ThuliumV1, PubMed, Corpus, bibRecord, 000633

Strong visible up-conversion emission in Tb3+, Tm3+ and Tb3+-Tm3+ co-doped tellurite glasses sensitized by Yb3+.

Identifieur interne : 000633 ( PubMed/Corpus ); précédent : 000632; suivant : 000634

Strong visible up-conversion emission in Tb3+, Tm3+ and Tb3+-Tm3+ co-doped tellurite glasses sensitized by Yb3+.

Auteurs : Xunsi Wang ; Liren Liu ; Qiuhua Nie ; Tiefeng Xu ; Xiang Shen ; Shixun Dai ; Xianghua Zhang

Source :

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy [ 1386-1425 ] ; 2007.

RBID : pubmed:17110158

English descriptors

KwdEn :
- Glass (chemistry), Ions, Luminescence, Spectrophotometry (methods), Tellurium (chemistry), Terbium (chemistry), Thulium (chemistry), Time Factors, Ytterbium (chemistry).
MESH :
- chemical , chemistry : Tellurium, Terbium, Thulium, Ytterbium.
- chemical : Ions.
- chemistry : Glass.
- methods : Spectrophotometry.
- Luminescence, Time Factors.

Abstract

Up-conversion luminescence characteristics under 975 nm excitation have been investigated with Tb3+/Tm3+/Yb3+ triply doped tellurite glasses. Here, green (547 nm: (5)D(4)-->(7)F(4)) and red (660 nm: (5)D(4)-->(7)F(2)) up-conversion (UC) luminescence originating from Tb3+ is observed strongly, because of the quadratic dependences of emission intensities on the excitation power. Especially, the UC luminescence was intensified violently with the energy transfer from the Tm3+ ions involves in the Tb3+ excitation. To the Tb3+/Tm3+/Yb3+ triply doped glass system, a novel up-conversion mechanism is proposed as follows: the energy of (3)G(4) level (Tm3+) was transferred to (5)D(4) (Tb(3+)) and the 477-nm UC luminescence of Tm3+ was nearly quenched.

DOI: 10.1016/j.saa.2006.09.023
PubMed: 17110158

Links to Exploration step

pubmed:17110158

Le document en format XML

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<author><name sortKey="Wang, Xunsi" sort="Wang, Xunsi" uniqKey="Wang X" first="Xunsi" last="Wang">Xunsi Wang</name>
<affiliation><nlm:affiliation>Shanghai Institute of Optics & Fine Mechanics, CAS, Shanghai 201800, China. xunsiwang@siom.ac.cn</nlm:affiliation>
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<author><name sortKey="Liu, Liren" sort="Liu, Liren" uniqKey="Liu L" first="Liren" last="Liu">Liren Liu</name>
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<author><name sortKey="Nie, Qiuhua" sort="Nie, Qiuhua" uniqKey="Nie Q" first="Qiuhua" last="Nie">Qiuhua Nie</name>
</author>
<author><name sortKey="Xu, Tiefeng" sort="Xu, Tiefeng" uniqKey="Xu T" first="Tiefeng" last="Xu">Tiefeng Xu</name>
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<author><name sortKey="Shen, Xiang" sort="Shen, Xiang" uniqKey="Shen X" first="Xiang" last="Shen">Xiang Shen</name>
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<author><name sortKey="Dai, Shixun" sort="Dai, Shixun" uniqKey="Dai S" first="Shixun" last="Dai">Shixun Dai</name>
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<author><name sortKey="Zhang, Xianghua" sort="Zhang, Xianghua" uniqKey="Zhang X" first="Xianghua" last="Zhang">Xianghua Zhang</name>
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<term>Terbium (chemistry)</term>
<term>Thulium (chemistry)</term>
<term>Time Factors</term>
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<front><div type="abstract" xml:lang="en">Up-conversion luminescence characteristics under 975 nm excitation have been investigated with Tb3+/Tm3+/Yb3+ triply doped tellurite glasses. Here, green (547 nm: (5)D(4)-->(7)F(4)) and red (660 nm: (5)D(4)-->(7)F(2)) up-conversion (UC) luminescence originating from Tb3+ is observed strongly, because of the quadratic dependences of emission intensities on the excitation power. Especially, the UC luminescence was intensified violently with the energy transfer from the Tm3+ ions involves in the Tb3+ excitation. To the Tb3+/Tm3+/Yb3+ triply doped glass system, a novel up-conversion mechanism is proposed as follows: the energy of (3)G(4) level (Tm3+) was transferred to (5)D(4) (Tb(3+)) and the 477-nm UC luminescence of Tm3+ was nearly quenched.</div>
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<Abstract><AbstractText>Up-conversion luminescence characteristics under 975 nm excitation have been investigated with Tb3+/Tm3+/Yb3+ triply doped tellurite glasses. Here, green (547 nm: (5)D(4)-->(7)F(4)) and red (660 nm: (5)D(4)-->(7)F(2)) up-conversion (UC) luminescence originating from Tb3+ is observed strongly, because of the quadratic dependences of emission intensities on the excitation power. Especially, the UC luminescence was intensified violently with the energy transfer from the Tm3+ ions involves in the Tb3+ excitation. To the Tb3+/Tm3+/Yb3+ triply doped glass system, a novel up-conversion mechanism is proposed as follows: the energy of (3)G(4) level (Tm3+) was transferred to (5)D(4) (Tb(3+)) and the 477-nm UC luminescence of Tm3+ was nearly quenched.</AbstractText>
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Strong visible up-conversion emission in Tb3+, Tm3+ and Tb3+-Tm3+ co-doped tellurite glasses sensitized by Yb3+.

Strong visible up-conversion emission in Tb3+, Tm3+ and Tb3+-Tm3+ co-doped tellurite glasses sensitized by Yb3+.

Source :

English descriptors

Abstract

Links to Exploration step

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