The determination of heterogeneous rate constants by the double-step potentiostatic method
Identifieur interne : 002208 ( Istex/Corpus ); précédent : 002207; suivant : 002209The determination of heterogeneous rate constants by the double-step potentiostatic method
Auteurs : F. M. Kimmerle ; J. ChevaletSource :
- Journal of Electroanalytical Chemistry [ 0022-0728 ] ; 1968.
Abstract
The theory of a new technique for the measurement of electrochemical rate constants is developed. It is shown that the double-step potentiostatic methods, hitherto applied only in the study of homogeneous kinetics, may be extended to the study of heterogeneous rate constants. The boundary value problem for this system has been solved analytically for the case of a plane electrode, and the solution has been extended to the case of the dropping mercury electrode. Algebraic and tabulated functions are presented relating the current or charge measured to the kinetic parameters governing the charge transfer processes occurring in either step.
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DOI: 10.1016/S0022-0728(69)80093-8
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It is shown that the double-step potentiostatic methods, hitherto applied only in the study of homogeneous kinetics, may be extended to the study of heterogeneous rate constants. The boundary value problem for this system has been solved analytically for the case of a plane electrode, and the solution has been extended to the case of the dropping mercury electrode. Algebraic and tabulated functions are presented relating the current or charge measured to the kinetic parameters governing the charge transfer processes occurring in either step.</div></front></TEI><istex><corpusName>elsevier</corpusName><author><json:item><name>F.M. Kimmerle</name><affiliations><json:string>Free University of Brussels, Brussels (Belgium)</json:string></affiliations></json:item><json:item><name>J. 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It is shown that the double-step potentiostatic methods, hitherto applied only in the study of homogeneous kinetics, may be extended to the study of heterogeneous rate constants. The boundary value problem for this system has been solved analytically for the case of a plane electrode, and the solution has been extended to the case of the dropping mercury electrode. Algebraic and tabulated functions are presented relating the current or charge measured to the kinetic parameters governing the charge transfer processes occurring in either step.</p></abstract></profileDesc><revisionDesc><change when="1968-09-20">Received</change><change when="1968">Published</change></revisionDesc></teiHeader></istex:fulltextTEI></fulltext><metadata><istex:metadataXml wicri:clean="Elsevier doc found" wicri:toSee="Elsevier, no converted or simple article"><istex:xmlDeclaration>version="1.0" encoding="utf-8"</istex:xmlDeclaration><istex:docType PUBLIC="-//ES//DTD journal article DTD version 5.0.1//EN//XML" URI="art501.dtd" name="istex:docType"></istex:docType><istex:document><article version="5.0" xml:lang="en" docsubtype="fla"><item-info><jid>JEC</jid><aid>69800938</aid><ce:pii>S0022-0728(69)80093-8</ce:pii><ce:doi>10.1016/S0022-0728(69)80093-8</ce:doi><ce:copyright type="unknown" year="1969">Elsevier Sequoia S.A., Lausanne</ce:copyright></item-info><head><ce:title>The determination of heterogeneous rate constants by the double-step potentiostatic method</ce:title><ce:author-group><ce:author><ce:given-name>F.M.</ce:given-name><ce:surname>Kimmerle</ce:surname><ce:cross-ref refid="fn1"><ce:sup>*</ce:sup></ce:cross-ref></ce:author><ce:affiliation id="aff1"><ce:textfn>Free University of Brussels, Brussels (Belgium)</ce:textfn></ce:affiliation><ce:footnote id="fn1"><ce:label>*</ce:label><ce:note-para>Present address: Department of Chemistry, Université de Sherbrooke, Sherbrooke, Québec (Canada).</ce:note-para></ce:footnote></ce:author-group><ce:author-group><ce:author><ce:given-name>J.</ce:given-name><ce:surname>Chevalet</ce:surname></ce:author><ce:affiliation id="aff2"><ce:textfn>Faculty of Science, Paris (France)</ce:textfn></ce:affiliation></ce:author-group><ce:date-received day="20" month="9" year="1968"></ce:date-received><ce:abstract id="ab1" class="author" xml:lang="en"><ce:section-title>Summary</ce:section-title><ce:abstract-sec><ce:simple-para>The theory of a new technique for the measurement of electrochemical rate constants is developed. It is shown that the double-step potentiostatic methods, hitherto applied only in the study of homogeneous kinetics, may be extended to the study of heterogeneous rate constants. The boundary value problem for this system has been solved analytically for the case of a plane electrode, and the solution has been extended to the case of the dropping mercury electrode. Algebraic and tabulated functions are presented relating the current or charge measured to the kinetic parameters governing the charge transfer processes occurring in either step.</ce:simple-para></ce:abstract-sec></ce:abstract></head><tail><ce:bibliography><ce:section-title>References</ce:section-title><ce:bibliography-sec><ce:bib-reference id="bib1"><ce:label>1</ce:label><sb:reference><sb:contribution langtype="en"><sb:authors><sb:author><ce:given-name>W.M.</ce:given-name><ce:surname>Schwarz</ce:surname></sb:author><sb:author><ce:given-name>I.</ce:given-name><ce:surname>Shain</ce:surname></sb:author></sb:authors></sb:contribution><sb:host><sb:issue><sb:series><sb:title><sb:maintitle>J. Phys. Chem.</sb:maintitle></sb:title><sb:volume-nr>69</sb:volume-nr></sb:series><sb:date>1965</sb:date></sb:issue><sb:pages><sb:first-page>30</sb:first-page></sb:pages></sb:host></sb:reference></ce:bib-reference><ce:bib-reference id="bib2"><ce:label>2</ce:label><sb:reference><sb:contribution langtype="en"><sb:authors><sb:author><ce:given-name>F.C.</ce:given-name><ce:surname>Anson</ce:surname></sb:author></sb:authors></sb:contribution><sb:host><sb:issue><sb:series><sb:title><sb:maintitle>Anal. Chem.</sb:maintitle></sb:title><sb:volume-nr>38</sb:volume-nr></sb:series><sb:date>1966</sb:date></sb:issue><sb:pages><sb:first-page>54</sb:first-page></sb:pages></sb:host></sb:reference></ce:bib-reference><ce:bib-reference id="bib3"><ce:label>3</ce:label><sb:reference><sb:contribution langtype="en"><sb:authors><sb:author><ce:given-name>W.H.</ce:given-name><ce:surname>Reinmuth</ce:surname></sb:author></sb:authors></sb:contribution><sb:host><sb:issue><sb:series><sb:title><sb:maintitle>Anal. Chem.</sb:maintitle></sb:title><sb:volume-nr>40</sb:volume-nr></sb:series><sb:date>1968</sb:date></sb:issue><sb:pages><sb:first-page>185R</sb:first-page></sb:pages></sb:host></sb:reference></ce:bib-reference><ce:bib-reference id="bib4"><ce:label>4</ce:label><sb:reference><sb:contribution langtype="en"><sb:authors><sb:author><ce:given-name>R.V.</ce:given-name><ce:surname>Churchill</ce:surname></sb:author></sb:authors></sb:contribution><sb:host><sb:edited-book><sb:book-series><sb:series><sb:title><sb:maintitle>Modern Operational Mathematics in Engineering</sb:maintitle></sb:title></sb:series></sb:book-series><sb:date>1944</sb:date><sb:publisher><sb:name>McGraw-Hill Book Co.</sb:name><sb:location>New York, N.Y.</sb:location></sb:publisher></sb:edited-book></sb:host></sb:reference><sb:reference><sb:contribution langtype="en"><sb:authors><sb:author><ce:given-name>H.S.</ce:given-name><ce:surname>Carslaw</ce:surname></sb:author></sb:authors></sb:contribution><sb:host><sb:edited-book><sb:book-series><sb:series><sb:title><sb:maintitle>Mathematical Theory of the Conduction of Heat in Solids</sb:maintitle></sb:title></sb:series></sb:book-series><sb:date>1945</sb:date><sb:publisher><sb:name>Dover Publications</sb:name><sb:location>New York N.Y.</sb:location></sb:publisher></sb:edited-book></sb:host></sb:reference></ce:bib-reference><ce:bib-reference id="bib5"><ce:label>5</ce:label><sb:reference><sb:contribution langtype="en"><sb:authors><sb:author><ce:given-name>V.G.</ce:given-name><ce:surname>Levich</ce:surname></sb:author></sb:authors></sb:contribution><sb:host><sb:edited-book><sb:book-series><sb:series><sb:title><sb:maintitle>Physicochemical Hydrodynamics</sb:maintitle></sb:title></sb:series></sb:book-series><sb:date>1962</sb:date><sb:publisher><sb:name>Prentice-Hall Inc.</sb:name><sb:location>Englewood Cliffs, N.J.</sb:location></sb:publisher></sb:edited-book><sb:pages><sb:first-page>537 ff</sb:first-page></sb:pages></sb:host></sb:reference></ce:bib-reference><ce:bib-reference id="bib6"><ce:label>6</ce:label><sb:reference><sb:contribution langtype="en"><sb:authors><sb:author><ce:given-name>J.</ce:given-name><ce:surname>Koutecký</ce:surname></sb:author></sb:authors></sb:contribution><sb:host><sb:issue><sb:series><sb:title><sb:maintitle>Collection Czech. Chem. Commun.</sb:maintitle></sb:title><sb:volume-nr>18</sb:volume-nr></sb:series><sb:date>1953</sb:date></sb:issue><sb:pages><sb:first-page>597</sb:first-page></sb:pages></sb:host></sb:reference></ce:bib-reference><ce:bib-reference id="bib7"><ce:label>7</ce:label><sb:reference><sb:contribution langtype="en"><sb:authors><sb:author><ce:given-name>F.H.</ce:given-name><ce:surname>Beyerlein</ce:surname></sb:author><sb:author><ce:given-name>R.S.</ce:given-name><ce:surname>Nicholson</ce:surname></sb:author></sb:authors></sb:contribution><sb:host><sb:issue><sb:series><sb:title><sb:maintitle>Anal. Chem.</sb:maintitle></sb:title><sb:volume-nr>40</sb:volume-nr></sb:series><sb:date>1968</sb:date></sb:issue><sb:pages><sb:first-page>268</sb:first-page></sb:pages></sb:host></sb:reference></ce:bib-reference></ce:bibliography-sec></ce:bibliography></tail></article></istex:document></istex:metadataXml><mods version="3.6"><titleInfo lang="en"><title>The determination of heterogeneous rate constants by the double-step potentiostatic method</title></titleInfo><titleInfo type="alternative" lang="en" contentType="CDATA"><title>The determination of heterogeneous rate constants by the double-step potentiostatic method</title></titleInfo><name type="personal"><namePart type="given">F.M.</namePart><namePart type="family">Kimmerle</namePart><affiliation>Free University of Brussels, Brussels (Belgium)</affiliation><description>Present address: Department of Chemistry, Université de Sherbrooke, Sherbrooke, Québec (Canada).</description><role><roleTerm type="text">author</roleTerm></role></name><name type="personal"><namePart type="given">J.</namePart><namePart type="family">Chevalet</namePart><affiliation>Faculty of Science, Paris (France)</affiliation><role><roleTerm type="text">author</roleTerm></role></name><typeOfResource>text</typeOfResource><genre type="research-article" displayLabel="Full-length article"></genre><originInfo><publisher>ELSEVIER</publisher><dateIssued encoding="w3cdtf">1968</dateIssued><dateCaptured encoding="w3cdtf">1968-09-20</dateCaptured><copyrightDate encoding="w3cdtf">1969</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm><languageTerm type="code" authority="rfc3066">en</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="en">The theory of a new technique for the measurement of electrochemical rate constants is developed. It is shown that the double-step potentiostatic methods, hitherto applied only in the study of homogeneous kinetics, may be extended to the study of heterogeneous rate constants. The boundary value problem for this system has been solved analytically for the case of a plane electrode, and the solution has been extended to the case of the dropping mercury electrode. Algebraic and tabulated functions are presented relating the current or charge measured to the kinetic parameters governing the charge transfer processes occurring in either step.</abstract><relatedItem type="host"><titleInfo><title>Journal of Electroanalytical Chemistry</title></titleInfo><titleInfo type="abbreviated"><title>JEC</title></titleInfo><genre type="Journal">journal</genre><originInfo><dateIssued encoding="w3cdtf">196905</dateIssued></originInfo><identifier type="ISSN">0022-0728</identifier><identifier type="PII">S0022-0728(69)X8040-3</identifier><part><detail type="volume"><number>21</number><caption>vol.</caption></detail><detail type="issue"><number>2</number><caption>no.</caption></detail><extent unit="issue pages"><start>221</start><end>420</end></extent><extent unit="pages"><start>237</start><end>255</end></extent></part></relatedItem><identifier type="istex">FA3CFD7402914E39EF2AB6604CD82BCE056F9A22</identifier><identifier type="DOI">10.1016/S0022-0728(69)80093-8</identifier><identifier type="PII">S0022-0728(69)80093-8</identifier><identifier type="ArticleID">69800938</identifier><accessCondition type="use and reproduction" contentType="">© 1969Elsevier Sequoia S.A., Lausanne</accessCondition><recordInfo><recordContentSource>ELSEVIER</recordContentSource><recordOrigin>Elsevier Sequoia S.A., Lausanne, ©1969</recordOrigin></recordInfo></mods></metadata><enrichments><istex:catWosTEI uri="https://api.istex.fr/document/FA3CFD7402914E39EF2AB6604CD82BCE056F9A22/enrichments/catWos"><teiHeader><profileDesc><textClass><classCode scheme="WOS">CHEMISTRY, ANALYTICAL</classCode><classCode scheme="WOS">ELECTROCHEMISTRY</classCode></textClass></profileDesc></teiHeader></istex:catWosTEI></enrichments><serie></serie></istex></record>Pour manipuler ce document sous Unix (Dilib)
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