ThuliumV1, Pascal, Curation, bibRecord, 000186

Emission analysis of Pr3+ and Tm3+: Ca2Gd2W3O14 phosphors

Identifieur interne : 000186 ( Pascal/Curation ); précédent : 000185; suivant : 000187

Emission analysis of Pr3+ and Tm3+: Ca2Gd2W3O14 phosphors

Auteurs : S. Sailaja [Inde] ; S. J. Dhoble [Inde] ; C. Nageswara Raju [Inde] ; B. Sudhakar Reddy [Inde]

Source :

Physica. B, Condensed matter [ 0921-4526 ] ; 2012.

RBID : Pascal:12-0017319

Descripteurs français

Pascal (Inist)
- Réaction état solide, Photoluminescence, Diffraction RX, Microscopie électronique balayage, Dopage, Spectrométrie dispersive, Addition praséodyme, Addition thulium, Spectrométrie FTIR, Transition niveau énergie, Calcium Gadolinium Tungstate Mixte, Spectre excitation, Transfert charge, Matériau luminescent.
Wicri :
- topic : Dopage.

English descriptors

KwdEn :
- Calcium Gadolinium Tungstates Mixed, Charge transfer, Dispersive spectrometry, Doping, Energy-level transitions, Excitation spectrum, Fourier-transformed infrared spectrometry, Phosphors, Photoluminescence, Praseodymium additions, Scanning electron microscopy, Solid state reaction, Thulium additions, XRD.

Abstract

5 mol% of Pr³⁺ and Tm³⁺ ions activated calcium gadolinium tungstate (Ca₂Gd₂W₃O₁₄) phosphors were synthesized by traditional solid state reaction method. Crystalline phase structure was identified from the X-ray diffraction (XRD) profiles. From the scanning electron microscopy (SEM) images, we have observed the agglomeration of the particles, and average grain size is around 40-300 nm. Using the energy dispersive X-ray analysis (EDAX) and Fourier transform infrared (FTIR) spectra, identified the elements and functional groups present in the prepared phosphors. The emission spectrum of Pr³⁺: Ca₂Gd₂W₃O₁₄ powder phosphors have shown an intense red emission at 615 nm with the excitation wavelength λ_exci=450 nm and thus these red color emitting powder phosphors are used as one of the components in the preparation of WLEDs. The excitation spectrum of Tm³⁺: Ca₂Gd₂W₃O₁₄ powder phosphor has shown a ligand to metal charge transfer (W-O) band (LMCT) within the WO^2-₄ group. Emission spectrum of Tm³⁺: Ca₂Gd₂W₃O₁₄ phosphors have shown blue emissions at 453 nm (¹D₂→³F₄).

A01	`01`	`1`		`@0 0921-4526`
A03		`1`		`@0 Physica, B Condens. matter`
A05				`@2 407`
A06				`@2 1`
A08	`01`	`1`	`ENG`	`@1 Emission analysis of Pr³⁺ and Tm³⁺: Ca₂Gd₂W₃O₁₄ phosphors`
A11	`01`	`1`		`@1 SAILAJA (S.)`
A11	`02`	`1`		`@1 DHOBLE (S. J.)`
A11	`03`	`1`		`@1 NAGESWARA RAJU (C.)`
A11	`04`	`1`		`@1 SUDHAKAR REDDY (B.)`
A14	`01`			`@1 Department of Physics (Research Centre), S.V. Degree College @2 Kadapa 516003 @3 IND @Z 1 aut. @Z 3 aut. @Z 4 aut.`
A14	`02`			`@1 Department of Physics, RTM Nagpur University @2 Nagpur 440 001 @3 IND @Z 2 aut.`
A20				`@1 103-107`
A21				`@1 2012`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 145B @5 354000507342100190`
A44				`@0 0000 @1 © 2012 INIST-CNRS. All rights reserved.`
A45				`@0 23 ref.`
A47	`01`	`1`		`@0 12-0017319`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Physica. B, Condensed matter`
A66	`01`			`@0 GBR`
C01	`01`		`ENG`	@0 5 mol% of Pr³⁺ and Tm³⁺ ions activated calcium gadolinium tungstate (Ca₂Gd₂W₃O₁₄) phosphors were synthesized by traditional solid state reaction method. Crystalline phase structure was identified from the X-ray diffraction (XRD) profiles. From the scanning electron microscopy (SEM) images, we have observed the agglomeration of the particles, and average grain size is around 40-300 nm. Using the energy dispersive X-ray analysis (EDAX) and Fourier transform infrared (FTIR) spectra, identified the elements and functional groups present in the prepared phosphors. The emission spectrum of Pr³⁺: Ca₂Gd₂W₃O₁₄ powder phosphors have shown an intense red emission at 615 nm with the excitation wavelength λ_exci=450 nm and thus these red color emitting powder phosphors are used as one of the components in the preparation of WLEDs. The excitation spectrum of Tm³⁺: Ca₂Gd₂W₃O₁₄ powder phosphor has shown a ligand to metal charge transfer (W-O) band (LMCT) within the WO^2-₄ group. Emission spectrum of Tm³⁺: Ca₂Gd₂W₃O₁₄ phosphors have shown blue emissions at 453 nm (¹D₂→³F₄).
C02	`01`	`3`		`@0 001B70H55H`
C03	`01`	`X`	`FRE`	`@0 Réaction état solide @5 02`
C03	`01`	`X`	`ENG`	`@0 Solid state reaction @5 02`
C03	`01`	`X`	`SPA`	`@0 Reacción estado sólido @5 02`
C03	`02`	`3`	`FRE`	`@0 Photoluminescence @5 03`
C03	`02`	`3`	`ENG`	`@0 Photoluminescence @5 03`
C03	`03`	`3`	`FRE`	`@0 Diffraction RX @5 04`
C03	`03`	`3`	`ENG`	`@0 XRD @5 04`
C03	`04`	`3`	`FRE`	`@0 Microscopie électronique balayage @5 05`
C03	`04`	`3`	`ENG`	`@0 Scanning electron microscopy @5 05`
C03	`05`	`X`	`FRE`	`@0 Dopage @5 06`
C03	`05`	`X`	`ENG`	`@0 Doping @5 06`
C03	`05`	`X`	`SPA`	`@0 Doping @5 06`
C03	`06`	`X`	`FRE`	`@0 Spectrométrie dispersive @5 07`
C03	`06`	`X`	`ENG`	`@0 Dispersive spectrometry @5 07`
C03	`06`	`X`	`SPA`	`@0 Espectrometría dispersiva @5 07`
C03	`07`	`3`	`FRE`	`@0 Addition praséodyme @5 08`
C03	`07`	`3`	`ENG`	`@0 Praseodymium additions @5 08`
C03	`08`	`3`	`FRE`	`@0 Addition thulium @5 09`
C03	`08`	`3`	`ENG`	`@0 Thulium additions @5 09`
C03	`09`	`X`	`FRE`	`@0 Spectrométrie FTIR @5 10`
C03	`09`	`X`	`ENG`	`@0 Fourier-transformed infrared spectrometry @5 10`
C03	`09`	`X`	`SPA`	`@0 Espectrometría FTIR @5 10`
C03	`10`	`3`	`FRE`	`@0 Transition niveau énergie @5 11`
C03	`10`	`3`	`ENG`	`@0 Energy-level transitions @5 11`
C03	`11`	`X`	`FRE`	`@0 Calcium Gadolinium Tungstate Mixte @2 NC @2 NA @5 12`
C03	`11`	`X`	`ENG`	`@0 Calcium Gadolinium Tungstates Mixed @2 NC @2 NA @5 12`
C03	`11`	`X`	`SPA`	`@0 Mixto @2 NC @2 NA @5 12`
C03	`12`	`X`	`FRE`	`@0 Spectre excitation @5 13`
C03	`12`	`X`	`ENG`	`@0 Excitation spectrum @5 13`
C03	`12`	`X`	`SPA`	`@0 Espectro excitación @5 13`
C03	`13`	`X`	`FRE`	`@0 Transfert charge @5 14`
C03	`13`	`X`	`ENG`	`@0 Charge transfer @5 14`
C03	`13`	`X`	`SPA`	`@0 Transferencia carga @5 14`
C03	`14`	`3`	`FRE`	`@0 Matériau luminescent @5 15`
C03	`14`	`3`	`ENG`	`@0 Phosphors @5 15`
N21				`@1 002`

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Le document en format XML

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: Ca<sub>2</sub>
Gd<sub>2</sub>
W<sub>3</sub>
O<sub>14</sub>
 phosphors</title>
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Gd<sub>2</sub>
W<sub>3</sub>
O<sub>14</sub>
 phosphors</title>
<author><name sortKey="Sailaja, S" sort="Sailaja, S" uniqKey="Sailaja S" first="S." last="Sailaja">S. Sailaja</name>
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<author><name sortKey="Dhoble, S J" sort="Dhoble, S J" uniqKey="Dhoble S" first="S. J." last="Dhoble">S. J. Dhoble</name>
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<author><name sortKey="Nageswara Raju, C" sort="Nageswara Raju, C" uniqKey="Nageswara Raju C" first="C." last="Nageswara Raju">C. Nageswara Raju</name>
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<s2>Kadapa 516003</s2>
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<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
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<country>Inde</country>
</affiliation>
</author>
<author><name sortKey="Sudhakar Reddy, B" sort="Sudhakar Reddy, B" uniqKey="Sudhakar Reddy B" first="B." last="Sudhakar Reddy">B. Sudhakar Reddy</name>
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<series><title level="j" type="main">Physica. B, Condensed matter</title>
<title level="j" type="abbreviated">Physica, B Condens. matter</title>
<idno type="ISSN">0921-4526</idno>
<imprint><date when="2012">2012</date>
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<seriesStmt><title level="j" type="main">Physica. B, Condensed matter</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Calcium Gadolinium Tungstates Mixed</term>
<term>Charge transfer</term>
<term>Dispersive spectrometry</term>
<term>Doping</term>
<term>Energy-level transitions</term>
<term>Excitation spectrum</term>
<term>Fourier-transformed infrared spectrometry</term>
<term>Phosphors</term>
<term>Photoluminescence</term>
<term>Praseodymium additions</term>
<term>Scanning electron microscopy</term>
<term>Solid state reaction</term>
<term>Thulium additions</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Réaction état solide</term>
<term>Photoluminescence</term>
<term>Diffraction RX</term>
<term>Microscopie électronique balayage</term>
<term>Dopage</term>
<term>Spectrométrie dispersive</term>
<term>Addition praséodyme</term>
<term>Addition thulium</term>
<term>Spectrométrie FTIR</term>
<term>Transition niveau énergie</term>
<term>Calcium Gadolinium Tungstate Mixte</term>
<term>Spectre excitation</term>
<term>Transfert charge</term>
<term>Matériau luminescent</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Dopage</term>
</keywords>
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<front><div type="abstract" xml:lang="en">5 mol% of Pr<sup>3+</sup>
 and Tm<sup>3+</sup>
 ions activated calcium gadolinium tungstate (Ca<sub>2</sub>
Gd<sub>2</sub>
W<sub>3</sub>
O<sub>14</sub>
) phosphors were synthesized by traditional solid state reaction method. Crystalline phase structure was identified from the X-ray diffraction (XRD) profiles. From the scanning electron microscopy (SEM) images, we have observed the agglomeration of the particles, and average grain size is around 40-300 nm. Using the energy dispersive X-ray analysis (EDAX) and Fourier transform infrared (FTIR) spectra, identified the elements and functional groups present in the prepared phosphors. The emission spectrum of Pr<sup>3+</sup>
: Ca<sub>2</sub>
Gd<sub>2</sub>
W<sub>3</sub>
O<sub>14</sub>
 powder phosphors have shown an intense red emission at 615 nm with the excitation wavelength λ<sub>exci</sub>
=450 nm and thus these red color emitting powder phosphors are used as one of the components in the preparation of WLEDs. The excitation spectrum of Tm<sup>3+</sup>
: Ca<sub>2</sub>
Gd<sub>2</sub>
W<sub>3</sub>
O<sub>14</sub>
 powder phosphor has shown a ligand to metal charge transfer (W-O) band (LMCT) within the WO<sup>2-</sup>
<sub>4</sub>
 group. Emission spectrum of Tm<sup>3+</sup>
: Ca<sub>2</sub>
Gd<sub>2</sub>
W<sub>3</sub>
O<sub>14</sub>
 phosphors have shown blue emissions at 453 nm (<sup>1</sup>
D<sub>2</sub>
→<sup>3</sup>
F<sub>4</sub>
).</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0921-4526</s0>
</fA01>
<fA03 i2="1"><s0>Physica, B Condens. matter</s0>
</fA03>
<fA05><s2>407</s2>
</fA05>
<fA06><s2>1</s2>
</fA06>
<fA08 i1="01" i2="1" l="ENG"><s1>Emission analysis of Pr<sup>3+</sup>
 and Tm<sup>3+</sup>
: Ca<sub>2</sub>
Gd<sub>2</sub>
W<sub>3</sub>
O<sub>14</sub>
 phosphors</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>SAILAJA (S.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>DHOBLE (S. J.)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>NAGESWARA RAJU (C.)</s1>
</fA11>
<fA11 i1="04" i2="1"><s1>SUDHAKAR REDDY (B.)</s1>
</fA11>
<fA14 i1="01"><s1>Department of Physics (Research Centre), S.V. Degree College</s1>
<s2>Kadapa 516003</s2>
<s3>IND</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Department of Physics, RTM Nagpur University</s1>
<s2>Nagpur 440 001</s2>
<s3>IND</s3>
<sZ>2 aut.</sZ>
</fA14>
<fA20><s1>103-107</s1>
</fA20>
<fA21><s1>2012</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>145B</s2>
<s5>354000507342100190</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2012 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>23 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>12-0017319</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
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<fA64 i1="01" i2="1"><s0>Physica. B, Condensed matter</s0>
</fA64>
<fA66 i1="01"><s0>GBR</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>5 mol% of Pr<sup>3+</sup>
 and Tm<sup>3+</sup>
 ions activated calcium gadolinium tungstate (Ca<sub>2</sub>
Gd<sub>2</sub>
W<sub>3</sub>
O<sub>14</sub>
) phosphors were synthesized by traditional solid state reaction method. Crystalline phase structure was identified from the X-ray diffraction (XRD) profiles. From the scanning electron microscopy (SEM) images, we have observed the agglomeration of the particles, and average grain size is around 40-300 nm. Using the energy dispersive X-ray analysis (EDAX) and Fourier transform infrared (FTIR) spectra, identified the elements and functional groups present in the prepared phosphors. The emission spectrum of Pr<sup>3+</sup>
: Ca<sub>2</sub>
Gd<sub>2</sub>
W<sub>3</sub>
O<sub>14</sub>
 powder phosphors have shown an intense red emission at 615 nm with the excitation wavelength λ<sub>exci</sub>
=450 nm and thus these red color emitting powder phosphors are used as one of the components in the preparation of WLEDs. The excitation spectrum of Tm<sup>3+</sup>
: Ca<sub>2</sub>
Gd<sub>2</sub>
W<sub>3</sub>
O<sub>14</sub>
 powder phosphor has shown a ligand to metal charge transfer (W-O) band (LMCT) within the WO<sup>2-</sup>
<sub>4</sub>
 group. Emission spectrum of Tm<sup>3+</sup>
: Ca<sub>2</sub>
Gd<sub>2</sub>
W<sub>3</sub>
O<sub>14</sub>
 phosphors have shown blue emissions at 453 nm (<sup>1</sup>
D<sub>2</sub>
→<sup>3</sup>
F<sub>4</sub>
).</s0>
</fC01>
<fC02 i1="01" i2="3"><s0>001B70H55H</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Réaction état solide</s0>
<s5>02</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Solid state reaction</s0>
<s5>02</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Reacción estado sólido</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE"><s0>Photoluminescence</s0>
<s5>03</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG"><s0>Photoluminescence</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Diffraction RX</s0>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>XRD</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="3" l="FRE"><s0>Microscopie électronique balayage</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="3" l="ENG"><s0>Scanning electron microscopy</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Dopage</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Doping</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Doping</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Spectrométrie dispersive</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Dispersive spectrometry</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Espectrometría dispersiva</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE"><s0>Addition praséodyme</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG"><s0>Praseodymium additions</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE"><s0>Addition thulium</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG"><s0>Thulium additions</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Spectrométrie FTIR</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Fourier-transformed infrared spectrometry</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Espectrometría FTIR</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE"><s0>Transition niveau énergie</s0>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG"><s0>Energy-level transitions</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Calcium Gadolinium Tungstate Mixte</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Calcium Gadolinium Tungstates Mixed</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Mixto</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Spectre excitation</s0>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Excitation spectrum</s0>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Espectro excitación</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Transfert charge</s0>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Charge transfer</s0>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Transferencia carga</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE"><s0>Matériau luminescent</s0>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG"><s0>Phosphors</s0>
<s5>15</s5>
</fC03>
<fN21><s1>002</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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Emission analysis of Pr3+ and Tm3+: Ca2Gd2W3O14 phosphors

Emission analysis of Pr3+ and Tm3+: Ca2Gd2W3O14 phosphors

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