Heterometallic Na-Y(Ln) trifluoroacetate diglyme complexes as novel single-source precursors for upconverting NaYF4 nanocrystals co-doped with Yb and Er/Tm ions.
Identifieur interne : 000482 ( PubMed/Checkpoint ); précédent : 000481; suivant : 000483Heterometallic Na-Y(Ln) trifluoroacetate diglyme complexes as novel single-source precursors for upconverting NaYF4 nanocrystals co-doped with Yb and Er/Tm ions.
Auteurs : Shashank Mishra [France] ; Stéphane Daniele ; Gilles Ledoux ; Erwann Jeanneau ; Marie-France JoubertSource :
- Chemical communications (Cambridge, England) [ 1364-548X ] ; 2010.
Descripteurs français
- KwdFr :
- MESH :
English descriptors
- KwdEn :
- MESH :
- chemical , chemistry : Alkenes, Coordination Complexes, Erbium, Ethylene Glycols, Fluorides, Methyl Ethers, Thulium, Trifluoroacetic Acid, Yttrium.
- chemistry : Nanoparticles.
- Molecular Conformation, Temperature.
Abstract
We report synthesis of new single-source heterometallic precursors [NaLn(TFA)(4)(diglyme)] (Ln = Y, Er, Tm, Yb; TFA = trifluoroacetate), which decompose in 1-octadecene at significantly low temperature, without using any surfactant or capping reagent, to give sub-50 nm particles of cubic and/or hexagonal NaYF(4) : Yb(3+), Er(3+)/Tm(3+) materials forming well-dispersed colloidal solutions in dichloromethane and exhibiting green/blue upconversion luminescence.
DOI: 10.1039/b921474g
PubMed: 20401365
Affiliations:
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Einstein, 69626 Villeurbanne, France. mishrashashank74@rediffmail.com</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Université Lyon 1, IRCELYON, 2 Avenue A. 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Commun. (Camb.)</ISOAbbreviation></Journal><ArticleTitle>Heterometallic Na-Y(Ln) trifluoroacetate diglyme complexes as novel single-source precursors for upconverting NaYF4 nanocrystals co-doped with Yb and Er/Tm ions.</ArticleTitle><Pagination><MedlinePgn>3756-8</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1039/b921474g</ELocationID><Abstract><AbstractText>We report synthesis of new single-source heterometallic precursors [NaLn(TFA)(4)(diglyme)] (Ln = Y, Er, Tm, Yb; TFA = trifluoroacetate), which decompose in 1-octadecene at significantly low temperature, without using any surfactant or capping reagent, to give sub-50 nm particles of cubic and/or hexagonal NaYF(4) : Yb(3+), Er(3+)/Tm(3+) materials forming well-dispersed colloidal solutions in dichloromethane and exhibiting green/blue upconversion luminescence.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Mishra</LastName><ForeName>Shashank</ForeName><Initials>S</Initials><AffiliationInfo><Affiliation>Université Lyon 1, IRCELYON, 2 Avenue A. 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Daniele</name><name sortKey="Jeanneau, Erwann" sort="Jeanneau, Erwann" uniqKey="Jeanneau E" first="Erwann" last="Jeanneau">Erwann Jeanneau</name><name sortKey="Joubert, Marie France" sort="Joubert, Marie France" uniqKey="Joubert M" first="Marie-France" last="Joubert">Marie-France Joubert</name><name sortKey="Ledoux, Gilles" sort="Ledoux, Gilles" uniqKey="Ledoux G" first="Gilles" last="Ledoux">Gilles Ledoux</name></noCountry><country name="France"><region name="Auvergne-Rhône-Alpes"><name sortKey="Mishra, Shashank" sort="Mishra, Shashank" uniqKey="Mishra S" first="Shashank" last="Mishra">Shashank Mishra</name></region></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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