ThuliumV1, Pascal, Curation, bibRecord, 000120

Luminescence and upconversion from thulium(III) species in solution

Identifieur interne : 000120 ( Pascal/Curation ); précédent : 000119; suivant : 000121

Luminescence and upconversion from thulium(III) species in solution

Auteurs : Octavia A. Blackburn [Royaume-Uni] ; Manuel Tropiano [Royaume-Uni] ; Thomas Just S Rensen [Royaume-Uni, Danemark] ; James Thom [Royaume-Uni] ; Andrew Beeby [Royaume-Uni] ; Lisa M. Bushby [Royaume-Uni] ; David Parker [Royaume-Uni] ; Louise S. Natrajan [Royaume-Uni] ; Stephen Faulkner [Royaume-Uni]

Source :

PCCP. Physical chemistry chemical physics : (Print) [ 1463-9076 ] ; 2012.

RBID : Pascal:12-0430416

Descripteurs français

Pascal (Inist)
- Luminescence, Thulium, Complexe de thulium, Etat excité, Transfert énergie, Energie, Chromophore, Structure, Photon, Excitation, Spectre excitation, Séquentiel, Optique quantique, Absorption photon, Relaxation.

English descriptors

KwdEn :
- Chromophore, Energy, Energy transfer, Excitation, Excitation spectrum, Excited state, Luminescence, Photon, Photon absorption, Quantum optics, Relaxation, Sequential, Structure, Thulium, Thulium complex.

Abstract

Thulium salts and complexes are shown to be emissive from three states in the excited state manifold of Tm³⁺. Formation of the ¹D₂ state can result in luminescence, or in energy transfer to the lower energy ¹G₄ and ³H₄ emissive states. Where chromophores are present in the ligand structure, emission is restricted to thulium centred emissive states that are lower in energy than the chromophore centred donor state. We have also observed direct multi-photon excitation of the thulium excited state manifold. Furthermore, additional transitions are observed in the multi-photon excitation spectra that are consistent with upconversion as a consequence of sequential single photon absorption and relaxation processes within the thulium excited state manifold.

A01	`01`	`1`		`@0 1463-9076`
A03		`1`		`@0 PCCP, Phys. chem. chem. phys. : (Print)`
A05				`@2 14`
A06				`@2 38`
A08	`01`	`1`	`ENG`	`@1 Luminescence and upconversion from thulium(III) species in solution`
A11	`01`	`1`		`@1 BLACKBURN (Octavia A.)`
A11	`02`	`1`		`@1 TROPIANO (Manuel)`
A11	`03`	`1`		`@1 JUST SØRENSEN (Thomas)`
A11	`04`	`1`		`@1 THOM (James)`
A11	`05`	`1`		`@1 BEEBY (Andrew)`
A11	`06`	`1`		`@1 BUSHBY (Lisa M.)`
A11	`07`	`1`		`@1 PARKER (David)`
A11	`08`	`1`		`@1 NATRAJAN (Louise S.)`
A11	`09`	`1`		`@1 FAULKNER (Stephen)`
A14	`01`			`@1 Chemistry Research Laboratory, University of Oxford, Mansfield Road @2 Oxford, OX1 3TA @3 GBR @Z 1 aut. @Z 2 aut. @Z 3 aut. @Z 4 aut. @Z 9 aut.`
A14	`02`			`@1 Nano-Science Center & Department of Chemistry, University of Copenhagen, Universitetsparken 5 @2 2100 København Ø @3 DNK @Z 3 aut.`
A14	`03`			`@1 Department of Chemistry, University of Durham, South Road @2 Durham, DH1 3LE @3 GBR @Z 5 aut. @Z 6 aut. @Z 7 aut.`
A14	`04`			`@1 School of Chemistry, University of Manchester, Oxford Road @2 Manchester, M13 9PL @3 GBR @Z 8 aut.`
A20				`@1 13378-13384`
A21				`@1 2012`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 26801 @5 354000508185340320`
A44				`@0 0000 @1 © 2012 INIST-CNRS. All rights reserved.`
A45				`@0 15 ref.`
A47	`01`	`1`		`@0 12-0430416`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 PCCP. Physical chemistry chemical physics : (Print)`
A66	`01`			`@0 GBR`
C01	`01`		`ENG`	@0 Thulium salts and complexes are shown to be emissive from three states in the excited state manifold of Tm³⁺. Formation of the ¹D₂ state can result in luminescence, or in energy transfer to the lower energy ¹G₄ and ³H₄ emissive states. Where chromophores are present in the ligand structure, emission is restricted to thulium centred emissive states that are lower in energy than the chromophore centred donor state. We have also observed direct multi-photon excitation of the thulium excited state manifold. Furthermore, additional transitions are observed in the multi-photon excitation spectra that are consistent with upconversion as a consequence of sequential single photon absorption and relaxation processes within the thulium excited state manifold.
C02	`01`	`X`		`@0 001C01`
C03	`01`	`X`	`FRE`	`@0 Luminescence @5 01`
C03	`01`	`X`	`ENG`	`@0 Luminescence @5 01`
C03	`01`	`X`	`SPA`	`@0 Luminiscencia @5 01`
C03	`02`	`X`	`FRE`	`@0 Thulium @2 NC @5 02`
C03	`02`	`X`	`ENG`	`@0 Thulium @2 NC @5 02`
C03	`02`	`X`	`SPA`	`@0 Tulio @2 NC @5 02`
C03	`03`	`X`	`FRE`	`@0 Complexe de thulium @5 03`
C03	`03`	`X`	`ENG`	`@0 Thulium complex @5 03`
C03	`03`	`X`	`SPA`	`@0 Tulio complejo @5 03`
C03	`04`	`X`	`FRE`	`@0 Etat excité @5 04`
C03	`04`	`X`	`ENG`	`@0 Excited state @5 04`
C03	`04`	`X`	`SPA`	`@0 Estado excitado @5 04`
C03	`05`	`X`	`FRE`	`@0 Transfert énergie @5 05`
C03	`05`	`X`	`ENG`	`@0 Energy transfer @5 05`
C03	`05`	`X`	`SPA`	`@0 Transferencia energía @5 05`
C03	`06`	`X`	`FRE`	`@0 Energie @5 06`
C03	`06`	`X`	`ENG`	`@0 Energy @5 06`
C03	`06`	`X`	`SPA`	`@0 Energía @5 06`
C03	`07`	`X`	`FRE`	`@0 Chromophore @5 07`
C03	`07`	`X`	`ENG`	`@0 Chromophore @5 07`
C03	`07`	`X`	`SPA`	`@0 Cromóforo @5 07`
C03	`08`	`X`	`FRE`	`@0 Structure @5 08`
C03	`08`	`X`	`ENG`	`@0 Structure @5 08`
C03	`08`	`X`	`SPA`	`@0 Estructura @5 08`
C03	`09`	`X`	`FRE`	`@0 Photon @5 09`
C03	`09`	`X`	`ENG`	`@0 Photon @5 09`
C03	`09`	`X`	`SPA`	`@0 Fotón @5 09`
C03	`10`	`X`	`FRE`	`@0 Excitation @5 10`
C03	`10`	`X`	`ENG`	`@0 Excitation @5 10`
C03	`10`	`X`	`SPA`	`@0 Excitación @5 10`
C03	`11`	`X`	`FRE`	`@0 Spectre excitation @5 11`
C03	`11`	`X`	`ENG`	`@0 Excitation spectrum @5 11`
C03	`11`	`X`	`SPA`	`@0 Espectro excitación @5 11`
C03	`12`	`X`	`FRE`	`@0 Séquentiel @5 12`
C03	`12`	`X`	`ENG`	`@0 Sequential @5 12`
C03	`12`	`X`	`SPA`	`@0 Secuencial @5 12`
C03	`13`	`X`	`FRE`	`@0 Optique quantique @5 13`
C03	`13`	`X`	`ENG`	`@0 Quantum optics @5 13`
C03	`13`	`X`	`SPA`	`@0 Optica cuántica @5 13`
C03	`14`	`X`	`FRE`	`@0 Absorption photon @5 14`
C03	`14`	`X`	`ENG`	`@0 Photon absorption @5 14`
C03	`14`	`X`	`SPA`	`@0 Absorción fotón @5 14`
C03	`15`	`X`	`FRE`	`@0 Relaxation @5 15`
C03	`15`	`X`	`ENG`	`@0 Relaxation @5 15`
C03	`15`	`X`	`SPA`	`@0 Relajación @5 15`
N21				`@1 331`
N44	`01`			`@1 OTO`
N82				`@1 OTO`

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Le document en format XML

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<s2>Manchester, M13 9PL</s2>
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<author><name sortKey="Faulkner, Stephen" sort="Faulkner, Stephen" uniqKey="Faulkner S" first="Stephen" last="Faulkner">Stephen Faulkner</name>
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<s2>Oxford, OX1 3TA</s2>
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<series><title level="j" type="main">PCCP. Physical chemistry chemical physics : (Print)</title>
<title level="j" type="abbreviated">PCCP, Phys. chem. chem. phys. : (Print)</title>
<idno type="ISSN">1463-9076</idno>
<imprint><date when="2012">2012</date>
</imprint>
</series>
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<seriesStmt><title level="j" type="main">PCCP. Physical chemistry chemical physics : (Print)</title>
<title level="j" type="abbreviated">PCCP, Phys. chem. chem. phys. : (Print)</title>
<idno type="ISSN">1463-9076</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Chromophore</term>
<term>Energy</term>
<term>Energy transfer</term>
<term>Excitation</term>
<term>Excitation spectrum</term>
<term>Excited state</term>
<term>Luminescence</term>
<term>Photon</term>
<term>Photon absorption</term>
<term>Quantum optics</term>
<term>Relaxation</term>
<term>Sequential</term>
<term>Structure</term>
<term>Thulium</term>
<term>Thulium complex</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Luminescence</term>
<term>Thulium</term>
<term>Complexe de thulium</term>
<term>Etat excité</term>
<term>Transfert énergie</term>
<term>Energie</term>
<term>Chromophore</term>
<term>Structure</term>
<term>Photon</term>
<term>Excitation</term>
<term>Spectre excitation</term>
<term>Séquentiel</term>
<term>Optique quantique</term>
<term>Absorption photon</term>
<term>Relaxation</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Thulium salts and complexes are shown to be emissive from three states in the excited state manifold of Tm<sup>3+</sup>
. Formation of the <sup>1</sup>
D<sub>2</sub>
 state can result in luminescence, or in energy transfer to the lower energy <sup>1</sup>
G<sub>4</sub>
 and <sup>3</sup>
H<sub>4</sub>
 emissive states. Where chromophores are present in the ligand structure, emission is restricted to thulium centred emissive states that are lower in energy than the chromophore centred donor state. We have also observed direct multi-photon excitation of the thulium excited state manifold. Furthermore, additional transitions are observed in the multi-photon excitation spectra that are consistent with upconversion as a consequence of sequential single photon absorption and relaxation processes within the thulium excited state manifold.</div>
</front>
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</fA08>
<fA11 i1="01" i2="1"><s1>BLACKBURN (Octavia A.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>TROPIANO (Manuel)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>JUST SØRENSEN (Thomas)</s1>
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<fA11 i1="04" i2="1"><s1>THOM (James)</s1>
</fA11>
<fA11 i1="05" i2="1"><s1>BEEBY (Andrew)</s1>
</fA11>
<fA11 i1="06" i2="1"><s1>BUSHBY (Lisa M.)</s1>
</fA11>
<fA11 i1="07" i2="1"><s1>PARKER (David)</s1>
</fA11>
<fA11 i1="08" i2="1"><s1>NATRAJAN (Louise S.)</s1>
</fA11>
<fA11 i1="09" i2="1"><s1>FAULKNER (Stephen)</s1>
</fA11>
<fA14 i1="01"><s1>Chemistry Research Laboratory, University of Oxford, Mansfield Road</s1>
<s2>Oxford, OX1 3TA</s2>
<s3>GBR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>9 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Nano-Science Center & Department of Chemistry, University of Copenhagen, Universitetsparken 5</s1>
<s2>2100 København Ø</s2>
<s3>DNK</s3>
<sZ>3 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>Department of Chemistry, University of Durham, South Road</s1>
<s2>Durham, DH1 3LE</s2>
<s3>GBR</s3>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
<sZ>7 aut.</sZ>
</fA14>
<fA14 i1="04"><s1>School of Chemistry, University of Manchester, Oxford Road</s1>
<s2>Manchester, M13 9PL</s2>
<s3>GBR</s3>
<sZ>8 aut.</sZ>
</fA14>
<fA20><s1>13378-13384</s1>
</fA20>
<fA21><s1>2012</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>26801</s2>
<s5>354000508185340320</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2012 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>15 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>12-0430416</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>PCCP. Physical chemistry chemical physics : (Print)</s0>
</fA64>
<fA66 i1="01"><s0>GBR</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>Thulium salts and complexes are shown to be emissive from three states in the excited state manifold of Tm<sup>3+</sup>
. Formation of the <sup>1</sup>
D<sub>2</sub>
 state can result in luminescence, or in energy transfer to the lower energy <sup>1</sup>
G<sub>4</sub>
 and <sup>3</sup>
H<sub>4</sub>
 emissive states. Where chromophores are present in the ligand structure, emission is restricted to thulium centred emissive states that are lower in energy than the chromophore centred donor state. We have also observed direct multi-photon excitation of the thulium excited state manifold. Furthermore, additional transitions are observed in the multi-photon excitation spectra that are consistent with upconversion as a consequence of sequential single photon absorption and relaxation processes within the thulium excited state manifold.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001C01</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Luminescence</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Luminescence</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Luminiscencia</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Thulium</s0>
<s2>NC</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Thulium</s0>
<s2>NC</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Tulio</s0>
<s2>NC</s2>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Complexe de thulium</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Thulium complex</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Tulio complejo</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Etat excité</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Excited state</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Estado excitado</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Transfert énergie</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Energy transfer</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Transferencia energía</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Energie</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Energy</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Energía</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Chromophore</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Chromophore</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Cromóforo</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Structure</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Structure</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Estructura</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Photon</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Photon</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Fotón</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Excitation</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Excitation</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Excitación</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Spectre excitation</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Excitation spectrum</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Espectro excitación</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Séquentiel</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Sequential</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Secuencial</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Optique quantique</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Quantum optics</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Optica cuántica</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Absorption photon</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG"><s0>Photon absorption</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Absorción fotón</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Relaxation</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG"><s0>Relaxation</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA"><s0>Relajación</s0>
<s5>15</s5>
</fC03>
<fN21><s1>331</s1>
</fN21>
<fN44 i1="01"><s1>OTO</s1>
</fN44>
<fN82><s1>OTO</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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Luminescence and upconversion from thulium(III) species in solution

Luminescence and upconversion from thulium(III) species in solution

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