ThuliumV1, Pascal, Curation, bibRecord, 000771

Energy transfer between Tm3+ and Er3+ ions in a TeO2-based glass pumped at diode laser wavelength

Identifieur interne : 000771 ( Pascal/Curation ); précédent : 000770; suivant : 000772

Energy transfer between Tm3+ and Er3+ ions in a TeO2-based glass pumped at diode laser wavelength

Auteurs : A. B. De Souza [Brésil] ; M. T. De Araujo [Brésil] ; M. V. D. Vermelho [Brésil] ; F. C. Cassanjes [Brésil] ; S. J. L. Ribeiro [Brésil] ; Y. Massaddeq [Brésil]

Source :

Journal of non-crystalline solids [ 0022-3093 ] ; 2007.

RBID : Pascal:07-0293619

Descripteurs français

Pascal (Inist)
- Transfert énergie, Addition thulium, Dopage, Conversion fréquence, Fluorescence, Addition erbium, Transition niveau énergie, Photoluminescence, Equation vitesse, Verre chalcogénure, Tellurite, 7855Q.
Wicri :
- topic : Dopage.

English descriptors

KwdEn :
- Chalcogenide glasses, Doping, Energy transfer, Energy-level transitions, Erbium additions, Fluorescence, Frequency conversion, Photoluminescence, Rate equation, Tellurites, Thulium additions.

Abstract

In this paper we investigate the energy transfer processes in Tm³⁺/Er³⁺ doped telluride glass pumped at the commercial diode laser pump wavelength ∼800 nm. Tailoring the rare-earths content in the glass matrix, seven main energy transfer channels within the doping range considered were identified. A 6-fold enhancement of the Er³⁺ visible frequency upconversion fluorescence at ∼660 nm is observed due to the inclusion of Tm³⁺ ions. This is evidence of the relevant contribution of the route Er₁(⁴I_11/2) + Er₂(⁴I_13/2) → Er₁(⁴I_15/2) + Er₂(⁴F_9/2) to the process. Energy migration among pumped ⁴I_9/2 level reducing the efficiency of the upconversion emission rate (³H_11/2, ⁴S_3/2, and ⁴F_9/2) is observed for Er³⁺ above 1.5 wt%. The rate equations regarding the observed energy transfer routes are determined and a qualitative analysis of the observed processes is reported.

A01	`01`	`1`		`@0 0022-3093`
A02	`01`			`@0 JNCSBJ`
A03		`1`		`@0 J. non-cryst. solids`
A05				`@2 353`
A06				`@2 1`
A08	`01`	`1`	`ENG`	`@1 Energy transfer between Tm³⁺ and Er³⁺ ions in a TeO₂-based glass pumped at diode laser wavelength`
A11	`01`	`1`		`@1 DE SOUZA (A. B.)`
A11	`02`	`1`		`@1 DE ARAUJO (M. T.)`
A11	`03`	`1`		`@1 VERMELHO (M. V. D.)`
A11	`04`	`1`		`@1 CASSANJES (F. C.)`
A11	`05`	`1`		`@1 RIBEIRO (S. J. L.)`
A11	`06`	`1`		`@1 MASSADDEQ (Y.)`
A14	`01`			`@1 Departamento de Física, Universidade Fédéral de Alagoas @2 Maceió, 57072/970, AL @3 BRA @Z 1 aut. @Z 2 aut. @Z 3 aut.`
A14	`02`			`@1 Instituto de Química, UNESP @2 Araraquara, 14800/900, SP @3 BRA @Z 4 aut. @Z 5 aut. @Z 6 aut.`
A20				`@1 94-101`
A21				`@1 2007`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 14572 @5 354000145236590120`
A44				`@0 0000 @1 © 2007 INIST-CNRS. All rights reserved.`
A45				`@0 21 ref.`
A47	`01`	`1`		`@0 07-0293619`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Journal of non-crystalline solids`
A66	`01`			`@0 NLD`
C01	`01`		`ENG`	@0 In this paper we investigate the energy transfer processes in Tm³⁺/Er³⁺ doped telluride glass pumped at the commercial diode laser pump wavelength ∼800 nm. Tailoring the rare-earths content in the glass matrix, seven main energy transfer channels within the doping range considered were identified. A 6-fold enhancement of the Er³⁺ visible frequency upconversion fluorescence at ∼660 nm is observed due to the inclusion of Tm³⁺ ions. This is evidence of the relevant contribution of the route Er₁(⁴I_11/2) + Er₂(⁴I_13/2) → Er₁(⁴I_15/2) + Er₂(⁴F_9/2) to the process. Energy migration among pumped ⁴I_9/2 level reducing the efficiency of the upconversion emission rate (³H_11/2, ⁴S_3/2, and ⁴F_9/2) is observed for Er³⁺ above 1.5 wt%. The rate equations regarding the observed energy transfer routes are determined and a qualitative analysis of the observed processes is reported.
C02	`01`	`3`		`@0 001B70H55Q`
C03	`01`	`3`	`FRE`	`@0 Transfert énergie @5 02`
C03	`01`	`3`	`ENG`	`@0 Energy transfer @5 02`
C03	`02`	`3`	`FRE`	`@0 Addition thulium @5 03`
C03	`02`	`3`	`ENG`	`@0 Thulium additions @5 03`
C03	`03`	`X`	`FRE`	`@0 Dopage @5 04`
C03	`03`	`X`	`ENG`	`@0 Doping @5 04`
C03	`03`	`X`	`SPA`	`@0 Doping @5 04`
C03	`04`	`X`	`FRE`	`@0 Conversion fréquence @5 05`
C03	`04`	`X`	`ENG`	`@0 Frequency conversion @5 05`
C03	`04`	`X`	`SPA`	`@0 Conversión frecuencia @5 05`
C03	`05`	`3`	`FRE`	`@0 Fluorescence @5 06`
C03	`05`	`3`	`ENG`	`@0 Fluorescence @5 06`
C03	`06`	`3`	`FRE`	`@0 Addition erbium @5 07`
C03	`06`	`3`	`ENG`	`@0 Erbium additions @5 07`
C03	`07`	`3`	`FRE`	`@0 Transition niveau énergie @5 08`
C03	`07`	`3`	`ENG`	`@0 Energy-level transitions @5 08`
C03	`08`	`3`	`FRE`	`@0 Photoluminescence @5 09`
C03	`08`	`3`	`ENG`	`@0 Photoluminescence @5 09`
C03	`09`	`X`	`FRE`	`@0 Equation vitesse @5 10`
C03	`09`	`X`	`ENG`	`@0 Rate equation @5 10`
C03	`09`	`X`	`SPA`	`@0 Ecuación velocidad @5 10`
C03	`10`	`3`	`FRE`	`@0 Verre chalcogénure @5 15`
C03	`10`	`3`	`ENG`	`@0 Chalcogenide glasses @5 15`
C03	`11`	`X`	`FRE`	`@0 Tellurite @2 NA @5 16`
C03	`11`	`X`	`ENG`	`@0 Tellurites @2 NA @5 16`
C03	`11`	`X`	`SPA`	`@0 Telurito @2 NA @5 16`
C03	`12`	`3`	`FRE`	`@0 7855Q @4 INC @5 60`
N21				`@1 190`

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Le document en format XML

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 ions in a TeO<sub>2</sub>
-based glass pumped at diode laser wavelength</title>
<author><name sortKey="De Souza, A B" sort="De Souza, A B" uniqKey="De Souza A" first="A. B." last="De Souza">A. B. De Souza</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Energy transfer between Tm<sup>3+</sup>
 and Er<sup>3+</sup>
 ions in a TeO<sub>2</sub>
-based glass pumped at diode laser wavelength</title>
<author><name sortKey="De Souza, A B" sort="De Souza, A B" uniqKey="De Souza A" first="A. B." last="De Souza">A. B. De Souza</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Departamento de Física, Universidade Fédéral de Alagoas</s1>
<s2>Maceió, 57072/970, AL</s2>
<s3>BRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Brésil</country>
</affiliation>
</author>
<author><name sortKey="De Araujo, M T" sort="De Araujo, M T" uniqKey="De Araujo M" first="M. T." last="De Araujo">M. T. De Araujo</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Departamento de Física, Universidade Fédéral de Alagoas</s1>
<s2>Maceió, 57072/970, AL</s2>
<s3>BRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Brésil</country>
</affiliation>
</author>
<author><name sortKey="Vermelho, M V D" sort="Vermelho, M V D" uniqKey="Vermelho M" first="M. V. D." last="Vermelho">M. V. D. Vermelho</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Departamento de Física, Universidade Fédéral de Alagoas</s1>
<s2>Maceió, 57072/970, AL</s2>
<s3>BRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Brésil</country>
</affiliation>
</author>
<author><name sortKey="Cassanjes, F C" sort="Cassanjes, F C" uniqKey="Cassanjes F" first="F. C." last="Cassanjes">F. C. Cassanjes</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Instituto de Química, UNESP</s1>
<s2>Araraquara, 14800/900, SP</s2>
<s3>BRA</s3>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>Brésil</country>
</affiliation>
</author>
<author><name sortKey="Ribeiro, S J L" sort="Ribeiro, S J L" uniqKey="Ribeiro S" first="S. J. L." last="Ribeiro">S. J. L. Ribeiro</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Instituto de Química, UNESP</s1>
<s2>Araraquara, 14800/900, SP</s2>
<s3>BRA</s3>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>Brésil</country>
</affiliation>
</author>
<author><name sortKey="Massaddeq, Y" sort="Massaddeq, Y" uniqKey="Massaddeq Y" first="Y." last="Massaddeq">Y. Massaddeq</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Instituto de Química, UNESP</s1>
<s2>Araraquara, 14800/900, SP</s2>
<s3>BRA</s3>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>Brésil</country>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Journal of non-crystalline solids</title>
<title level="j" type="abbreviated">J. non-cryst. solids</title>
<idno type="ISSN">0022-3093</idno>
<imprint><date when="2007">2007</date>
</imprint>
</series>
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<seriesStmt><title level="j" type="main">Journal of non-crystalline solids</title>
<title level="j" type="abbreviated">J. non-cryst. solids</title>
<idno type="ISSN">0022-3093</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Chalcogenide glasses</term>
<term>Doping</term>
<term>Energy transfer</term>
<term>Energy-level transitions</term>
<term>Erbium additions</term>
<term>Fluorescence</term>
<term>Frequency conversion</term>
<term>Photoluminescence</term>
<term>Rate equation</term>
<term>Tellurites</term>
<term>Thulium additions</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Transfert énergie</term>
<term>Addition thulium</term>
<term>Dopage</term>
<term>Conversion fréquence</term>
<term>Fluorescence</term>
<term>Addition erbium</term>
<term>Transition niveau énergie</term>
<term>Photoluminescence</term>
<term>Equation vitesse</term>
<term>Verre chalcogénure</term>
<term>Tellurite</term>
<term>7855Q</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Dopage</term>
</keywords>
</textClass>
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</teiHeader>
<front><div type="abstract" xml:lang="en">In this paper we investigate the energy transfer processes in Tm<sup>3+</sup>
/Er<sup>3+</sup>
 doped telluride glass pumped at the commercial diode laser pump wavelength ∼800 nm. Tailoring the rare-earths content in the glass matrix, seven main energy transfer channels within the doping range considered were identified. A 6-fold enhancement of the Er<sup>3+</sup>
 visible frequency upconversion fluorescence at ∼660 nm is observed due to the inclusion of Tm<sup>3+</sup>
 ions. This is evidence of the relevant contribution of the route Er<sub>1</sub>
(<sup>4</sup>
I<sub>11/2</sub>
) + Er<sub>2</sub>
(<sup>4</sup>
I<sub>13/2</sub>
) → Er<sub>1</sub>
(<sup>4</sup>
I<sub>15/2</sub>
) + Er<sub>2</sub>
(<sup>4</sup>
F<sub>9/2</sub>
) to the process. Energy migration among pumped <sup>4</sup>
I<sub>9/2</sub>
 level reducing the efficiency of the upconversion emission rate (<sup>3</sup>
H<sub>11/2</sub>
, <sup>4</sup>
S<sub>3/2</sub>
, and <sup>4</sup>
F<sub>9/2</sub>
) is observed for Er<sup>3+</sup>
 above 1.5 wt%. The rate equations regarding the observed energy transfer routes are determined and a qualitative analysis of the observed processes is reported.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0022-3093</s0>
</fA01>
<fA02 i1="01"><s0>JNCSBJ</s0>
</fA02>
<fA03 i2="1"><s0>J. non-cryst. solids</s0>
</fA03>
<fA05><s2>353</s2>
</fA05>
<fA06><s2>1</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Energy transfer between Tm<sup>3+</sup>
 and Er<sup>3+</sup>
 ions in a TeO<sub>2</sub>
-based glass pumped at diode laser wavelength</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>DE SOUZA (A. B.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>DE ARAUJO (M. T.)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>VERMELHO (M. V. D.)</s1>
</fA11>
<fA11 i1="04" i2="1"><s1>CASSANJES (F. C.)</s1>
</fA11>
<fA11 i1="05" i2="1"><s1>RIBEIRO (S. J. L.)</s1>
</fA11>
<fA11 i1="06" i2="1"><s1>MASSADDEQ (Y.)</s1>
</fA11>
<fA14 i1="01"><s1>Departamento de Física, Universidade Fédéral de Alagoas</s1>
<s2>Maceió, 57072/970, AL</s2>
<s3>BRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Instituto de Química, UNESP</s1>
<s2>Araraquara, 14800/900, SP</s2>
<s3>BRA</s3>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</fA14>
<fA20><s1>94-101</s1>
</fA20>
<fA21><s1>2007</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>14572</s2>
<s5>354000145236590120</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2007 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>21 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>07-0293619</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Journal of non-crystalline solids</s0>
</fA64>
<fA66 i1="01"><s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>In this paper we investigate the energy transfer processes in Tm<sup>3+</sup>
/Er<sup>3+</sup>
 doped telluride glass pumped at the commercial diode laser pump wavelength ∼800 nm. Tailoring the rare-earths content in the glass matrix, seven main energy transfer channels within the doping range considered were identified. A 6-fold enhancement of the Er<sup>3+</sup>
 visible frequency upconversion fluorescence at ∼660 nm is observed due to the inclusion of Tm<sup>3+</sup>
 ions. This is evidence of the relevant contribution of the route Er<sub>1</sub>
(<sup>4</sup>
I<sub>11/2</sub>
) + Er<sub>2</sub>
(<sup>4</sup>
I<sub>13/2</sub>
) → Er<sub>1</sub>
(<sup>4</sup>
I<sub>15/2</sub>
) + Er<sub>2</sub>
(<sup>4</sup>
F<sub>9/2</sub>
) to the process. Energy migration among pumped <sup>4</sup>
I<sub>9/2</sub>
 level reducing the efficiency of the upconversion emission rate (<sup>3</sup>
H<sub>11/2</sub>
, <sup>4</sup>
S<sub>3/2</sub>
, and <sup>4</sup>
F<sub>9/2</sub>
) is observed for Er<sup>3+</sup>
 above 1.5 wt%. The rate equations regarding the observed energy transfer routes are determined and a qualitative analysis of the observed processes is reported.</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B70H55Q</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE"><s0>Transfert énergie</s0>
<s5>02</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG"><s0>Energy transfer</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Addition thulium</s0>
<s5>03</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>Thulium additions</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Dopage</s0>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Doping</s0>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Doping</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Conversion fréquence</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Frequency conversion</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Conversión frecuencia</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Fluorescence</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Fluorescence</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE"><s0>Addition erbium</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG"><s0>Erbium additions</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Transition niveau énergie</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Energy-level transitions</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Photoluminescence</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Photoluminescence</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Equation vitesse</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Rate equation</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Ecuación velocidad</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Verre chalcogénure</s0>
<s5>15</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Chalcogenide glasses</s0>
<s5>15</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Tellurite</s0>
<s2>NA</s2>
<s5>16</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Tellurites</s0>
<s2>NA</s2>
<s5>16</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Telurito</s0>
<s2>NA</s2>
<s5>16</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE"><s0>7855Q</s0>
<s4>INC</s4>
<s5>60</s5>
</fC03>
<fN21><s1>190</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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Energy transfer between Tm3+ and Er3+ ions in a TeO2-based glass pumped at diode laser wavelength

Energy transfer between Tm3+ and Er3+ ions in a TeO2-based glass pumped at diode laser wavelength

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