Lanthanide complexes as nuclear magnetic resonance structural probes: paramagnetic anisotropy of shift reagent adducts.
Identifieur interne : 000896 ( PubMed/Corpus ); précédent : 000895; suivant : 000897Lanthanide complexes as nuclear magnetic resonance structural probes: paramagnetic anisotropy of shift reagent adducts.
Auteurs : W D Horrocks ; J P SipeSource :
- Science (New York, N.Y.) [ 0036-8075 ] ; 1972.
Abstract
Magnetic anisotropy measurements on single crystals of a series of paramagnetic 8-coordinate lanthanide shift reagent adducts of the type Ln[(CH(3))(3)CCOCHCOC(CH(3))(3)(4-CH(3)C(5)H(1)N)(2) have been made for the following lanthanides: praseodymium, neodymium, samarium, europium, terbium, dysprosium, holmium, erbium, thulium, and ytterbium. The susceptibility tensors are highly anisotropic and nonaxial. Dipolar nuclear magnetic resonance shifts evaluated from the solid-state date are in satisfactory agreement with the solution results.
DOI: 10.1126/science.177.4053.994
PubMed: 17788812
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