Maximum spin cyclopentadienyl complexes of 3d transition metals
Identifieur interne : 007D62 ( Main/Merge ); précédent : 007D61; suivant : 007D63Maximum spin cyclopentadienyl complexes of 3d transition metals
Auteurs : H. Sitzmann [Allemagne]Source :
- Coordination Chemistry Reviews [ 0010-8545 ] ; 2000.
English descriptors
- KwdEn :
- 3d Transition metals, Cyclopentadienyl complexes, Maximum spin, Me, methyl, Mes, mesityl, VE, valence electrons, acac, acetylacetonate, dme, 1,2-dimethoxyethane, dmpe, 1,2-bis(dimethylphosphino)ethane, dppe, 1,2-bis(diphenylphosphino)ethane, thf, tetrahydrofuran, tmeda, 1,2-bis(dimethylamino)ethane, μB, Bohr magnetons, μeff, effective magnetic moment.
Abstract
For decades maximum spin behavior of transition metal cyclopentadienyl complexes seemed to be limited to a small set of 3d central atoms in certain oxidation states such as V(II), V(III), Cr(III), Mn(II), and nickelocenes. The observation of four unpaired electrons for the Fe(II) central atoms of the tetraisopropylcyclopentadienyliron bromide dimer in 1996 erased such limitations. High spin behavior has then also been observed for chromocenes and nickel(II) half sandwich complexes. Many of these species are easily accessible, highly reactive and serve as versatile starting compounds for a broad range of follow-up products.
Url:
DOI: 10.1016/S0010-8545(01)00298-3
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 000392
- to stream Istex, to step Curation: 000392
- to stream Istex, to step Checkpoint: 002C12
Links to Exploration step
ISTEX:F1D1A8D5253BECD81B79DE0D04D3ADB0E1471573Le document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Maximum spin cyclopentadienyl complexes of 3d transition metals</title><author><name sortKey="Sitzmann, H" sort="Sitzmann, H" uniqKey="Sitzmann H" first="H." last="Sitzmann">H. Sitzmann</name></author></titleStmt><publicationStmt><idno type="wicri:source">ISTEX</idno><idno type="RBID">ISTEX:F1D1A8D5253BECD81B79DE0D04D3ADB0E1471573</idno><date when="2001" year="2001">2001</date><idno type="doi">10.1016/S0010-8545(01)00298-3</idno><idno type="url">https://api.istex.fr/document/F1D1A8D5253BECD81B79DE0D04D3ADB0E1471573/fulltext/pdf</idno><idno type="wicri:Area/Istex/Corpus">000392</idno><idno type="wicri:Area/Istex/Curation">000392</idno><idno type="wicri:Area/Istex/Checkpoint">002C12</idno><idno type="wicri:doubleKey">0010-8545:2001:Sitzmann H:maximum:spin:cyclopentadienyl</idno><idno type="wicri:Area/Main/Merge">007D62</idno></publicationStmt><sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Maximum spin cyclopentadienyl complexes of 3d transition metals</title><author><name sortKey="Sitzmann, H" sort="Sitzmann, H" uniqKey="Sitzmann H" first="H." last="Sitzmann">H. Sitzmann</name><affiliation wicri:level="3"><country xml:lang="fr">Allemagne</country><wicri:regionArea>FB Chemie der Universitat, Erwin-Schroedinger Strasse, 67663 Kaiserslautern</wicri:regionArea><placeName><region type="land" nuts="2">Rhénanie-Palatinat</region><settlement type="city">Kaiserslautern</settlement></placeName></affiliation><affiliation wicri:level="1"><country wicri:rule="url">Allemagne</country></affiliation></author></analytic><monogr></monogr><series><title level="j">Coordination Chemistry Reviews</title><title level="j" type="abbrev">CCR</title><idno type="ISSN">0010-8545</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="2000">2000</date><biblScope unit="volume">214</biblScope><biblScope unit="issue">1</biblScope><biblScope unit="page" from="287">287</biblScope><biblScope unit="page" to="327">327</biblScope></imprint><idno type="ISSN">0010-8545</idno></series><idno type="istex">F1D1A8D5253BECD81B79DE0D04D3ADB0E1471573</idno><idno type="DOI">10.1016/S0010-8545(01)00298-3</idno><idno type="PII">S0010-8545(01)00298-3</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0010-8545</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>3d Transition metals</term><term>Cyclopentadienyl complexes</term><term>Maximum spin</term><term>Me, methyl</term><term>Mes, mesityl</term><term>VE, valence electrons</term><term>acac, acetylacetonate</term><term>dme, 1,2-dimethoxyethane</term><term>dmpe, 1,2-bis(dimethylphosphino)ethane</term><term>dppe, 1,2-bis(diphenylphosphino)ethane</term><term>thf, tetrahydrofuran</term><term>tmeda, 1,2-bis(dimethylamino)ethane</term><term>μB, Bohr magnetons</term><term>μeff, effective magnetic moment</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">For decades maximum spin behavior of transition metal cyclopentadienyl complexes seemed to be limited to a small set of 3d central atoms in certain oxidation states such as V(II), V(III), Cr(III), Mn(II), and nickelocenes. The observation of four unpaired electrons for the Fe(II) central atoms of the tetraisopropylcyclopentadienyliron bromide dimer in 1996 erased such limitations. High spin behavior has then also been observed for chromocenes and nickel(II) half sandwich complexes. Many of these species are easily accessible, highly reactive and serve as versatile starting compounds for a broad range of follow-up products.</div></front></TEI></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Ticri/CIDE/explor/HapticV1/Data/Main/Merge
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 007D62 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Merge/biblio.hfd -nk 007D62 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Ticri/CIDE
|area= HapticV1
|flux= Main
|étape= Merge
|type= RBID
|clé= ISTEX:F1D1A8D5253BECD81B79DE0D04D3ADB0E1471573
|texte= Maximum spin cyclopentadienyl complexes of 3d transition metals
}}
| This area was generated with Dilib version V0.6.23. |  |