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Isolation and Structural Characterization of Two Very Large, and Largely Empty, Endohedral Fullerenes: Tm@C3v-C94 and Ca@C3v-C94

Identifieur interne : 000215 ( Pmc/Curation ); précédent : 000214; suivant : 000216

Isolation and Structural Characterization of Two Very Large, and Largely Empty, Endohedral Fullerenes: Tm@C3v-C94 and Ca@C3v-C94

Auteurs : Yuliang Che [République populaire de Chine] ; Hua Yang [République populaire de Chine] ; Zhimin Wang [République populaire de Chine] ; Hongxiao Jin [République populaire de Chine] ; Ziyang Liu [République populaire de Chine] ; Chunxin Lu [République populaire de Chine] ; Tianming Zuo ; Harry C. Dorn ; Christine M. Beavers [États-Unis] ; Marilyn M. Olmstead [États-Unis] ; Alan L. Balch [États-Unis]

Source :

Inorganic chemistry [ 0020-1669 ] ; 2009.

RBID : PMC:2878390

Abstract

The structures of two newly synthesized endohedral fullerenes - Tm@C_3v-C₉₄ and Ca@C_3v-C₉₄ - have been determined by single crystal X-ray diffraction on samples co-crystallized with Ni^II(octaethylporphyrin). Both compounds exhibit the same cage geometry and conform to the isolated pentagon rule (IPR). The metal ions within these rather large cages are localized near one end and along the C₃ axis. While the calcium ion is situated over a C-C bond at a 6:6 ring junction, the thulium ion is positioned above a six-membered ring of the fullerene.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2878390

DOI: 10.1021/ic900322d
PubMed: 19507844
PubMed Central: 2878390

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Tianming Zuo

<affiliation><nlm:aff id="A2"> Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, VA, 24061</nlm:aff>
<wicri:noCountry code="subfield">24061</wicri:noCountry>
</affiliation>

Harry C. Dorn

<affiliation><nlm:aff id="A2"> Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, VA, 24061</nlm:aff>
<wicri:noCountry code="subfield">24061</wicri:noCountry>
</affiliation>

Le document en format XML

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<author><name sortKey="Dorn, Harry C" sort="Dorn, Harry C" uniqKey="Dorn H" first="Harry C." last="Dorn">Harry C. Dorn</name>
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<wicri:noCountry code="subfield">24061</wicri:noCountry>
</affiliation>
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<author><name sortKey="Beavers, Christine M" sort="Beavers, Christine M" uniqKey="Beavers C" first="Christine M." last="Beavers">Christine M. Beavers</name>
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<country xml:lang="fr">États-Unis</country>
<placeName><region type="state">Californie</region>
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<series><title level="j">Inorganic chemistry</title>
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<front><div type="abstract" xml:lang="en"><p id="P1">The structures of two newly synthesized endohedral fullerenes - Tm@<italic>C<sub>3v</sub>
</italic>
-C<sub>94</sub>
 and Ca@<italic>C<sub>3v</sub>
</italic>
-C<sub>94</sub>
 - have been determined by single crystal X-ray diffraction on samples co-crystallized with Ni<sup>II</sup>
(octaethylporphyrin). Both compounds exhibit the same cage geometry and conform to the isolated pentagon rule (IPR). The metal ions within these rather large cages are localized near one end and along the C<sub>3</sub>
 axis. While the calcium ion is situated over a C-C bond at a 6:6 ring junction, the thulium ion is positioned above a six-membered ring of the fullerene.</p>
</div>
</front>
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  <front><journal-meta><journal-id journal-id-type="nlm-journal-id">0366543</journal-id>
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<title-group><article-title>Isolation and Structural Characterization of Two Very Large, and Largely Empty, Endohedral Fullerenes: Tm@C3v-C94 and Ca@C3v-C94</article-title>
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<contrib-group><contrib contrib-type="author"><name><surname>Che</surname>
<given-names>Yuliang</given-names>
</name>
<xref rid="A1" ref-type="aff">‡</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Yang</surname>
<given-names>Hua</given-names>
</name>
<xref rid="A1" ref-type="aff">‡</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Wang</surname>
<given-names>Zhimin</given-names>
</name>
<xref rid="A1" ref-type="aff">‡</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Jin</surname>
<given-names>Hongxiao</given-names>
</name>
<xref rid="A1" ref-type="aff">‡</xref>
</contrib>
<contrib contrib-type="author" corresp="yes"><name><surname>Liu</surname>
<given-names>Ziyang</given-names>
</name>
<xref rid="A1" ref-type="aff">‡</xref>
<email>zyliu@zju.edu.cn</email>
</contrib>
<contrib contrib-type="author"><name><surname>Lu</surname>
<given-names>Chunxin</given-names>
</name>
<xref rid="A1" ref-type="aff">‡</xref>
</contrib>
<contrib contrib-type="author"><name><surname>Zuo</surname>
<given-names>Tianming</given-names>
</name>
<xref rid="A2" ref-type="aff">†</xref>
</contrib>
<contrib contrib-type="author" corresp="yes"><name><surname>Dorn</surname>
<given-names>Harry C.</given-names>
</name>
<xref rid="A2" ref-type="aff">†</xref>
<email>hdorn@vt.edu</email>
</contrib>
<contrib contrib-type="author"><name><surname>Beavers</surname>
<given-names>Christine M.</given-names>
</name>
<xref rid="A3" ref-type="aff">+</xref>
</contrib>
<contrib contrib-type="author" corresp="yes"><name><surname>Olmstead</surname>
<given-names>Marilyn M.</given-names>
</name>
<xref rid="A3" ref-type="aff">+</xref>
<email>mmolmstead@ucdavis.edu</email>
</contrib>
<contrib contrib-type="author" corresp="yes"><name><surname>Balch</surname>
<given-names>Alan L.</given-names>
</name>
<xref rid="A3" ref-type="aff">+</xref>
<email>albalch@ucdavis.edu</email>
</contrib>
</contrib-group>
<aff id="A1"><label>‡</label>
 Department of Chemistry, Zhejiang University, Hangzhou 310027, China</aff>
<aff id="A2"><label>†</label>
 Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, VA, 24061</aff>
<aff id="A3"><label>+</label>
 Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, California 95616</aff>
<pub-date pub-type="nihms-submitted"><day>5</day>
<month>11</month>
<year>2009</year>
</pub-date>
<pub-date pub-type="ppub"><day>6</day>
<month>7</month>
<year>2009</year>
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<pub-date pub-type="pmc-release"><day>6</day>
<month>7</month>
<year>2010</year>
</pub-date>
<volume>48</volume>
<issue>13</issue>
<fpage>6004</fpage>
<lpage>6010</lpage>
<abstract><p id="P1">The structures of two newly synthesized endohedral fullerenes - Tm@<italic>C<sub>3v</sub>
</italic>
-C<sub>94</sub>
 and Ca@<italic>C<sub>3v</sub>
</italic>
-C<sub>94</sub>
 - have been determined by single crystal X-ray diffraction on samples co-crystallized with Ni<sup>II</sup>
(octaethylporphyrin). Both compounds exhibit the same cage geometry and conform to the isolated pentagon rule (IPR). The metal ions within these rather large cages are localized near one end and along the C<sub>3</sub>
 axis. While the calcium ion is situated over a C-C bond at a 6:6 ring junction, the thulium ion is positioned above a six-membered ring of the fullerene.</p>
</abstract>
<contract-num rid="CA1">R01 CA119371-01
				||CA</contract-num>
<contract-sponsor id="CA1">National Cancer Institute : NCI</contract-sponsor>
</article-meta>
</front>
</pmc>
</record>

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Isolation and Structural Characterization of Two Very Large, and Largely Empty, Endohedral Fullerenes: Tm@C3v-C94 and Ca@C3v-C94

Isolation and Structural Characterization of Two Very Large, and Largely Empty, Endohedral Fullerenes: Tm@C3v-C94 and Ca@C3v-C94

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Abstract

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