Serveur d'exploration sur le cobalt au Maghreb

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β-Dicobalt pyrophosphate

Identifieur interne : 000359 ( PascalFrancis/Checkpoint ); précédent : 000358; suivant : 000360

β-Dicobalt pyrophosphate

Auteurs : A. El Belghitti [Maroc] ; A. Boukhari [Maroc]

Source :

RBID : Pascal:94-0443191

Descripteurs français

English descriptors

Abstract

A new high-temperature or β form of dicobalt diphosphate, Co2P2O7, has been isolated in space group A2/m (non-standard setting of C2/m). As in other high-temperature forms of transition-metal pyrophosphates, metal atoms lie on planes in a two-dimensional hexagonal array [Co-Co distances 3.461 (4) and 3.284 (3) Å] with adjacent metal atoms linked by two O-atom bridges. Co atoms are octahedrally coordinated with final distortions [average Co-Oeq 2.14 (1), Co-Oax 2.32 (1) Å]


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Pascal:94-0443191

Le document en format XML

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<div type="abstract" xml:lang="en">A new high-temperature or β form of dicobalt diphosphate, Co
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