β-Dicobalt pyrophosphate
Identifieur interne : 000364 ( PascalFrancis/Corpus ); précédent : 000363; suivant : 000365β-Dicobalt pyrophosphate
Auteurs : A. El Belghitti ; A. BoukhariSource :
- Acta crystallographica. Section C, Crystal structure communications [ 0108-2701 ] ; 1994.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
A new high-temperature or β form of dicobalt diphosphate, Co2P2O7, has been isolated in space group A2/m (non-standard setting of C2/m). As in other high-temperature forms of transition-metal pyrophosphates, metal atoms lie on planes in a two-dimensional hexagonal array [Co-Co distances 3.461 (4) and 3.284 (3) Å] with adjacent metal atoms linked by two O-atom bridges. Co atoms are octahedrally coordinated with final distortions [average Co-Oeq 2.14 (1), Co-Oax 2.32 (1) Å]
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Pour connaître la documentation sur le format Inist Standard.
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Format Inist (serveur)
NO : | PASCAL 94-0443191 INIST |
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ET : | β-Dicobalt pyrophosphate |
AU : | EL BELGHITTI (A.); BOUKHARI (A.) |
AF : | Univ. Mohammed V, fac. sci., lab. chimie solide appliqué/Rabat/Maroc (1 aut., 2 aut.) |
DT : | Publication en série; Niveau analytique |
SO : | Acta crystallographica. Section C, Crystal structure communications; ISSN 0108-2701; Coden ACSCEE; Danemark; Da. 1994; Vol. 50; No. p.4; Pp. 482-484; Bibl. 13 ref. |
LA : | Anglais |
EA : | A new high-temperature or β form of dicobalt diphosphate, Co2P2O7, has been isolated in space group A2/m (non-standard setting of C2/m). As in other high-temperature forms of transition-metal pyrophosphates, metal atoms lie on planes in a two-dimensional hexagonal array [Co-Co distances 3.461 (4) and 3.284 (3) Å] with adjacent metal atoms linked by two O-atom bridges. Co atoms are octahedrally coordinated with final distortions [average Co-Oeq 2.14 (1), Co-Oax 2.32 (1) Å] |
CC : | 001B60A66F4; 001B60A10M |
FD : | Etude expérimentale; XRD; Structure cristalline; Composé ternaire; Cobalt phosphate; Cobalt Diphosphate; 6166F; 6110M; Co2P2O7; Co O P |
FG : | Composé minéral; Métal transition composé |
ED : | Experimental study; XRD; Crystal structure; Ternary compounds; Cobalt phosphates; Cobalt Pyrophosphates |
EG : | Inorganic compounds; Transition element compounds |
LO : | INIST-5160 C.354000049985980040 |
ID : | 94-0443191 |
Links to Exploration step
Pascal:94-0443191Le document en format XML
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<author><name sortKey="El Belghitti, A" sort="El Belghitti, A" uniqKey="El Belghitti A" first="A." last="El Belghitti">A. El Belghitti</name>
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<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<author><name sortKey="Boukhari, A" sort="Boukhari, A" uniqKey="Boukhari A" first="A." last="Boukhari">A. Boukhari</name>
<affiliation><inist:fA14 i1="01"><s1>Univ. Mohammed V, fac. sci., lab. chimie solide appliqué</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">β-Dicobalt pyrophosphate</title>
<author><name sortKey="El Belghitti, A" sort="El Belghitti, A" uniqKey="El Belghitti A" first="A." last="El Belghitti">A. El Belghitti</name>
<affiliation><inist:fA14 i1="01"><s1>Univ. Mohammed V, fac. sci., lab. chimie solide appliqué</s1>
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<term>Cobalt phosphates</term>
<term>Crystal structure</term>
<term>Experimental study</term>
<term>Ternary compounds</term>
<term>XRD</term>
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<term>XRD</term>
<term>Structure cristalline</term>
<term>Composé ternaire</term>
<term>Cobalt phosphate</term>
<term>Cobalt Diphosphate</term>
<term>6166F</term>
<term>6110M</term>
<term>Co2P2O7</term>
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<front><div type="abstract" xml:lang="en">A new high-temperature or β form of dicobalt diphosphate, Co<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
, has been isolated in space group A2/m (non-standard setting of C2/m). As in other high-temperature forms of transition-metal pyrophosphates, metal atoms lie on planes in a two-dimensional hexagonal array [Co-Co distances 3.461 (4) and 3.284 (3) Å] with adjacent metal atoms linked by two O-atom bridges. Co atoms are octahedrally coordinated with final distortions [average Co-O<sub>eq</sub>
2.14 (1), Co-O<sub>ax</sub>
2.32 (1) Å]</div>
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<sZ>2 aut.</sZ>
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<fC01 i1="01" l="ENG"><s0>A new high-temperature or β form of dicobalt diphosphate, Co<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
, has been isolated in space group A2/m (non-standard setting of C2/m). As in other high-temperature forms of transition-metal pyrophosphates, metal atoms lie on planes in a two-dimensional hexagonal array [Co-Co distances 3.461 (4) and 3.284 (3) Å] with adjacent metal atoms linked by two O-atom bridges. Co atoms are octahedrally coordinated with final distortions [average Co-O<sub>eq</sub>
2.14 (1), Co-O<sub>ax</sub>
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<s5>03</s5>
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<s5>03</s5>
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<s5>05</s5>
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<s5>05</s5>
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<fC03 i1="05" i2="3" l="FRE"><s0>Cobalt phosphate</s0>
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<s5>07</s5>
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<s2>NK</s2>
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<s2>NA</s2>
<s5>08</s5>
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<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>6110M</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>57</s5>
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<fC03 i1="09" i2="3" l="FRE"><s0>Co2P2O7</s0>
<s4>INC</s4>
<s5>92</s5>
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<s4>INC</s4>
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<s5>06</s5>
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<s5>06</s5>
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<server><NO>PASCAL 94-0443191 INIST</NO>
<ET>β-Dicobalt pyrophosphate</ET>
<AU>EL BELGHITTI (A.); BOUKHARI (A.)</AU>
<AF>Univ. Mohammed V, fac. sci., lab. chimie solide appliqué/Rabat/Maroc (1 aut., 2 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Acta crystallographica. Section C, Crystal structure communications; ISSN 0108-2701; Coden ACSCEE; Danemark; Da. 1994; Vol. 50; No. p.4; Pp. 482-484; Bibl. 13 ref.</SO>
<LA>Anglais</LA>
<EA>A new high-temperature or β form of dicobalt diphosphate, Co<sub>2</sub>
P<sub>2</sub>
O<sub>7</sub>
, has been isolated in space group A2/m (non-standard setting of C2/m). As in other high-temperature forms of transition-metal pyrophosphates, metal atoms lie on planes in a two-dimensional hexagonal array [Co-Co distances 3.461 (4) and 3.284 (3) Å] with adjacent metal atoms linked by two O-atom bridges. Co atoms are octahedrally coordinated with final distortions [average Co-O<sub>eq</sub>
2.14 (1), Co-O<sub>ax</sub>
2.32 (1) Å]</EA>
<CC>001B60A66F4; 001B60A10M</CC>
<FD>Etude expérimentale; XRD; Structure cristalline; Composé ternaire; Cobalt phosphate; Cobalt Diphosphate; 6166F; 6110M; Co2P2O7; Co O P</FD>
<FG>Composé minéral; Métal transition composé</FG>
<ED>Experimental study; XRD; Crystal structure; Ternary compounds; Cobalt phosphates; Cobalt Pyrophosphates</ED>
<EG>Inorganic compounds; Transition element compounds</EG>
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