ThuliumV1, Pascal, Curation, bibRecord, 001382

Sensitizing effect of Tm3+ on 2.9 μm emission from Dy3+-doped Ge25Ga5S70 glass

Identifieur interne : 001382 ( Pascal/Curation ); précédent : 001381; suivant : 001383

Sensitizing effect of Tm3+ on 2.9 μm emission from Dy3+-doped Ge25Ga5S70 glass

Auteurs : J. Heo [Corée du Sud] ; W. Y. Cho [Corée du Sud] ; W. J. Chung [Corée du Sud]

Source :

Journal of non-crystalline solids [ 0022-3093 ] ; 1997.

RBID : Pascal:97-0326175

Descripteurs français

Pascal (Inist)
- Photoluminescence, Fluorescence, Matériau dopé, Codopage, Addition dysprosium, Addition thulium, Transfert énergie, Durée vie, Transition niveau énergie, Recouvrement raie spectrale, Déclin luminescence, Paire accepteur donneur, Etude expérimentale, Verre chalcogénure, Composé ternaire, Germanium sulfure, Gallium sulfure, 7855H, Ge25Ga5S70:Dy Tm, Ga Ge S.

English descriptors

KwdEn :
- Acceptor donor pair, Chalcogenide glasses, Codoping, Doped materials, Dysprosium additions, Energy transfer, Energy-level transitions, Experimental study, Fluorescence, Gallium sulfides, Germanium sulfides, Lifetime, Luminescence decay, Photoluminescence, Spectral line overlapping, Ternary compounds, Thulium additions.

Abstract

Copyright (c) 1997 Elsevier Science B.V. All rights reserved. Energy transfer mechanisms and the effect of Tm³⁺ addition on the intensity of the Dy³⁺:2.9 μm emission from Ge₂₅Ga₅S₇₀ glass were investigated. Intensity of the 2.9 μm fluorescence from Dy³⁺ increased with increasing Tm³⁺ content when the Dy³⁺ concentration remained constant, which indicates the presence of an efficient energy transfer between Tm³⁺ and Dy³⁺. A decrease in the measured lifetimes of the Tm³⁺:³F₄ level and a wide spectral overlap between the Tm³⁺:1.8 μm emission and the absorption of Dy³⁺:⁶H_15/2→⁶H_11/2 also supported the proposed energy transfer scheme. Analyses of the emission intensities and decay times suggested that a direct energy transfer from the Tm³⁺:³F₄ level to Dy³⁺:⁶H_11/2 level occurred after a fast diffusion-limited migration of the excitation energy among Tm³⁺.

A01	`01`	`1`		`@0 0022-3093`
A02	`01`			`@0 JNCSBJ`
A03		`1`		`@0 J. non-cryst. solids`
A05				`@2 212`
A06				`@2 2-3`
A08	`01`	`1`	`ENG`	`@1 Sensitizing effect of Tm³⁺ on 2.9 μm emission from Dy³⁺-doped Ge₂₅Ga₅S₇₀ glass`
A11	`01`	`1`		`@1 HEO (J.)`
A11	`02`	`1`		`@1 CHO (W. Y.)`
A11	`03`	`1`		`@1 CHUNG (W. J.)`
A14	`01`			`@1 Non-Crystalline Materials Laboratory, Department of Materials Science and Engineering, Pohang University of Science and Technology @2 Pohang @3 KOR @Z 1 aut. @Z 2 aut. @Z 3 aut.`
A20				`@1 151-156`
A21				`@1 1997`
A23	`01`			`@0 ENG`
A24	`01`			`@0 eng`
A43	`01`			`@1 INIST @2 14572 @5 354000061677880012`
A44				`@0 9000 @1 © 1997 Elsevier Science B.V. All rights reserved.`
A47	`01`	`1`		`@0 97-0326175`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Journal of non-crystalline solids`
A66	`01`			`@0 NLD`
C01	`01`		`ENG`	@0 Copyright (c) 1997 Elsevier Science B.V. All rights reserved. Energy transfer mechanisms and the effect of Tm³⁺ addition on the intensity of the Dy³⁺:2.9 μm emission from Ge₂₅Ga₅S₇₀ glass were investigated. Intensity of the 2.9 μm fluorescence from Dy³⁺ increased with increasing Tm³⁺ content when the Dy³⁺ concentration remained constant, which indicates the presence of an efficient energy transfer between Tm³⁺ and Dy³⁺. A decrease in the measured lifetimes of the Tm³⁺:³F₄ level and a wide spectral overlap between the Tm³⁺:1.8 μm emission and the absorption of Dy³⁺:⁶H_15/2→⁶H_11/2 also supported the proposed energy transfer scheme. Analyses of the emission intensities and decay times suggested that a direct energy transfer from the Tm³⁺:³F₄ level to Dy³⁺:⁶H_11/2 level occurred after a fast diffusion-limited migration of the excitation energy among Tm³⁺.
C02	`01`	`3`		`@0 001B70H55H`
C03	`01`	`3`	`FRE`	`@0 Photoluminescence @5 01`
C03	`01`	`3`	`ENG`	`@0 Photoluminescence @5 01`
C03	`02`	`3`	`FRE`	`@0 Fluorescence @5 02`
C03	`02`	`3`	`ENG`	`@0 Fluorescence @5 02`
C03	`03`	`3`	`FRE`	`@0 Matériau dopé @5 03`
C03	`03`	`3`	`ENG`	`@0 Doped materials @5 03`
C03	`04`	`X`	`FRE`	`@0 Codopage @5 04`
C03	`04`	`X`	`ENG`	`@0 Codoping @5 04`
C03	`04`	`X`	`SPA`	`@0 Codrogado @5 04`
C03	`05`	`3`	`FRE`	`@0 Addition dysprosium @5 05`
C03	`05`	`3`	`ENG`	`@0 Dysprosium additions @5 05`
C03	`06`	`3`	`FRE`	`@0 Addition thulium @5 06`
C03	`06`	`3`	`ENG`	`@0 Thulium additions @5 06`
C03	`07`	`3`	`FRE`	`@0 Transfert énergie @5 07`
C03	`07`	`3`	`ENG`	`@0 Energy transfer @5 07`
C03	`08`	`3`	`FRE`	`@0 Durée vie @5 08`
C03	`08`	`3`	`ENG`	`@0 Lifetime @5 08`
C03	`09`	`3`	`FRE`	`@0 Transition niveau énergie @5 09`
C03	`09`	`3`	`ENG`	`@0 Energy-level transitions @5 09`
C03	`10`	`X`	`FRE`	`@0 Recouvrement raie spectrale @5 10`
C03	`10`	`X`	`ENG`	`@0 Spectral line overlapping @5 10`
C03	`10`	`X`	`SPA`	`@0 Recubrimiento raya espectral @5 10`
C03	`11`	`X`	`FRE`	`@0 Déclin luminescence @5 11`
C03	`11`	`X`	`ENG`	`@0 Luminescence decay @5 11`
C03	`11`	`X`	`SPA`	`@0 Decadencia luminiscencia @5 11`
C03	`12`	`X`	`FRE`	`@0 Paire accepteur donneur @5 12`
C03	`12`	`X`	`ENG`	`@0 Acceptor donor pair @5 12`
C03	`12`	`X`	`SPA`	`@0 Par aceptor dador @5 12`
C03	`13`	`3`	`FRE`	`@0 Etude expérimentale @5 13`
C03	`13`	`3`	`ENG`	`@0 Experimental study @5 13`
C03	`14`	`3`	`FRE`	`@0 Verre chalcogénure @5 14`
C03	`14`	`3`	`ENG`	`@0 Chalcogenide glasses @5 14`
C03	`15`	`3`	`FRE`	`@0 Composé ternaire @5 15`
C03	`15`	`3`	`ENG`	`@0 Ternary compounds @5 15`
C03	`16`	`3`	`FRE`	`@0 Germanium sulfure @2 NK @5 17`
C03	`16`	`3`	`ENG`	`@0 Germanium sulfides @2 NK @5 17`
C03	`17`	`3`	`FRE`	`@0 Gallium sulfure @2 NK @5 18`
C03	`17`	`3`	`ENG`	`@0 Gallium sulfides @2 NK @5 18`
C03	`18`	`3`	`FRE`	`@0 7855H @2 PAC @4 INC @5 56`
C03	`19`	`3`	`FRE`	`@0 Ge25Ga5S70:Dy Tm @4 INC @5 92`
C03	`20`	`3`	`FRE`	`@0 Ga Ge S @4 INC @5 93`
C07	`01`	`3`	`FRE`	`@0 Composé minéral @5 16`
C07	`01`	`3`	`ENG`	`@0 Inorganic compounds @5 16`
N21				`@1 188`

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Pascal:97-0326175

Le document en format XML

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 on 2.9 μm emission from Dy<sup>3+</sup>
-doped Ge<sub>25</sub>
Ga<sub>5</sub>
S<sub>70</sub>
 glass</title>
<author><name sortKey="Heo, J" sort="Heo, J" uniqKey="Heo J" first="J." last="Heo">J. Heo</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Sensitizing effect of Tm<sup>3+</sup>
 on 2.9 μm emission from Dy<sup>3+</sup>
-doped Ge<sub>25</sub>
Ga<sub>5</sub>
S<sub>70</sub>
 glass</title>
<author><name sortKey="Heo, J" sort="Heo, J" uniqKey="Heo J" first="J." last="Heo">J. Heo</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Non-Crystalline Materials Laboratory, Department of Materials Science and Engineering, Pohang University of Science and Technology</s1>
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<sZ>1 aut.</sZ>
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<country>Corée du Sud</country>
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<author><name sortKey="Cho, W Y" sort="Cho, W Y" uniqKey="Cho W" first="W. Y." last="Cho">W. Y. Cho</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Non-Crystalline Materials Laboratory, Department of Materials Science and Engineering, Pohang University of Science and Technology</s1>
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<author><name sortKey="Chung, W J" sort="Chung, W J" uniqKey="Chung W" first="W. J." last="Chung">W. J. Chung</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Non-Crystalline Materials Laboratory, Department of Materials Science and Engineering, Pohang University of Science and Technology</s1>
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<s3>KOR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>Corée du Sud</country>
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</author>
</analytic>
<series><title level="j" type="main">Journal of non-crystalline solids</title>
<title level="j" type="abbreviated">J. non-cryst. solids</title>
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<seriesStmt><title level="j" type="main">Journal of non-crystalline solids</title>
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<term>Codoping</term>
<term>Doped materials</term>
<term>Dysprosium additions</term>
<term>Energy transfer</term>
<term>Energy-level transitions</term>
<term>Experimental study</term>
<term>Fluorescence</term>
<term>Gallium sulfides</term>
<term>Germanium sulfides</term>
<term>Lifetime</term>
<term>Luminescence decay</term>
<term>Photoluminescence</term>
<term>Spectral line overlapping</term>
<term>Ternary compounds</term>
<term>Thulium additions</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Photoluminescence</term>
<term>Fluorescence</term>
<term>Matériau dopé</term>
<term>Codopage</term>
<term>Addition dysprosium</term>
<term>Addition thulium</term>
<term>Transfert énergie</term>
<term>Durée vie</term>
<term>Transition niveau énergie</term>
<term>Recouvrement raie spectrale</term>
<term>Déclin luminescence</term>
<term>Paire accepteur donneur</term>
<term>Etude expérimentale</term>
<term>Verre chalcogénure</term>
<term>Composé ternaire</term>
<term>Germanium sulfure</term>
<term>Gallium sulfure</term>
<term>7855H</term>
<term>Ge25Ga5S70:Dy Tm</term>
<term>Ga Ge S</term>
</keywords>
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<front><div type="abstract" xml:lang="en">Copyright (c) 1997  Elsevier Science B.V. All rights reserved. Energy transfer mechanisms and the effect of Tm<sup>3+</sup>
 addition on the intensity of the Dy<sup>3+</sup>
:2.9 μm emission from Ge<sub>25</sub>
Ga<sub>5</sub>
S<sub>70</sub>
 glass were investigated. Intensity of the 2.9 μm fluorescence from Dy<sup>3+</sup>
 increased with increasing Tm<sup>3+</sup>
 content when the Dy<sup>3+</sup>
 concentration remained constant, which indicates the presence of an efficient energy transfer between Tm<sup>3+</sup>
 and Dy<sup>3+</sup>
. A decrease in the measured lifetimes of the Tm<sup>3+</sup>
:<sup>3</sup>
F<sub>4</sub>
 level and a wide spectral overlap between the Tm<sup>3+</sup>
:1.8 μm emission and the absorption of Dy<sup>3+</sup>
:<sup>6</sup>
H<sub>15/2</sub>
→<sup>6</sup>
H<sub>11/2</sub>
 also supported the proposed energy transfer scheme. Analyses of the emission intensities and decay times suggested that a direct energy transfer from the Tm<sup>3+</sup>
:<sup>3</sup>
F<sub>4</sub>
 level to Dy<sup>3+</sup>
:<sup>6</sup>
H<sub>11/2</sub>
 level occurred after a fast diffusion-limited migration of the excitation energy among Tm<sup>3+</sup>
.</div>
</front>
</TEI>
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</fA05>
<fA06><s2>2-3</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Sensitizing effect of Tm<sup>3+</sup>
 on 2.9 μm emission from Dy<sup>3+</sup>
-doped Ge<sub>25</sub>
Ga<sub>5</sub>
S<sub>70</sub>
 glass</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>HEO (J.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>CHO (W. Y.)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>CHUNG (W. J.)</s1>
</fA11>
<fA14 i1="01"><s1>Non-Crystalline Materials Laboratory, Department of Materials Science and Engineering, Pohang University of Science and Technology</s1>
<s2>Pohang</s2>
<s3>KOR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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</fA23>
<fA24 i1="01"><s0>eng</s0>
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<fA47 i1="01" i2="1"><s0>97-0326175</s0>
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<fA60><s1>P</s1>
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<fA66 i1="01"><s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>Copyright (c) 1997  Elsevier Science B.V. All rights reserved. Energy transfer mechanisms and the effect of Tm<sup>3+</sup>
 addition on the intensity of the Dy<sup>3+</sup>
:2.9 μm emission from Ge<sub>25</sub>
Ga<sub>5</sub>
S<sub>70</sub>
 glass were investigated. Intensity of the 2.9 μm fluorescence from Dy<sup>3+</sup>
 increased with increasing Tm<sup>3+</sup>
 content when the Dy<sup>3+</sup>
 concentration remained constant, which indicates the presence of an efficient energy transfer between Tm<sup>3+</sup>
 and Dy<sup>3+</sup>
. A decrease in the measured lifetimes of the Tm<sup>3+</sup>
:<sup>3</sup>
F<sub>4</sub>
 level and a wide spectral overlap between the Tm<sup>3+</sup>
:1.8 μm emission and the absorption of Dy<sup>3+</sup>
:<sup>6</sup>
H<sub>15/2</sub>
→<sup>6</sup>
H<sub>11/2</sub>
 also supported the proposed energy transfer scheme. Analyses of the emission intensities and decay times suggested that a direct energy transfer from the Tm<sup>3+</sup>
:<sup>3</sup>
F<sub>4</sub>
 level to Dy<sup>3+</sup>
:<sup>6</sup>
H<sub>11/2</sub>
 level occurred after a fast diffusion-limited migration of the excitation energy among Tm<sup>3+</sup>
.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B70H55H</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Photoluminescence</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Photoluminescence</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Fluorescence</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>Fluorescence</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Matériau dopé</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Doped materials</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Codopage</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Codoping</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Codrogado</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Addition dysprosium</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Dysprosium additions</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Addition thulium</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Thulium additions</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Transfert énergie</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Energy transfer</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Durée vie</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Lifetime</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE"><s0>Transition niveau énergie</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG"><s0>Energy-level transitions</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Recouvrement raie spectrale</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Spectral line overlapping</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Recubrimiento raya espectral</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Déclin luminescence</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Luminescence decay</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Decadencia luminiscencia</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Paire accepteur donneur</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Acceptor donor pair</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Par aceptor dador</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG"><s0>Experimental study</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>Verre chalcogénure</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG"><s0>Chalcogenide glasses</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE"><s0>Composé ternaire</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG"><s0>Ternary compounds</s0>
<s5>15</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE"><s0>Germanium sulfure</s0>
<s2>NK</s2>
<s5>17</s5>
</fC03>
<fC03 i1="16" i2="3" l="ENG"><s0>Germanium sulfides</s0>
<s2>NK</s2>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE"><s0>Gallium sulfure</s0>
<s2>NK</s2>
<s5>18</s5>
</fC03>
<fC03 i1="17" i2="3" l="ENG"><s0>Gallium sulfides</s0>
<s2>NK</s2>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE"><s0>7855H</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE"><s0>Ge25Ga5S70:Dy Tm</s0>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC03 i1="20" i2="3" l="FRE"><s0>Ga Ge S</s0>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0>
<s5>16</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0>
<s5>16</s5>
</fC07>
<fN21><s1>188</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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Sensitizing effect of Tm3+ on 2.9 μm emission from Dy3+-doped Ge25Ga5S70 glass

Sensitizing effect of Tm3+ on 2.9 μm emission from Dy3+-doped Ge25Ga5S70 glass

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