[Fluorescence enhancement character of terbium perchlorate and thulium perchlorate with phenylcarboxymethyl sulfoxide coordination compounds].
Identifieur interne : 000697 ( PubMed/Corpus ); précédent : 000696; suivant : 000698[Fluorescence enhancement character of terbium perchlorate and thulium perchlorate with phenylcarboxymethyl sulfoxide coordination compounds].
Auteurs : Wen-Xian Li ; Guo-Jiun Wu ; Zhong-Shi Liu ; Feng-Mei HanSource :
- Guang pu xue yu guang pu fen xi = Guang pu [ 1000-0593 ] ; 2002.
English descriptors
- KwdEn :
- MESH :
- chemical , chemistry : Benzene Derivatives, Chelating Agents, Perchlorates, Terbium, Thulium.
- Spectrometry, Fluorescence, Spectrophotometry, Infrared.
Abstract
(Tb1-x Tmx).L2.(ClO4).2H2O(x = 0.000 to 0.200, L = C6H5SOCH2COO-) have been synthesized. The coordination compounds have been studied by means of composition analysis, molar conductivity, IR, and the condition of coordination have been inferred. In the fluorescent spectra it was found that Tm3+ has a strongly sensitization effect to the fluorescence of Tb3+. The fluorescent emission intensity of Terbium perchlorate with phenylcarboxymethyl sulfoxide coordination compounds would be enhanced by Tm3+ in mixing. Tm3+ has a sensitization to the fluorescence of Tb3+ in the ratio of Tb3+:Tm3+ = 0.999:0.001-0.900:0.100. In the solubility experiment it was found that the complexes have high solubility in ethanol.
PubMed: 12914160
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">[Fluorescence enhancement character of terbium perchlorate and thulium perchlorate with phenylcarboxymethyl sulfoxide coordination compounds].</title><author><name sortKey="Li, Wen Xian" sort="Li, Wen Xian" uniqKey="Li W" first="Wen-Xian" last="Li">Wen-Xian Li</name><affiliation><nlm:affiliation>College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China.</nlm:affiliation></affiliation></author><author><name sortKey="Wu, Guo Jiun" sort="Wu, Guo Jiun" uniqKey="Wu G" first="Guo-Jiun" last="Wu">Guo-Jiun Wu</name></author><author><name sortKey="Liu, Zhong Shi" sort="Liu, Zhong Shi" uniqKey="Liu Z" first="Zhong-Shi" last="Liu">Zhong-Shi Liu</name></author><author><name sortKey="Han, Feng Mei" sort="Han, Feng Mei" uniqKey="Han F" first="Feng-Mei" last="Han">Feng-Mei Han</name></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2002">2002</date><idno type="RBID">pubmed:12914160</idno><idno type="pmid">12914160</idno><idno type="wicri:Area/PubMed/Corpus">000697</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000697</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">[Fluorescence enhancement character of terbium perchlorate and thulium perchlorate with phenylcarboxymethyl sulfoxide coordination compounds].</title><author><name sortKey="Li, Wen Xian" sort="Li, Wen Xian" uniqKey="Li W" first="Wen-Xian" last="Li">Wen-Xian Li</name><affiliation><nlm:affiliation>College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China.</nlm:affiliation></affiliation></author><author><name sortKey="Wu, Guo Jiun" sort="Wu, Guo Jiun" uniqKey="Wu G" first="Guo-Jiun" last="Wu">Guo-Jiun Wu</name></author><author><name sortKey="Liu, Zhong Shi" sort="Liu, Zhong Shi" uniqKey="Liu Z" first="Zhong-Shi" last="Liu">Zhong-Shi Liu</name></author><author><name sortKey="Han, Feng Mei" sort="Han, Feng Mei" uniqKey="Han F" first="Feng-Mei" last="Han">Feng-Mei Han</name></author></analytic><series><title level="j">Guang pu xue yu guang pu fen xi = Guang pu</title><idno type="ISSN">1000-0593</idno><imprint><date when="2002" type="published">2002</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Benzene Derivatives (chemistry)</term><term>Chelating Agents (chemistry)</term><term>Perchlorates (chemistry)</term><term>Spectrometry, Fluorescence</term><term>Spectrophotometry, Infrared</term><term>Terbium (chemistry)</term><term>Thulium (chemistry)</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Benzene Derivatives</term><term>Chelating Agents</term><term>Perchlorates</term><term>Terbium</term><term>Thulium</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Spectrometry, Fluorescence</term><term>Spectrophotometry, Infrared</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">(Tb1-x Tmx).L2.(ClO4).2H2O(x = 0.000 to 0.200, L = C6H5SOCH2COO-) have been synthesized. The coordination compounds have been studied by means of composition analysis, molar conductivity, IR, and the condition of coordination have been inferred. In the fluorescent spectra it was found that Tm3+ has a strongly sensitization effect to the fluorescence of Tb3+. The fluorescent emission intensity of Terbium perchlorate with phenylcarboxymethyl sulfoxide coordination compounds would be enhanced by Tm3+ in mixing. Tm3+ has a sensitization to the fluorescence of Tb3+ in the ratio of Tb3+:Tm3+ = 0.999:0.001-0.900:0.100. In the solubility experiment it was found that the complexes have high solubility in ethanol.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="MEDLINE"><PMID Version="1">12914160</PMID><DateCreated><Year>2003</Year><Month>08</Month><Day>13</Day></DateCreated><DateCompleted><Year>2004</Year><Month>07</Month><Day>06</Day></DateCompleted><DateRevised><Year>2013</Year><Month>11</Month><Day>21</Day></DateRevised><Article PubModel="Print"><Journal><ISSN IssnType="Print">1000-0593</ISSN><JournalIssue CitedMedium="Print"><Volume>22</Volume><Issue>6</Issue><PubDate><Year>2002</Year><Month>Dec</Month></PubDate></JournalIssue><Title>Guang pu xue yu guang pu fen xi = Guang pu</Title><ISOAbbreviation>Guang Pu Xue Yu Guang Pu Fen Xi</ISOAbbreviation></Journal><ArticleTitle>[Fluorescence enhancement character of terbium perchlorate and thulium perchlorate with phenylcarboxymethyl sulfoxide coordination compounds].</ArticleTitle><Pagination><MedlinePgn>905-7</MedlinePgn></Pagination><Abstract><AbstractText>(Tb1-x Tmx).L2.(ClO4).2H2O(x = 0.000 to 0.200, L = C6H5SOCH2COO-) have been synthesized. The coordination compounds have been studied by means of composition analysis, molar conductivity, IR, and the condition of coordination have been inferred. In the fluorescent spectra it was found that Tm3+ has a strongly sensitization effect to the fluorescence of Tb3+. The fluorescent emission intensity of Terbium perchlorate with phenylcarboxymethyl sulfoxide coordination compounds would be enhanced by Tm3+ in mixing. Tm3+ has a sensitization to the fluorescence of Tb3+ in the ratio of Tb3+:Tm3+ = 0.999:0.001-0.900:0.100. In the solubility experiment it was found that the complexes have high solubility in ethanol.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Li</LastName><ForeName>Wen-xian</ForeName><Initials>WX</Initials><AffiliationInfo><Affiliation>College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Wu</LastName><ForeName>Guo-jiun</ForeName><Initials>GJ</Initials></Author><Author ValidYN="Y"><LastName>Liu</LastName><ForeName>Zhong-shi</ForeName><Initials>ZS</Initials></Author><Author ValidYN="Y"><LastName>Han</LastName><ForeName>Feng-mei</ForeName><Initials>FM</Initials></Author></AuthorList><Language>chi</Language><PublicationTypeList><PublicationType UI="D004740">English Abstract</PublicationType><PublicationType UI="D016428">Journal Article</PublicationType><PublicationType UI="D013485">Research Support, Non-U.S. Gov't</PublicationType></PublicationTypeList></Article><MedlineJournalInfo><Country>China</Country><MedlineTA>Guang Pu Xue Yu Guang Pu Fen Xi</MedlineTA><NlmUniqueID>9424805</NlmUniqueID><ISSNLinking>1000-0593</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D001555">Benzene Derivatives</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D002614">Chelating Agents</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D010472">Perchlorates</NameOfSubstance></Chemical><Chemical><RegistryNumber>06SSF7P179</RegistryNumber><NameOfSubstance UI="D013725">Terbium</NameOfSubstance></Chemical><Chemical><RegistryNumber>8RKC5ATI4P</RegistryNumber><NameOfSubstance UI="D013932">Thulium</NameOfSubstance></Chemical><Chemical><RegistryNumber>945-51-7</RegistryNumber><NameOfSubstance UI="C048860">diphenyl sulfoxide</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName MajorTopicYN="N" UI="D001555">Benzene Derivatives</DescriptorName><QualifierName MajorTopicYN="N" UI="Q000737">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D002614">Chelating Agents</DescriptorName><QualifierName MajorTopicYN="N" UI="Q000737">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D010472">Perchlorates</DescriptorName><QualifierName MajorTopicYN="Y" UI="Q000737">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D013050">Spectrometry, Fluorescence</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D013055">Spectrophotometry, Infrared</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D013725">Terbium</DescriptorName><QualifierName MajorTopicYN="Y" UI="Q000737">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D013932">Thulium</DescriptorName><QualifierName MajorTopicYN="Y" UI="Q000737">chemistry</QualifierName></MeshHeading></MeshHeadingList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="pubmed"><Year>2003</Year><Month>8</Month><Day>14</Day><Hour>5</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2004</Year><Month>7</Month><Day>9</Day><Hour>5</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2003</Year><Month>8</Month><Day>14</Day><Hour>5</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">12914160</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
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