Electrochemical oxidation of cholesterol
Identifieur interne : 000044 ( Pmc/Corpus ); précédent : 000043; suivant : 000045Electrochemical oxidation of cholesterol
Auteurs : Jacek W. Morzycki ; Andrzej SobkowiakSource :
- Beilstein Journal of Organic Chemistry [ 1860-5397 ] ; 2015.
Abstract
Indirect cholesterol electrochemical oxidation in the presence of various mediators leads to electrophilic addition to the double bond, oxidation at the allylic position, oxidation of the hydroxy group, or functionalization of the side chain. Recent studies have proven that direct electrochemical oxidation of cholesterol is also possible and affords different products depending on the reaction conditions.
Url:
DOI: 10.3762/bjoc.11.45
PubMed: 25977713
PubMed Central: 4419515
Links to Exploration step
PMC:4419515Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Electrochemical oxidation of cholesterol</title><author><name sortKey="Morzycki, Jacek W" sort="Morzycki, Jacek W" uniqKey="Morzycki J" first="Jacek W" last="Morzycki">Jacek W. Morzycki</name><affiliation><nlm:aff id="A1">Institute of Chemistry, University of Białystok, ul. Ciołkowskiego 1K, 15-245 Białystok, Poland</nlm:aff></affiliation></author><author><name sortKey="Sobkowiak, Andrzej" sort="Sobkowiak, Andrzej" uniqKey="Sobkowiak A" first="Andrzej" last="Sobkowiak">Andrzej Sobkowiak</name><affiliation><nlm:aff id="A2">Faculty of Chemistry, Rzeszów University of Technology, P.O. Box 85, 35-959 Rzeszów, Poland</nlm:aff></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">25977713</idno><idno type="pmc">4419515</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4419515</idno><idno type="RBID">PMC:4419515</idno><idno type="doi">10.3762/bjoc.11.45</idno><date when="2015">2015</date><idno type="wicri:Area/Pmc/Corpus">000044</idno><idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000044</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Electrochemical oxidation of cholesterol</title><author><name sortKey="Morzycki, Jacek W" sort="Morzycki, Jacek W" uniqKey="Morzycki J" first="Jacek W" last="Morzycki">Jacek W. Morzycki</name><affiliation><nlm:aff id="A1">Institute of Chemistry, University of Białystok, ul. Ciołkowskiego 1K, 15-245 Białystok, Poland</nlm:aff></affiliation></author><author><name sortKey="Sobkowiak, Andrzej" sort="Sobkowiak, Andrzej" uniqKey="Sobkowiak A" first="Andrzej" last="Sobkowiak">Andrzej Sobkowiak</name><affiliation><nlm:aff id="A2">Faculty of Chemistry, Rzeszów University of Technology, P.O. Box 85, 35-959 Rzeszów, Poland</nlm:aff></affiliation></author></analytic><series><title level="j">Beilstein Journal of Organic Chemistry</title><idno type="eISSN">1860-5397</idno><imprint><date when="2015">2015</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><title>Summary</title><p>Indirect cholesterol electrochemical oxidation in the presence of various mediators leads to electrophilic addition to the double bond, oxidation at the allylic position, oxidation of the hydroxy group, or functionalization of the side chain. Recent studies have proven that direct electrochemical oxidation of cholesterol is also possible and affords different products depending on the reaction conditions.</p></div></front></TEI><pmc article-type="review-article"><pmc-comment>The publisher of this article does not allow downloading of the full text in XML form.</pmc-comment>
<front><journal-meta><journal-id journal-id-type="nlm-ta">Beilstein J Org Chem</journal-id><journal-id journal-id-type="iso-abbrev">Beilstein J Org Chem</journal-id><journal-title-group><journal-title>Beilstein Journal of Organic Chemistry</journal-title></journal-title-group><issn pub-type="epub">1860-5397</issn><publisher><publisher-name>Beilstein-Institut</publisher-name><publisher-loc>Trakehner Str. 7-9, 60487 Frankfurt am Main, Germany</publisher-loc></publisher></journal-meta><article-meta><article-id pub-id-type="pmid">25977713</article-id><article-id pub-id-type="pmc">4419515</article-id><article-id pub-id-type="doi">10.3762/bjoc.11.45</article-id><article-categories><subj-group subj-group-type="heading"><subject>Review</subject></subj-group><subj-group subj-group-type="topic"><subject>Chemistry</subject><subj-group subj-group-type="topic"><subject>Organic Chemistry</subject></subj-group></subj-group></article-categories><title-group><article-title>Electrochemical oxidation of cholesterol</article-title></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name><surname>Morzycki</surname><given-names>Jacek W</given-names></name><email>morzycki@uwb.edu.pl</email><xref ref-type="aff" rid="A1">1</xref></contrib><contrib contrib-type="author" corresp="yes"><name><surname>Sobkowiak</surname><given-names>Andrzej</given-names></name><email>asobkow@prz.edu.pl</email><xref ref-type="aff" rid="A2">2</xref></contrib></contrib-group><contrib-group><contrib contrib-type="editor"><name><surname>Waldvogel</surname><given-names>Siegfried R</given-names></name><role>Guest Editor</role></contrib></contrib-group><aff id="A1"><label>1</label>Institute of Chemistry, University of Białystok, ul. Ciołkowskiego 1K, 15-245 Białystok, Poland</aff><aff id="A2"><label>2</label>Faculty of Chemistry, Rzeszów University of Technology, P.O. Box 85, 35-959 Rzeszów, Poland</aff><pub-date pub-type="collection"><year>2015</year></pub-date><pub-date pub-type="epub"><day>25</day><month>3</month><year>2015</year></pub-date><volume>11</volume><fpage>392</fpage><lpage>402</lpage><ext-link ext-link-type="doi" xlink:href="10.3762/bjoc.11.45">10.3762/bjoc.11.45</ext-link><history><date date-type="received"><day>5</day><month>1</month><year>2015</year></date><date date-type="accepted"><day>3</day><month>3</month><year>2015</year></date></history><permissions><copyright-statement>Copyright © 2015, Morzycki and Sobkowiak; licensee Beilstein-Institut.</copyright-statement><copyright-year>2015</copyright-year><copyright-holder>Morzycki and Sobkowiak; licensee Beilstein-Institut.</copyright-holder><license license-type="Beilstein" xlink:href="http://www.beilstein-journals.org/bjoc"><license-p>This is an Open Access article under the terms of the Creative Commons Attribution License (<ext-link ext-link-type="uri" xlink:href="http://creativecommons.org/licenses/by/2.0">http://creativecommons.org/licenses/by/2.0</ext-link>), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.</license-p><license-p>The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (<ext-link ext-link-type="uri" xlink:href="http://www.beilstein-journals.org/bjoc">http://www.beilstein-journals.org/bjoc</ext-link>)</license-p></license></permissions><abstract><title>Summary</title><p>Indirect cholesterol electrochemical oxidation in the presence of various mediators leads to electrophilic addition to the double bond, oxidation at the allylic position, oxidation of the hydroxy group, or functionalization of the side chain. Recent studies have proven that direct electrochemical oxidation of cholesterol is also possible and affords different products depending on the reaction conditions.</p></abstract><abstract abstract-type="graphical"><p><disp-formula id="graphical-abstract"><graphic xlink:href="Beilstein_J_Org_Chem-11-392-g001.jpg" position="float" orientation="portrait"></graphic></disp-formula></p></abstract><kwd-group kwd-group-type="author"><kwd>allylic oxidation</kwd><kwd>cholesterol</kwd><kwd>electrochemical halogenation</kwd><kwd>electrochemical oxidation</kwd></kwd-group></article-meta><notes><p>This article is part of the Thematic Series "Electrosynthesis".</p></notes></front></pmc></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/ThuliumV1/Data/Pmc/Corpus
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000044 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Pmc/Corpus/biblio.hfd -nk 000044 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Terre
|area= ThuliumV1
|flux= Pmc
|étape= Corpus
|type= RBID
|clé= PMC:4419515
|texte= Electrochemical oxidation of cholesterol
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Pmc/Corpus/RBID.i -Sk "pubmed:25977713" \
| HfdSelect -Kh $EXPLOR_AREA/Data/Pmc/Corpus/biblio.hfd \
| NlmPubMed2Wicri -a ThuliumV1
| This area was generated with Dilib version V0.6.21. |  |