ThuliumV1, Pascal, Curation, bibRecord, 000228

Energy levels and crystal-field analysis of Tm3+ in YAl3(BO3)4 crystals

Identifieur interne : 000228 ( Pascal/Curation ); précédent : 000227; suivant : 000229

Energy levels and crystal-field analysis of Tm3+ in YAl3(BO3)4 crystals

Auteurs : I. Kebaïli [Tunisie] ; M. Dammak [Tunisie] ; E. Cavalli [Italie] ; M. Bettinelli [Italie]

Source :

Journal of luminescence [ 0022-2313 ] ; 2011.

RBID : Pascal:11-0339152

Descripteurs français

Pascal (Inist)
- Niveau énergie, Champ cristallin, Photoluminescence, Spectre absorption, Effet Stark, Dopage, Hamiltonien, Ion libre, Transfert énergie, Addition thulium, Aluminium Yttrium Borate Mixte.
Wicri :
- topic : Dopage.

English descriptors

KwdEn :
- Absorption spectra, Aluminium Yttrium Borates Mixed, Crystal field, Doping, Energy levels, Energy transfer, Free ion, Hamiltonians, Photoluminescence, Stark effect, Thulium additions.

Abstract

The electronic structure of the Tm³⁺ in YAl₃(BO₃)₄ crystals has been investigated by means of low temperature absorption and emission spectroscopy in the 5000-30,000 cm^-1 range. The assignment of the lines composing the observed manifolds to transitions between the Stark levels of Tm³⁺ is is complicated by the presence of extra features having different origins. The energy levels scheme of the doping ion has been compiled after a careful analysis of the spectra by reproducing the observed transitions by means of theoretical calculations based on a Hamiltonian, including the free ion and the crystal field (CF) terms. The agreement between experimental and calculated energy values was reasonably good, the overall r.m.s. deviation being 16 cm^-1. The resulting CF parameters have been tabulated and compared with those reported in literature for other rare earth ions doped in YAB. The analysis of trends observed along the lanthanide series evidences some inconsistencies and the necessity of a systematic investigation of these systems.

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A02	`01`			`@0 JLUMA8`
A03		`1`		`@0 J. lumin.`
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A08	`01`	`1`	`ENG`	`@1 Energy levels and crystal-field analysis of Tm³⁺ in YAl₃(BO₃)₄ crystals`
A11	`01`	`1`		`@1 KEBAÏLI (I.)`
A11	`02`	`1`		`@1 DAMMAK (M.)`
A11	`03`	`1`		`@1 CAVALLI (E.)`
A11	`04`	`1`		`@1 BETTINELLI (M.)`
A14	`01`			`@1 Universite de Sfax, Faculté des Sciences de Sfax, Département de Physique, Laboratoire de Physique Appliquée, Groupe de physique théorique @2 Sfax @3 TUN @Z 1 aut. @Z 2 aut.`
A14	`02`			`@1 Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica e Chimica Fisica, Università di Parma @2 Parma @3 ITA @Z 3 aut.`
A14	`03`			`@1 Laboratory of Solid State Chemistry, Department of Biotechnology, Università di Verona, INSTN, UdR Verona @2 Verona @3 ITA @Z 4 aut.`
A20				`@1 2010-2015`
A21				`@1 2011`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 14666 @5 354000191085630310`
A44				`@0 0000 @1 © 2011 INIST-CNRS. All rights reserved.`
A45				`@0 25 ref.`
A47	`01`	`1`		`@0 11-0339152`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Journal of luminescence`
A66	`01`			`@0 NLD`
C01	`01`		`ENG`	@0 The electronic structure of the Tm³⁺ in YAl₃(BO₃)₄ crystals has been investigated by means of low temperature absorption and emission spectroscopy in the 5000-30,000 cm^-1 range. The assignment of the lines composing the observed manifolds to transitions between the Stark levels of Tm³⁺ is is complicated by the presence of extra features having different origins. The energy levels scheme of the doping ion has been compiled after a careful analysis of the spectra by reproducing the observed transitions by means of theoretical calculations based on a Hamiltonian, including the free ion and the crystal field (CF) terms. The agreement between experimental and calculated energy values was reasonably good, the overall r.m.s. deviation being 16 cm^-1. The resulting CF parameters have been tabulated and compared with those reported in literature for other rare earth ions doped in YAB. The analysis of trends observed along the lanthanide series evidences some inconsistencies and the necessity of a systematic investigation of these systems.
C02	`01`	`3`		`@0 001B70H55H`
C03	`01`	`3`	`FRE`	`@0 Niveau énergie @5 02`
C03	`01`	`3`	`ENG`	`@0 Energy levels @5 02`
C03	`02`	`3`	`FRE`	`@0 Champ cristallin @5 03`
C03	`02`	`3`	`ENG`	`@0 Crystal field @5 03`
C03	`03`	`3`	`FRE`	`@0 Photoluminescence @5 04`
C03	`03`	`3`	`ENG`	`@0 Photoluminescence @5 04`
C03	`04`	`3`	`FRE`	`@0 Spectre absorption @5 05`
C03	`04`	`3`	`ENG`	`@0 Absorption spectra @5 05`
C03	`05`	`3`	`FRE`	`@0 Effet Stark @5 06`
C03	`05`	`3`	`ENG`	`@0 Stark effect @5 06`
C03	`06`	`X`	`FRE`	`@0 Dopage @5 07`
C03	`06`	`X`	`ENG`	`@0 Doping @5 07`
C03	`06`	`X`	`SPA`	`@0 Doping @5 07`
C03	`07`	`3`	`FRE`	`@0 Hamiltonien @5 08`
C03	`07`	`3`	`ENG`	`@0 Hamiltonians @5 08`
C03	`08`	`X`	`FRE`	`@0 Ion libre @5 09`
C03	`08`	`X`	`ENG`	`@0 Free ion @5 09`
C03	`08`	`X`	`SPA`	`@0 Ión libre @5 09`
C03	`09`	`3`	`FRE`	`@0 Transfert énergie @5 11`
C03	`09`	`3`	`ENG`	`@0 Energy transfer @5 11`
C03	`10`	`3`	`FRE`	`@0 Addition thulium @5 12`
C03	`10`	`3`	`ENG`	`@0 Thulium additions @5 12`
C03	`11`	`X`	`FRE`	`@0 Aluminium Yttrium Borate Mixte @2 NC @2 NA @5 15`
C03	`11`	`X`	`ENG`	`@0 Aluminium Yttrium Borates Mixed @2 NC @2 NA @5 15`
C03	`11`	`X`	`SPA`	`@0 Mixto @2 NC @2 NA @5 15`
N21				`@1 234`

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Le document en format XML

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 crystals</title>
<author><name sortKey="Kebaili, I" sort="Kebaili, I" uniqKey="Kebaili I" first="I." last="Kebaïli">I. Kebaïli</name>
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 in YAl<sub>3</sub>
(BO<sub>3</sub>
)<sub>4</sub>
 crystals</title>
<author><name sortKey="Kebaili, I" sort="Kebaili, I" uniqKey="Kebaili I" first="I." last="Kebaïli">I. Kebaïli</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Universite de Sfax, Faculté des Sciences de Sfax, Département de Physique, Laboratoire de Physique Appliquée, Groupe de physique théorique</s1>
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<author><name sortKey="Cavalli, E" sort="Cavalli, E" uniqKey="Cavalli E" first="E." last="Cavalli">E. Cavalli</name>
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<s3>ITA</s3>
<sZ>3 aut.</sZ>
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<country>Italie</country>
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</author>
<author><name sortKey="Bettinelli, M" sort="Bettinelli, M" uniqKey="Bettinelli M" first="M." last="Bettinelli">M. Bettinelli</name>
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<series><title level="j" type="main">Journal of luminescence</title>
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<seriesStmt><title level="j" type="main">Journal of luminescence</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Absorption spectra</term>
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<term>Energy levels</term>
<term>Energy transfer</term>
<term>Free ion</term>
<term>Hamiltonians</term>
<term>Photoluminescence</term>
<term>Stark effect</term>
<term>Thulium additions</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Niveau énergie</term>
<term>Champ cristallin</term>
<term>Photoluminescence</term>
<term>Spectre absorption</term>
<term>Effet Stark</term>
<term>Dopage</term>
<term>Hamiltonien</term>
<term>Ion libre</term>
<term>Transfert énergie</term>
<term>Addition thulium</term>
<term>Aluminium Yttrium Borate Mixte</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Dopage</term>
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<front><div type="abstract" xml:lang="en">The electronic structure of the Tm<sup>3+</sup>
 in YAl<sub>3</sub>
(BO<sub>3</sub>
)<sub>4</sub>
 crystals has been investigated by means of low temperature absorption and emission spectroscopy in the 5000-30,000 cm<sup>-1</sup>
 range. The assignment of the lines composing the observed manifolds to transitions between the Stark levels of Tm<sup>3+</sup>
 is is complicated by the presence of extra features having different origins. The energy levels scheme of the doping ion has been compiled after a careful analysis of the spectra by reproducing the observed transitions by means of theoretical calculations based on a Hamiltonian, including the free ion and the crystal field (CF) terms. The agreement between experimental and calculated energy values was reasonably good, the overall r.m.s. deviation being 16 cm<sup>-1</sup>
. The resulting CF parameters have been tabulated and compared with those reported in literature for other rare earth ions doped in YAB. The analysis of trends observed along the lanthanide series evidences some inconsistencies and the necessity of a systematic investigation of these systems.</div>
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 crystals</s1>
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<fA11 i1="01" i2="1"><s1>KEBAÏLI (I.)</s1>
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<fA14 i1="01"><s1>Universite de Sfax, Faculté des Sciences de Sfax, Département de Physique, Laboratoire de Physique Appliquée, Groupe de physique théorique</s1>
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<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<fA14 i1="02"><s1>Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica e Chimica Fisica, Università di Parma</s1>
<s2>Parma</s2>
<s3>ITA</s3>
<sZ>3 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>Laboratory of Solid State Chemistry, Department of Biotechnology, Università di Verona, INSTN, UdR Verona</s1>
<s2>Verona</s2>
<s3>ITA</s3>
<sZ>4 aut.</sZ>
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<fC01 i1="01" l="ENG"><s0>The electronic structure of the Tm<sup>3+</sup>
 in YAl<sub>3</sub>
(BO<sub>3</sub>
)<sub>4</sub>
 crystals has been investigated by means of low temperature absorption and emission spectroscopy in the 5000-30,000 cm<sup>-1</sup>
 range. The assignment of the lines composing the observed manifolds to transitions between the Stark levels of Tm<sup>3+</sup>
 is is complicated by the presence of extra features having different origins. The energy levels scheme of the doping ion has been compiled after a careful analysis of the spectra by reproducing the observed transitions by means of theoretical calculations based on a Hamiltonian, including the free ion and the crystal field (CF) terms. The agreement between experimental and calculated energy values was reasonably good, the overall r.m.s. deviation being 16 cm<sup>-1</sup>
. The resulting CF parameters have been tabulated and compared with those reported in literature for other rare earth ions doped in YAB. The analysis of trends observed along the lanthanide series evidences some inconsistencies and the necessity of a systematic investigation of these systems.</s0>
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<s5>03</s5>
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<fC03 i1="02" i2="3" l="ENG"><s0>Crystal field</s0>
<s5>03</s5>
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<fC03 i1="03" i2="3" l="FRE"><s0>Photoluminescence</s0>
<s5>04</s5>
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<s5>04</s5>
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<fC03 i1="04" i2="3" l="FRE"><s0>Spectre absorption</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Absorption spectra</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Effet Stark</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>Stark effect</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Dopage</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Doping</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Doping</s0>
<s5>07</s5>
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<fC03 i1="07" i2="3" l="FRE"><s0>Hamiltonien</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Hamiltonians</s0>
<s5>08</s5>
</fC03>
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<s5>09</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Free ion</s0>
<s5>09</s5>
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<s5>09</s5>
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<s5>11</s5>
</fC03>
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<s5>11</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Addition thulium</s0>
<s5>12</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Thulium additions</s0>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Aluminium Yttrium Borate Mixte</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>15</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Aluminium Yttrium Borates Mixed</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>15</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Mixto</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>15</s5>
</fC03>
<fN21><s1>234</s1>
</fN21>
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Energy levels and crystal-field analysis of Tm3+ in YAl3(BO3)4 crystals

Energy levels and crystal-field analysis of Tm3+ in YAl3(BO3)4 crystals

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Descripteurs français

English descriptors

Abstract

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