ThuliumV1, PubMed, Corpus, bibRecord, 000506

Enhanced 2.0 microm emission and gain coefficient of transparent glass ceramic containing BaF2: Ho3+,Tm3+ nanocrystals.

Identifieur interne : 000506 ( PubMed/Corpus ); précédent : 000505; suivant : 000507

Enhanced 2.0 microm emission and gain coefficient of transparent glass ceramic containing BaF2: Ho3+,Tm3+ nanocrystals.

Auteurs : W J Zhang ; Q Y Zhang ; Q J Chen ; Q. Qian ; Z M Yang ; J R Qiu ; P. Huang ; Y S Wang

Source :

Optics express [ 1094-4087 ] ; 2009.

RBID : pubmed:19997333

English descriptors

KwdEn :
- Barium Compounds (chemistry), Ceramics (chemistry), Equipment Design, Fluorides (chemistry), Glass (chemistry), Holmium (chemistry), Ions, Lasers, Microscopy, Electron, Transmission, Nanoparticles (chemistry), Spectrophotometry, Infrared (instrumentation), Thulium (chemistry), X-Ray Diffraction.
MESH :
- chemical , chemistry : Barium Compounds, Fluorides, Holmium, Thulium.
- chemistry : Ceramics, Glass, Nanoparticles.
- instrumentation : Spectrophotometry, Infrared.
- Equipment Design, Ions, Lasers, Microscopy, Electron, Transmission, X-Ray Diffraction.

Abstract

Transparent glass ceramic containing BaF(2):Ho(3+),Tm(3+) nanocrystals has been prepared by melt quenching and subsequent thermal treatment. The precipitation of BaF(2) nanocrystals was confirmed by X-ray diffraction and high-resolution transmission electron microscopy. Intense 2.0 microm fluorescence originating from Ho(3+): (5)I(7) --> (5)I(8) transition was achieved upon excitation with 808 nm laser diode. A large ratio of forward Tm(3+) --> Ho(3+) energy transfer constant to that of backward process indicated high efficient energy transfer from Tm(3+)((3)F(4)) to Ho(3+)((5)I(7)), benefited from the reduced ionic distances of Tm(3+)-Tm(3+) and Tm(3+)-Ho(3+) pairs and low phonon energy environment with the incorporation of rare-earth ions into the precipitated BaF(2) nanocrystals. The results indicate that glass ceramic is a promising candidate material for 2.0 microm laser.

PubMed: 19997333

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pubmed:19997333

Le document en format XML

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<author><name sortKey="Zhang, W J" sort="Zhang, W J" uniqKey="Zhang W" first="W J" last="Zhang">W J Zhang</name>
<affiliation><nlm:affiliation>Key Lab of Specially Functional Materials of Ministry of Education, Institute of Optical Communication Materials, South China University of Technology, Guangzhou 510641, P. R. China.</nlm:affiliation>
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<author><name sortKey="Zhang, Q Y" sort="Zhang, Q Y" uniqKey="Zhang Q" first="Q Y" last="Zhang">Q Y Zhang</name>
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<author><name sortKey="Chen, Q J" sort="Chen, Q J" uniqKey="Chen Q" first="Q J" last="Chen">Q J Chen</name>
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<author><name sortKey="Qian, Q" sort="Qian, Q" uniqKey="Qian Q" first="Q" last="Qian">Q. Qian</name>
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<author><name sortKey="Yang, Z M" sort="Yang, Z M" uniqKey="Yang Z" first="Z M" last="Yang">Z M Yang</name>
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<author><name sortKey="Qiu, J R" sort="Qiu, J R" uniqKey="Qiu J" first="J R" last="Qiu">J R Qiu</name>
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<author><name sortKey="Huang, P" sort="Huang, P" uniqKey="Huang P" first="P" last="Huang">P. Huang</name>
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<author><name sortKey="Wang, Y S" sort="Wang, Y S" uniqKey="Wang Y" first="Y S" last="Wang">Y S Wang</name>
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<term>Glass (chemistry)</term>
<term>Holmium (chemistry)</term>
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<term>Spectrophotometry, Infrared (instrumentation)</term>
<term>Thulium (chemistry)</term>
<term>X-Ray Diffraction</term>
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<term>Thulium</term>
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<front><div type="abstract" xml:lang="en">Transparent glass ceramic containing BaF(2):Ho(3+),Tm(3+) nanocrystals has been prepared by melt quenching and subsequent thermal treatment. The precipitation of BaF(2) nanocrystals was confirmed by X-ray diffraction and high-resolution transmission electron microscopy. Intense 2.0 microm fluorescence originating from Ho(3+): (5)I(7) --> (5)I(8) transition was achieved upon excitation with 808 nm laser diode. A large ratio of forward Tm(3+) --> Ho(3+) energy transfer constant to that of backward process indicated high efficient energy transfer from Tm(3+)((3)F(4)) to Ho(3+)((5)I(7)), benefited from the reduced ionic distances of Tm(3+)-Tm(3+) and Tm(3+)-Ho(3+) pairs and low phonon energy environment with the incorporation of rare-earth ions into the precipitated BaF(2) nanocrystals. The results indicate that glass ceramic is a promising candidate material for 2.0 microm laser.</div>
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<Abstract><AbstractText>Transparent glass ceramic containing BaF(2):Ho(3+),Tm(3+) nanocrystals has been prepared by melt quenching and subsequent thermal treatment. The precipitation of BaF(2) nanocrystals was confirmed by X-ray diffraction and high-resolution transmission electron microscopy. Intense 2.0 microm fluorescence originating from Ho(3+): (5)I(7) --> (5)I(8) transition was achieved upon excitation with 808 nm laser diode. A large ratio of forward Tm(3+) --> Ho(3+) energy transfer constant to that of backward process indicated high efficient energy transfer from Tm(3+)((3)F(4)) to Ho(3+)((5)I(7)), benefited from the reduced ionic distances of Tm(3+)-Tm(3+) and Tm(3+)-Ho(3+) pairs and low phonon energy environment with the incorporation of rare-earth ions into the precipitated BaF(2) nanocrystals. The results indicate that glass ceramic is a promising candidate material for 2.0 microm laser.</AbstractText>
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Enhanced 2.0 microm emission and gain coefficient of transparent glass ceramic containing BaF2: Ho3+,Tm3+ nanocrystals.

Enhanced 2.0 microm emission and gain coefficient of transparent glass ceramic containing BaF2: Ho3+,Tm3+ nanocrystals.

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English descriptors

Abstract

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