ThuliumV1, Pascal, Curation, bibRecord, 001895

Energy transfer by magnetic dipole-magnetic dipole interaction

Identifieur interne : 001895 ( Pascal/Curation ); précédent : 001894; suivant : 001896

Energy transfer by magnetic dipole-magnetic dipole interaction

Auteurs : P. A. Tanner [Hong Kong] ; M. Chua ; M. F. Reid

Source :

Chemical physics letters [ 0009-2614 ] ; 1993.

RBID : Pascal:93-0569622

Descripteurs français

Pascal (Inist)
- Etude théorique, Transfert énergie, Interaction dipolaire, Dipôle magnétique, Luminescence, Composé minéral, Césium Sodium Thulium Chlorure Mixte.
Wicri :
- topic : Composé minéral.

English descriptors

KwdEn :
- Cesium Sodium Thulium Chlorides Mixed, Dipolar interaction, Energy transfer, Inorganic compound, Luminescence, Magnetic dipole, Theoretical study.

Abstract

The magnetic dipole interaction mechanism is shown to be important in a nonradiative energy transfer process of a lanthanide ion in a centrosymmetric environment. The concentration quenching of near-ultraviolet luminescence in Cs₂NaTmCl₆ may be explained by this mechanism, the calculated nonradiative transfer rate from the donor Tm³⁺ being 1.44×10⁵s^-1. The transfer rate decreases by a factor of 103 for transfer to the 7th nearest neighbours, compared with that to the 1 st nearest. However, the angular dependence of the transfer, and the different coordination numbers for nth nearest neighbours, lead to an increased transfer rate to 3rd nearest neighbours, compared with that to the 2nd nearest set; and to the 5th nearest neighbours compared with the 4th set

A01	`01`	`1`		`@0 0009-2614`
A02	`01`			`@0 CHPLBC`
A03		`1`		`@0 Chem. phys. lett.`
A05				`@2 209`
A06				`@2 5-6`
A08	`01`	`1`	`ENG`	`@1 Energy transfer by magnetic dipole-magnetic dipole interaction`
A11	`01`	`1`		`@1 TANNER (P. A.)`
A11	`02`	`1`		`@1 CHUA (M.)`
A11	`03`	`1`		`@1 REID (M. F.)`
A14	`01`			`@1 City polytech. Hong Kong, dep. applied sci. @2 Kowloon @3 HKG @Z 1 aut.`
A20				`@1 539-546`
A21				`@1 1993`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 13494 @5 354000034815540190`
A44				`@0 0000`
A45				`@0 39 ref.`
A47	`01`	`1`		`@0 93-0569622`
A60				`@1 P`
A61				`@0 A`
A64		`1`		`@0 Chemical physics letters`
A66	`01`			`@0 NLD`
C01	`01`		`ENG`	@0 The magnetic dipole interaction mechanism is shown to be important in a nonradiative energy transfer process of a lanthanide ion in a centrosymmetric environment. The concentration quenching of near-ultraviolet luminescence in Cs₂NaTmCl₆ may be explained by this mechanism, the calculated nonradiative transfer rate from the donor Tm³⁺ being 1.44×10⁵s^-1. The transfer rate decreases by a factor of 103 for transfer to the 7th nearest neighbours, compared with that to the 1 st nearest. However, the angular dependence of the transfer, and the different coordination numbers for nth nearest neighbours, lead to an increased transfer rate to 3rd nearest neighbours, compared with that to the 2nd nearest set; and to the 5th nearest neighbours compared with the 4th set
C02	`01`	`X`		`@0 001B11H08`
C03	`01`	`X`	`FRE`	`@0 Etude théorique @5 01`
C03	`01`	`X`	`ENG`	`@0 Theoretical study @5 01`
C03	`01`	`X`	`GER`	`@0 Theoretische Untersuchung @5 01`
C03	`01`	`X`	`SPA`	`@0 Estudio teórico @5 01`
C03	`02`	`X`	`FRE`	`@0 Transfert énergie @5 02`
C03	`02`	`X`	`ENG`	`@0 Energy transfer @5 02`
C03	`02`	`X`	`SPA`	`@0 Transferencia energía @5 02`
C03	`03`	`X`	`FRE`	`@0 Interaction dipolaire @5 03`
C03	`03`	`X`	`ENG`	`@0 Dipolar interaction @5 03`
C03	`03`	`X`	`SPA`	`@0 Interacción dipolar @5 03`
C03	`04`	`X`	`FRE`	`@0 Dipôle magnétique @5 04`
C03	`04`	`X`	`ENG`	`@0 Magnetic dipole @5 04`
C03	`04`	`X`	`SPA`	`@0 Dipolo magnético @5 04`
C03	`05`	`X`	`FRE`	`@0 Luminescence @5 05`
C03	`05`	`X`	`ENG`	`@0 Luminescence @5 05`
C03	`05`	`X`	`GER`	`@0 Lumineszenz @5 05`
C03	`05`	`X`	`SPA`	`@0 Luminiscencia @5 05`
C03	`06`	`X`	`FRE`	`@0 Composé minéral @5 12`
C03	`06`	`X`	`ENG`	`@0 Inorganic compound @5 12`
C03	`06`	`X`	`SPA`	`@0 Compuesto inorgánico @5 12`
C03	`07`	`X`	`FRE`	`@0 Césium Sodium Thulium Chlorure Mixte @2 NC @2 NA @5 17`
C03	`07`	`X`	`ENG`	`@0 Cesium Sodium Thulium Chlorides Mixed @2 NC @2 NA @5 17`
C03	`07`	`X`	`SPA`	`@0 Cesio Sodio Tulio Cloruro Mixto @2 NC @2 NA @5 17`
C07	`01`	`X`	`FRE`	`@0 Lanthanide Composé @2 NC @2 NA @5 16`
C07	`01`	`X`	`ENG`	`@0 Lanthanide Compounds @2 NC @2 NA @5 16`
C07	`01`	`X`	`SPA`	`@0 Lantánido Compuesto @2 NC @2 NA @5 16`
N21				`@1 265`

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Pascal:93-0569622

Le document en format XML

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<author><name sortKey="Tanner, P A" sort="Tanner, P A" uniqKey="Tanner P" first="P. A." last="Tanner">P. A. Tanner</name>
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<author><name sortKey="Chua, M" sort="Chua, M" uniqKey="Chua M" first="M." last="Chua">M. Chua</name>
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<front><div type="abstract" xml:lang="en">The magnetic dipole interaction mechanism is shown to be important in a nonradiative energy transfer process of a lanthanide ion in a centrosymmetric environment. The concentration quenching of near-ultraviolet luminescence in Cs<sub>2</sub>
NaTmCl<sub>6</sub>
 may be explained by this mechanism, the calculated nonradiative transfer rate from the donor Tm<sup>3+</sup>
 being 1.44×10<sup>5</sup>
s<sup>-1</sup>
. The transfer rate decreases by a factor of 103 for transfer to the 7th nearest neighbours, compared with that to the 1 st nearest. However, the angular dependence of the transfer, and the different coordination numbers for nth nearest neighbours, lead to an increased transfer rate to 3rd nearest neighbours, compared with that to the 2nd nearest set; and to the 5th nearest neighbours compared with the 4th set</div>
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<fC01 i1="01" l="ENG"><s0>The magnetic dipole interaction mechanism is shown to be important in a nonradiative energy transfer process of a lanthanide ion in a centrosymmetric environment. The concentration quenching of near-ultraviolet luminescence in Cs<sub>2</sub>
NaTmCl<sub>6</sub>
 may be explained by this mechanism, the calculated nonradiative transfer rate from the donor Tm<sup>3+</sup>
 being 1.44×10<sup>5</sup>
s<sup>-1</sup>
. The transfer rate decreases by a factor of 103 for transfer to the 7th nearest neighbours, compared with that to the 1 st nearest. However, the angular dependence of the transfer, and the different coordination numbers for nth nearest neighbours, lead to an increased transfer rate to 3rd nearest neighbours, compared with that to the 2nd nearest set; and to the 5th nearest neighbours compared with the 4th set</s0>
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<s5>03</s5>
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<s5>03</s5>
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<s5>03</s5>
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<s5>04</s5>
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<s5>04</s5>
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<s5>04</s5>
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<s5>05</s5>
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<s5>17</s5>
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<s2>NC</s2>
<s2>NA</s2>
<s5>17</s5>
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<s5>16</s5>
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Energy transfer by magnetic dipole-magnetic dipole interaction

Energy transfer by magnetic dipole-magnetic dipole interaction

Source :

Descripteurs français

English descriptors

Abstract

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