Photoluminescence of YVO4:Tm phosphor prepared by a polymerizable complex method
Identifieur interne : 000A09 ( Pascal/Curation ); précédent : 000A08; suivant : 000A10Photoluminescence of YVO4:Tm phosphor prepared by a polymerizable complex method
Auteurs : HONGWU ZHANGA [République populaire de Chine] ; XIAOYAN FU [République populaire de Chine] ; SHUYUN NIU [République populaire de Chine] ; GONGQUAN SUN [République populaire de Chine] ; QIN XIN [République populaire de Chine]Source :
- Solid state communications [ 0038-1098 ] ; 2004.
Descripteurs français
- Pascal (Inist)
- Wicri :
- topic : Dopage.
English descriptors
- KwdEn :
Abstract
This paper reports the photoluminescence (PL) properties of nanocrystalline YVO4: Tm phosphor synthesized by the polymerizable complex method based on the Pechini-type reaction. The powder was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), absorption spectroscopy and PL. The results of XRD and TEM show that, high-quality nanopowders with controlled morphology and microstructure were prepared at a relatively low temperature about 700 °C. Upon ultra violet excitation the vanadate host transferred energy to thulium ions efficiently and strong blue emission (475 nm) assigned to 1G4→3H6 transmission is observed. By analyzing excitation and emission spectra of thulium doped yttrium vanadate, we deduced the mechanism of the energy transfer between vanadate host and thulium ions.
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:Tm phosphor prepared by a polymerizable complex method</title>
<author><name sortKey="Hongwu Zhanga" sort="Hongwu Zhanga" uniqKey="Hongwu Zhanga" last="Hongwu Zhanga">HONGWU ZHANGA</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Direct Methanol Fuel Cell Laboratory, Dalian Institute of Chemical Physics, CAS, 457 Zhongshan Road, P.O. Box 110</s1>
<s2>Dalian 116023</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
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<author><name sortKey="Xiaoyan Fu" sort="Xiaoyan Fu" uniqKey="Xiaoyan Fu" last="Xiaoyan Fu">XIAOYAN FU</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Department of Chemistry, Liaoning Normal University</s1>
<s2>Dalian 116029</s2>
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<author><name sortKey="Shuyun Niu" sort="Shuyun Niu" uniqKey="Shuyun Niu" last="Shuyun Niu">SHUYUN NIU</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Department of Chemistry, Liaoning Normal University</s1>
<s2>Dalian 116029</s2>
<s3>CHN</s3>
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<author><name sortKey="Gongquan Sun" sort="Gongquan Sun" uniqKey="Gongquan Sun" last="Gongquan Sun">GONGQUAN SUN</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Direct Methanol Fuel Cell Laboratory, Dalian Institute of Chemical Physics, CAS, 457 Zhongshan Road, P.O. Box 110</s1>
<s2>Dalian 116023</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
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<country>République populaire de Chine</country>
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<author><name sortKey="Qin Xin" sort="Qin Xin" uniqKey="Qin Xin" last="Qin Xin">QIN XIN</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Direct Methanol Fuel Cell Laboratory, Dalian Institute of Chemical Physics, CAS, 457 Zhongshan Road, P.O. Box 110</s1>
<s2>Dalian 116023</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Photoluminescence of YVO<sub>4</sub>
:Tm phosphor prepared by a polymerizable complex method</title>
<author><name sortKey="Hongwu Zhanga" sort="Hongwu Zhanga" uniqKey="Hongwu Zhanga" last="Hongwu Zhanga">HONGWU ZHANGA</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Direct Methanol Fuel Cell Laboratory, Dalian Institute of Chemical Physics, CAS, 457 Zhongshan Road, P.O. Box 110</s1>
<s2>Dalian 116023</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
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<country>République populaire de Chine</country>
</affiliation>
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<author><name sortKey="Xiaoyan Fu" sort="Xiaoyan Fu" uniqKey="Xiaoyan Fu" last="Xiaoyan Fu">XIAOYAN FU</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Department of Chemistry, Liaoning Normal University</s1>
<s2>Dalian 116029</s2>
<s3>CHN</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>République populaire de Chine</country>
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<author><name sortKey="Shuyun Niu" sort="Shuyun Niu" uniqKey="Shuyun Niu" last="Shuyun Niu">SHUYUN NIU</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Department of Chemistry, Liaoning Normal University</s1>
<s2>Dalian 116029</s2>
<s3>CHN</s3>
<sZ>2 aut.</sZ>
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<country>République populaire de Chine</country>
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</author>
<author><name sortKey="Gongquan Sun" sort="Gongquan Sun" uniqKey="Gongquan Sun" last="Gongquan Sun">GONGQUAN SUN</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Direct Methanol Fuel Cell Laboratory, Dalian Institute of Chemical Physics, CAS, 457 Zhongshan Road, P.O. Box 110</s1>
<s2>Dalian 116023</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
</affiliation>
</author>
<author><name sortKey="Qin Xin" sort="Qin Xin" uniqKey="Qin Xin" last="Qin Xin">QIN XIN</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Direct Methanol Fuel Cell Laboratory, Dalian Institute of Chemical Physics, CAS, 457 Zhongshan Road, P.O. Box 110</s1>
<s2>Dalian 116023</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
</affiliation>
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<series><title level="j" type="main">Solid state communications</title>
<title level="j" type="abbreviated">Solid state commun.</title>
<idno type="ISSN">0038-1098</idno>
<imprint><date when="2004">2004</date>
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<seriesStmt><title level="j" type="main">Solid state communications</title>
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<idno type="ISSN">0038-1098</idno>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Absorption spectra</term>
<term>Doping</term>
<term>Energy transfer</term>
<term>Excitation spectrum</term>
<term>Experimental study</term>
<term>Impurities</term>
<term>Microstructure</term>
<term>Nanocrystal</term>
<term>Phosphors</term>
<term>Photoluminescence</term>
<term>Thulium additions</term>
<term>Transmission electron microscopy</term>
<term>XRD</term>
<term>Yttrium Vanadates</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Photoluminescence</term>
<term>Diffraction RX</term>
<term>Microscopie électronique transmission</term>
<term>Spectre absorption</term>
<term>Microstructure</term>
<term>Spectre excitation</term>
<term>Dopage</term>
<term>Impureté</term>
<term>Transfert énergie</term>
<term>Addition thulium</term>
<term>Matériau luminescent</term>
<term>Nanocristal</term>
<term>Yttrium Vanadate</term>
<term>Etude expérimentale</term>
<term>YVO4:Tm</term>
<term>O V Y</term>
<term>7867B</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Dopage</term>
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<front><div type="abstract" xml:lang="en">This paper reports the photoluminescence (PL) properties of nanocrystalline YVO<sub>4</sub>
: Tm phosphor synthesized by the polymerizable complex method based on the Pechini-type reaction. The powder was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), absorption spectroscopy and PL. The results of XRD and TEM show that, high-quality nanopowders with controlled morphology and microstructure were prepared at a relatively low temperature about 700 °C. Upon ultra violet excitation the vanadate host transferred energy to thulium ions efficiently and strong blue emission (475 nm) assigned to <sup>1</sup>
G<sub>4</sub>
→<sup>3</sup>
H<sub>6</sub>
transmission is observed. By analyzing excitation and emission spectra of thulium doped yttrium vanadate, we deduced the mechanism of the energy transfer between vanadate host and thulium ions.</div>
</front>
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:Tm phosphor prepared by a polymerizable complex method</s1>
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<fA11 i1="01" i2="1"><s1>HONGWU ZHANGA</s1>
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<fA11 i1="02" i2="1"><s1>XIAOYAN FU</s1>
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<fA14 i1="01"><s1>Direct Methanol Fuel Cell Laboratory, Dalian Institute of Chemical Physics, CAS, 457 Zhongshan Road, P.O. Box 110</s1>
<s2>Dalian 116023</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Department of Chemistry, Liaoning Normal University</s1>
<s2>Dalian 116029</s2>
<s3>CHN</s3>
<sZ>2 aut.</sZ>
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<fC01 i1="01" l="ENG"><s0>This paper reports the photoluminescence (PL) properties of nanocrystalline YVO<sub>4</sub>
: Tm phosphor synthesized by the polymerizable complex method based on the Pechini-type reaction. The powder was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), absorption spectroscopy and PL. The results of XRD and TEM show that, high-quality nanopowders with controlled morphology and microstructure were prepared at a relatively low temperature about 700 °C. Upon ultra violet excitation the vanadate host transferred energy to thulium ions efficiently and strong blue emission (475 nm) assigned to <sup>1</sup>
G<sub>4</sub>
→<sup>3</sup>
H<sub>6</sub>
transmission is observed. By analyzing excitation and emission spectra of thulium doped yttrium vanadate, we deduced the mechanism of the energy transfer between vanadate host and thulium ions.</s0>
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<s5>02</s5>
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<s5>03</s5>
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<s5>03</s5>
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<s5>04</s5>
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<s5>04</s5>
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<s5>05</s5>
</fC03>
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<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Microstructure</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Microstructure</s0>
<s5>06</s5>
</fC03>
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<s5>07</s5>
</fC03>
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<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Espectro excitación</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Dopage</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Doping</s0>
<s5>08</s5>
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<s5>08</s5>
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<s5>09</s5>
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<s5>09</s5>
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<s5>10</s5>
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<s5>10</s5>
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<s5>11</s5>
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<s5>11</s5>
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<s5>15</s5>
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<s5>15</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Nanocristal</s0>
<s5>16</s5>
</fC03>
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<s5>16</s5>
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<s5>16</s5>
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<fC03 i1="13" i2="3" l="FRE"><s0>Yttrium Vanadate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>17</s5>
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<fC03 i1="13" i2="3" l="ENG"><s0>Yttrium Vanadates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>17</s5>
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<fC03 i1="14" i2="3" l="FRE"><s0>Etude expérimentale</s0>
<s5>18</s5>
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<s5>18</s5>
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<fC03 i1="15" i2="3" l="FRE"><s0>YVO4:Tm</s0>
<s4>INC</s4>
<s5>53</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE"><s0>O V Y</s0>
<s4>INC</s4>
<s5>54</s5>
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<fC03 i1="17" i2="3" l="FRE"><s0>7867B</s0>
<s4>INC</s4>
<s5>56</s5>
</fC03>
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<s5>49</s5>
</fC07>
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<s5>49</s5>
</fC07>
<fN21><s1>334</s1>
</fN21>
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