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Study of luminescence properties of novel Er3+ single-doped and Er3+/Yb3+ co-doped tellurite glasses.

Identifieur interne : 000667 ( PubMed/Corpus ); précédent : 000666; suivant : 000668

Study of luminescence properties of novel Er3+ single-doped and Er3+/Yb3+ co-doped tellurite glasses.

Auteurs : Yuan Gao ; Qiu-Hua Nie ; Tie-Feng Xu ; Xiang Shen

Source :

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy [ 1386-1425 ] ; 2005.

RBID : pubmed:15741130

English descriptors

KwdEn :
- Erbium (chemistry), Glass (chemistry), Luminescent Measurements, Oxides (chemistry), Phosphatidylethanolamines, Spectrophotometry, Tellurium (chemistry), Thulium (chemistry), Ytterbium (chemistry).
MESH :
- chemical , chemistry : Erbium, Oxides, Tellurium, Thulium, Ytterbium.
- chemistry : Glass.
- Luminescent Measurements, Phosphatidylethanolamines, Spectrophotometry.

Abstract

The novel Er(3+) single-doped and Er(3+)/Yb(3+) co-doped tellurite glasses were prepared. The effect of Yb(2)O(3) concentration on absorption spectra, emission spectra and upconversion spectra of glasses were measured and investigated. The emission intensity, fluorescence full width at half maximum (FWHM) and upconversion luminescence of Er(3+) go up with the increasing concentration of Yb(3+) ions. The maximum FWHM of (4)I(13/2) --> (4)I(15/2) transition of Er(3+) is approximate 77 nm for 1.41 x 10(21)ions/cm(3) concentration of Yb(3+)-doped glass. The visible upconversion emissions at about 532, 546 and 659 nm, corresponding to the (2)H(11/2) --> (4)I(15/2), (4)S(3/2) --> (4)I(15/2) and (4)F(9/2) --> (4)I(15/2) transitions of Er(3+), respectively, were simultaneously observed under the excitation at 970 nm. Subsequently, the possible upconversion mechanisms and important role of Yb(3+) on the green and red emissions were discussed and compared. The results demonstrate that this kind of tellurite glass may be a potentially useful material for developing potential amplifiers and upconversion optical devices.

DOI: 10.1016/j.saa.2004.06.050
PubMed: 15741130

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pubmed:15741130

Le document en format XML

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<author><name sortKey="Gao, Yuan" sort="Gao, Yuan" uniqKey="Gao Y" first="Yuan" last="Gao">Yuan Gao</name>
<affiliation><nlm:affiliation>College of Information Science and Engineering, Ningbo University, Ningbo 315211, China. gybetty@sohu.com</nlm:affiliation>
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<author><name sortKey="Nie, Qiu Hua" sort="Nie, Qiu Hua" uniqKey="Nie Q" first="Qiu-Hua" last="Nie">Qiu-Hua Nie</name>
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<author><name sortKey="Xu, Tie Feng" sort="Xu, Tie Feng" uniqKey="Xu T" first="Tie-Feng" last="Xu">Tie-Feng Xu</name>
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<author><name sortKey="Shen, Xiang" sort="Shen, Xiang" uniqKey="Shen X" first="Xiang" last="Shen">Xiang Shen</name>
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<term>Phosphatidylethanolamines</term>
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<front><div type="abstract" xml:lang="en">The novel Er(3+) single-doped and Er(3+)/Yb(3+) co-doped tellurite glasses were prepared. The effect of Yb(2)O(3) concentration on absorption spectra, emission spectra and upconversion spectra of glasses were measured and investigated. The emission intensity, fluorescence full width at half maximum (FWHM) and upconversion luminescence of Er(3+) go up with the increasing concentration of Yb(3+) ions. The maximum FWHM of (4)I(13/2) --> (4)I(15/2) transition of Er(3+) is approximate 77 nm for 1.41 x 10(21)ions/cm(3) concentration of Yb(3+)-doped glass. The visible upconversion emissions at about 532, 546 and 659 nm, corresponding to the (2)H(11/2) --> (4)I(15/2), (4)S(3/2) --> (4)I(15/2) and (4)F(9/2) --> (4)I(15/2) transitions of Er(3+), respectively, were simultaneously observed under the excitation at 970 nm. Subsequently, the possible upconversion mechanisms and important role of Yb(3+) on the green and red emissions were discussed and compared. The results demonstrate that this kind of tellurite glass may be a potentially useful material for developing potential amplifiers and upconversion optical devices.</div>
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<Abstract><AbstractText>The novel Er(3+) single-doped and Er(3+)/Yb(3+) co-doped tellurite glasses were prepared. The effect of Yb(2)O(3) concentration on absorption spectra, emission spectra and upconversion spectra of glasses were measured and investigated. The emission intensity, fluorescence full width at half maximum (FWHM) and upconversion luminescence of Er(3+) go up with the increasing concentration of Yb(3+) ions. The maximum FWHM of (4)I(13/2) --> (4)I(15/2) transition of Er(3+) is approximate 77 nm for 1.41 x 10(21)ions/cm(3) concentration of Yb(3+)-doped glass. The visible upconversion emissions at about 532, 546 and 659 nm, corresponding to the (2)H(11/2) --> (4)I(15/2), (4)S(3/2) --> (4)I(15/2) and (4)F(9/2) --> (4)I(15/2) transitions of Er(3+), respectively, were simultaneously observed under the excitation at 970 nm. Subsequently, the possible upconversion mechanisms and important role of Yb(3+) on the green and red emissions were discussed and compared. The results demonstrate that this kind of tellurite glass may be a potentially useful material for developing potential amplifiers and upconversion optical devices.</AbstractText>
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Study of luminescence properties of novel Er3+ single-doped and Er3+/Yb3+ co-doped tellurite glasses.

Study of luminescence properties of novel Er3+ single-doped and Er3+/Yb3+ co-doped tellurite glasses.

Source :

English descriptors

Abstract

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

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Pour générer des pages wiki