, Macmillan Publishers Limited. All rights reserved</copyright-statement><copyright-year>2014</copyright-year><copyright-holder>Macmillan Publishers Limited. All rights reserved</copyright-holder><license license-type="open-access" xlink:href="http://creativecommons.org/licenses/by-nc-sa/4.0/"><pmc-comment>author-paid</pmc-comment>
<license-p>This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License. The images or other third party material in this article are included in the article's Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder in order to reproduce the material. To view a copy of this license, visit <ext-link ext-link-type="uri" xlink:href="http://creativecommons.org/licenses/by-nc-sa/4.0/">http://creativecommons.org/licenses/by-nc-sa/4.0/</ext-link></license-p></license></permissions><abstract><p>Daniell cell (i.e. Zn-Cu battery) is widely used in chemistry curricula to illustrate how batteries work, although it has been supplanted in the late 19th century by more modern battery designs because of Cu<sup>2+</sup>-crossover-induced self-discharge and un-rechargeable characteristic. Herein, it is re-built by using a ceramic Li-ion exchange film to separate Cu and Zn electrodes for preventing Cu<sup>2+</sup>-crossover between two electrodes. The re-built Zn-Cu battery can be cycled for 150 times without capacity attenuation and self-discharge, and displays a theoretical energy density of 68.3 Wh kg<sup>−1</sup>. It is more important that both electrodes of the battery are renewable, reusable, low toxicity and environmentally friendly. Owing to these advantages mentioned above, the re-built Daniell cell can be considered as a promising and green stationary power source for large-scale energy storage.</p></abstract></article-meta></front><floats-group><fig id="f1"><label>Figure 1</label><caption><title>Schematic illustration and operating mechanism of rechargeable Zn-Cu battery with a Li-ion exchange membrane.</title></caption><graphic xlink:href="srep06916-f1"></graphic></fig><fig id="f2"><label>Figure 2</label><caption><title>Cyclic profile of the rechargeable Zn-Cu battery.</title><p>(a) Cell voltage vs. time. (b) Cell voltage vs. capacity. [In this investigation, a battery is charged for 6 hours to reach a charge capacity of 1.5 mAh, and then the battery is discharged to 0.2 V with an applied current of 0.25 mA.]</p></caption><graphic xlink:href="srep06916-f2"></graphic></fig><fig id="f3"><label>Figure 3</label><caption><title>Self-discharge investigation of the rechargeable Zn-Cu battery.</title><p>(a) OCV and discharge curves. (b) Enlargement of discharge curve after OCV test. (c) Discharge curve without OCV storage.</p></caption><graphic xlink:href="srep06916-f3"></graphic></fig><fig id="f4"><label>Figure 4</label><caption><title>Discharge curves of Zn-Cu batteries at different currents.</title><p>(a) Discharge curves of LATSP-based Zn-Cu battery. (b) Discharge curves of Nafion-based Zn-Cu battery. (c) Schematic illustrating the combination application between LATSP-based Zn-Cu battery and Nafion-based Zn-Cu battery.</p></caption><graphic xlink:href="srep06916-f4"></graphic></fig><fig id="f5"><label>Figure 5</label><caption><title>Rate performance (discharge voltage vs. current) of Nafion-based Zn-Cu battery investigated with 1 M Cu(NO<sub>3</sub>)<sub>2</sub> solution.</title><p>The inset is the discharge voltage vs. current of LATSP-based Zn-Cu battery tested at the same condition.</p></caption><graphic xlink:href="srep06916-f5"></graphic></fig></floats-group></pmc><affiliations><list><country><li>République populaire de Chine</li></country></list><tree><country name="République populaire de Chine"><noRegion><name sortKey="Dong, Xiaoli" sort="Dong, Xiaoli" uniqKey="Dong X" first="Xiaoli" last="Dong">Xiaoli Dong</name></noRegion><name sortKey="Wang, Yonggang" sort="Wang, Yonggang" uniqKey="Wang Y" first="Yonggang" last="Wang">Yonggang Wang</name><name sortKey="Xia, Yongyao" sort="Xia, Yongyao" uniqKey="Xia Y" first="Yongyao" last="Xia">Yongyao Xia</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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