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Optical spectroscopy of Tm3+ doped in KLa(MoO4)2 crystals

Identifieur interne : 001394 ( Pascal/Corpus ); précédent : 001393; suivant : 001395

Optical spectroscopy of Tm3+ doped in KLa(MoO4)2 crystals

Auteurs : E. Cavalli ; C. Meschini ; A. Toncelli ; M. Tonelli ; M. Bettinelli

Source :

RBID : Pascal:97-0232732

Descripteurs français

English descriptors

Abstract

The optical properties of Tm3+ doped KLa(MoO4)2 single crystals have been measured at various temperatures between 10 and 298 K. All the observed bands are inhomogeneously broadened as an effect of the random distribution of the K+ and La3+ (Tm3+) ions in the scheelite crystal lattice. The intensities of the absorption transitions have been analyzed by means of the Judd-Ofelt theory. The spontaneous transition probability, the branching ratios and the radiative lifetimes have been determined for the most important emitting states using the calculated intensity parameters. They are in good agreement with the experimental results. A structural analysis of the crystal lattice is also reported.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 0022-3697
A03   1    @0 J. phys. chem. solids
A05       @2 58
A06       @2 4
A08 01  1  ENG  @1 Optical spectroscopy of Tm3+ doped in KLa(MoO4)2 crystals
A11 01  1    @1 CAVALLI (E.)
A11 02  1    @1 MESCHINI (C.)
A11 03  1    @1 TONCELLI (A.)
A11 04  1    @1 TONELLI (M.)
A11 05  1    @1 BETTINELLI (M.)
A14 01      @1 Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica e Chimica Fisica, Università di Parma, Viale delle Scienze @2 43100 Parma @3 ITA @Z 1 aut.
A14 02      @1 INFM-Dipartimento di Fisica, Università di Pisa, Piazza Torricelli 2 @2 56100 Pisa @3 ITA @Z 2 aut. @Z 3 aut. @Z 4 aut.
A14 03      @1 Sezione di Chimica, Istituto Policattedra, Facoltà di Scienze MM. FF. NN., Università di Verona, Cà Vignal, Strada Le Grazie @2 37134 Verona @3 ITA @Z 5 aut.
A20       @1 587-595
A21       @1 1997
A23 01      @0 ENG
A43 01      @1 INIST @2 8204 @5 354000064663210080
A44       @0 0000 @1 © 1997 INIST-CNRS. All rights reserved.
A45       @0 16 ref.
A47 01  1    @0 97-0232732
A60       @1 P
A61       @0 A
A64 01  1    @0 The Journal of physics and chemistry of solids
A66 01      @0 GBR
C01 01    ENG  @0 The optical properties of Tm3+ doped KLa(MoO4)2 single crystals have been measured at various temperatures between 10 and 298 K. All the observed bands are inhomogeneously broadened as an effect of the random distribution of the K+ and La3+ (Tm3+) ions in the scheelite crystal lattice. The intensities of the absorption transitions have been analyzed by means of the Judd-Ofelt theory. The spontaneous transition probability, the branching ratios and the radiative lifetimes have been determined for the most important emitting states using the calculated intensity parameters. They are in good agreement with the experimental results. A structural analysis of the crystal lattice is also reported.
C02 01  3    @0 001B70H55H
C02 02  3    @0 001B70H30H
C02 03  3    @0 001B70H40H
C02 04  3    @0 001B70A55H
C03 01  3  FRE  @0 Etude expérimentale @5 01
C03 01  3  ENG  @0 Experimental study @5 01
C03 02  3  FRE  @0 Matériau dopé @5 02
C03 02  3  ENG  @0 Doped materials @5 02
C03 03  3  FRE  @0 Addition thulium @5 03
C03 03  3  ENG  @0 Thulium additions @5 03
C03 04  3  FRE  @0 Monocristal @5 04
C03 04  3  ENG  @0 Monocrystals @5 04
C03 05  3  FRE  @0 Potassium Molybdate @2 NC @2 NA @5 05
C03 05  3  ENG  @0 Potassium Molybdates @2 NC @2 NA @5 05
C03 06  3  FRE  @0 Lanthane Molybdate @2 NC @2 NA @5 06
C03 06  3  ENG  @0 Lanthanum Molybdates @2 NC @2 NA @5 06
C03 07  3  FRE  @0 Composé quaternaire @5 07
C03 07  3  ENG  @0 Quaternary compounds @5 07
C03 08  X  FRE  @0 Effet Judd Ofelt @5 08
C03 08  X  ENG  @0 Judd Ofelt effect @5 08
C03 08  X  SPA  @0 Efecto Judd Ofelt @5 08
C03 09  3  FRE  @0 Spectre absorption @5 09
C03 09  3  ENG  @0 Absorption spectra @5 09
C03 10  3  FRE  @0 Emission spontanée @5 10
C03 10  3  ENG  @0 Spontaneous emission @5 10
C03 11  3  FRE  @0 Luminescence @5 11
C03 11  3  ENG  @0 Luminescence @5 11
C03 12  3  FRE  @0 Rayonnement visible @5 12
C03 12  3  ENG  @0 Visible radiation @5 12
C03 13  3  FRE  @0 Etat impureté @5 13
C03 13  3  ENG  @0 Impurity states @5 13
C03 14  3  FRE  @0 Spectre IR @5 14
C03 14  3  ENG  @0 Infrared spectra @5 14
C03 15  3  FRE  @0 Spectre visible @5 15
C03 15  3  ENG  @0 Visible spectra @5 15
C03 16  3  FRE  @0 7855H @2 PAC @4 INC @5 56
C03 17  3  FRE  @0 7830H @2 PAC @4 INC @5 57
C03 18  3  FRE  @0 7840H @2 PAC @4 INC @5 58
C03 19  3  FRE  @0 7155H @2 PAC @4 INC @5 59
C03 20  3  FRE  @0 KLa(MoO4)2:Tm @4 INC @5 92
C03 21  3  FRE  @0 K La Mo O @4 INC @5 93
C07 01  3  FRE  @0 Composé minéral @5 16
C07 01  3  ENG  @0 Inorganic compounds @5 16
C07 02  3  FRE  @0 Lanthanide composé @5 17
C07 02  3  ENG  @0 Rare earth compounds @5 17
C07 03  3  FRE  @0 Métal transition composé @5 18
C07 03  3  ENG  @0 Transition element compounds @5 18
N21       @1 125

Format Inist (serveur)

NO : PASCAL 97-0232732 INIST
ET : Optical spectroscopy of Tm3+ doped in KLa(MoO4)2 crystals
AU : CAVALLI (E.); MESCHINI (C.); TONCELLI (A.); TONELLI (M.); BETTINELLI (M.)
AF : Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica e Chimica Fisica, Università di Parma, Viale delle Scienze/43100 Parma/Italie (1 aut.); INFM-Dipartimento di Fisica, Università di Pisa, Piazza Torricelli 2/56100 Pisa/Italie (2 aut., 3 aut., 4 aut.); Sezione di Chimica, Istituto Policattedra, Facoltà di Scienze MM. FF. NN., Università di Verona, Cà Vignal, Strada Le Grazie/37134 Verona/Italie (5 aut.)
DT : Publication en série; Niveau analytique
SO : The Journal of physics and chemistry of solids; ISSN 0022-3697; Royaume-Uni; Da. 1997; Vol. 58; No. 4; Pp. 587-595; Bibl. 16 ref.
LA : Anglais
EA : The optical properties of Tm3+ doped KLa(MoO4)2 single crystals have been measured at various temperatures between 10 and 298 K. All the observed bands are inhomogeneously broadened as an effect of the random distribution of the K+ and La3+ (Tm3+) ions in the scheelite crystal lattice. The intensities of the absorption transitions have been analyzed by means of the Judd-Ofelt theory. The spontaneous transition probability, the branching ratios and the radiative lifetimes have been determined for the most important emitting states using the calculated intensity parameters. They are in good agreement with the experimental results. A structural analysis of the crystal lattice is also reported.
CC : 001B70H55H; 001B70H30H; 001B70H40H; 001B70A55H
FD : Etude expérimentale; Matériau dopé; Addition thulium; Monocristal; Potassium Molybdate; Lanthane Molybdate; Composé quaternaire; Effet Judd Ofelt; Spectre absorption; Emission spontanée; Luminescence; Rayonnement visible; Etat impureté; Spectre IR; Spectre visible; 7855H; 7830H; 7840H; 7155H; KLa(MoO4)2:Tm; K La Mo O
FG : Composé minéral; Lanthanide composé; Métal transition composé
ED : Experimental study; Doped materials; Thulium additions; Monocrystals; Potassium Molybdates; Lanthanum Molybdates; Quaternary compounds; Judd Ofelt effect; Absorption spectra; Spontaneous emission; Luminescence; Visible radiation; Impurity states; Infrared spectra; Visible spectra
EG : Inorganic compounds; Rare earth compounds; Transition element compounds
SD : Efecto Judd Ofelt
LO : INIST-8204.354000064663210080
ID : 97-0232732

Links to Exploration step

Pascal:97-0232732

Le document en format XML

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<term>Infrared spectra</term>
<term>Judd Ofelt effect</term>
<term>Lanthanum Molybdates</term>
<term>Luminescence</term>
<term>Monocrystals</term>
<term>Potassium Molybdates</term>
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<term>Spontaneous emission</term>
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<term>Visible radiation</term>
<term>Visible spectra</term>
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<term>Etude expérimentale</term>
<term>Matériau dopé</term>
<term>Addition thulium</term>
<term>Monocristal</term>
<term>Potassium Molybdate</term>
<term>Lanthane Molybdate</term>
<term>Composé quaternaire</term>
<term>Effet Judd Ofelt</term>
<term>Spectre absorption</term>
<term>Emission spontanée</term>
<term>Luminescence</term>
<term>Rayonnement visible</term>
<term>Etat impureté</term>
<term>Spectre IR</term>
<term>Spectre visible</term>
<term>7855H</term>
<term>7830H</term>
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<div type="abstract" xml:lang="en">The optical properties of Tm
<sup>3+</sup>
doped KLa(MoO
<sub>4</sub>
)
<sub>2</sub>
single crystals have been measured at various temperatures between 10 and 298 K. All the observed bands are inhomogeneously broadened as an effect of the random distribution of the K
<sup>+</sup>
and La
<sup>3+</sup>
(Tm
<sup>3+</sup>
) ions in the scheelite crystal lattice. The intensities of the absorption transitions have been analyzed by means of the Judd-Ofelt theory. The spontaneous transition probability, the branching ratios and the radiative lifetimes have been determined for the most important emitting states using the calculated intensity parameters. They are in good agreement with the experimental results. A structural analysis of the crystal lattice is also reported.</div>
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<s1>Optical spectroscopy of Tm
<sup>3+</sup>
doped in KLa(MoO
<sub>4</sub>
)
<sub>2</sub>
crystals</s1>
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<s3>ITA</s3>
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<fA14 i1="02">
<s1>INFM-Dipartimento di Fisica, Università di Pisa, Piazza Torricelli 2</s1>
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<fA66 i1="01">
<s0>GBR</s0>
</fA66>
<fC01 i1="01" l="ENG">
<s0>The optical properties of Tm
<sup>3+</sup>
doped KLa(MoO
<sub>4</sub>
)
<sub>2</sub>
single crystals have been measured at various temperatures between 10 and 298 K. All the observed bands are inhomogeneously broadened as an effect of the random distribution of the K
<sup>+</sup>
and La
<sup>3+</sup>
(Tm
<sup>3+</sup>
) ions in the scheelite crystal lattice. The intensities of the absorption transitions have been analyzed by means of the Judd-Ofelt theory. The spontaneous transition probability, the branching ratios and the radiative lifetimes have been determined for the most important emitting states using the calculated intensity parameters. They are in good agreement with the experimental results. A structural analysis of the crystal lattice is also reported.</s0>
</fC01>
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<s0>Etude expérimentale</s0>
<s5>01</s5>
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<s0>Experimental study</s0>
<s5>01</s5>
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<s0>Matériau dopé</s0>
<s5>02</s5>
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<s0>Doped materials</s0>
<s5>02</s5>
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<s0>Addition thulium</s0>
<s5>03</s5>
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<fC03 i1="03" i2="3" l="ENG">
<s0>Thulium additions</s0>
<s5>03</s5>
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<s0>Monocristal</s0>
<s5>04</s5>
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<s0>Monocrystals</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE">
<s0>Potassium Molybdate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG">
<s0>Potassium Molybdates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE">
<s0>Lanthane Molybdate</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG">
<s0>Lanthanum Molybdates</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE">
<s0>Composé quaternaire</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG">
<s0>Quaternary compounds</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE">
<s0>Effet Judd Ofelt</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG">
<s0>Judd Ofelt effect</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Efecto Judd Ofelt</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE">
<s0>Spectre absorption</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG">
<s0>Absorption spectra</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE">
<s0>Emission spontanée</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG">
<s0>Spontaneous emission</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE">
<s0>Luminescence</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG">
<s0>Luminescence</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE">
<s0>Rayonnement visible</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG">
<s0>Visible radiation</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE">
<s0>Etat impureté</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG">
<s0>Impurity states</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE">
<s0>Spectre IR</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG">
<s0>Infrared spectra</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE">
<s0>Spectre visible</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG">
<s0>Visible spectra</s0>
<s5>15</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE">
<s0>7855H</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE">
<s0>7830H</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE">
<s0>7840H</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>58</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE">
<s0>7155H</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>59</s5>
</fC03>
<fC03 i1="20" i2="3" l="FRE">
<s0>KLa(MoO4)2:Tm</s0>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC03 i1="21" i2="3" l="FRE">
<s0>K La Mo O</s0>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE">
<s0>Composé minéral</s0>
<s5>16</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG">
<s0>Inorganic compounds</s0>
<s5>16</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE">
<s0>Lanthanide composé</s0>
<s5>17</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG">
<s0>Rare earth compounds</s0>
<s5>17</s5>
</fC07>
<fC07 i1="03" i2="3" l="FRE">
<s0>Métal transition composé</s0>
<s5>18</s5>
</fC07>
<fC07 i1="03" i2="3" l="ENG">
<s0>Transition element compounds</s0>
<s5>18</s5>
</fC07>
<fN21>
<s1>125</s1>
</fN21>
</pA>
</standard>
<server>
<NO>PASCAL 97-0232732 INIST</NO>
<ET>Optical spectroscopy of Tm
<sup>3+</sup>
doped in KLa(MoO
<sub>4</sub>
)
<sub>2</sub>
crystals</ET>
<AU>CAVALLI (E.); MESCHINI (C.); TONCELLI (A.); TONELLI (M.); BETTINELLI (M.)</AU>
<AF>Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica e Chimica Fisica, Università di Parma, Viale delle Scienze/43100 Parma/Italie (1 aut.); INFM-Dipartimento di Fisica, Università di Pisa, Piazza Torricelli 2/56100 Pisa/Italie (2 aut., 3 aut., 4 aut.); Sezione di Chimica, Istituto Policattedra, Facoltà di Scienze MM. FF. NN., Università di Verona, Cà Vignal, Strada Le Grazie/37134 Verona/Italie (5 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>The Journal of physics and chemistry of solids; ISSN 0022-3697; Royaume-Uni; Da. 1997; Vol. 58; No. 4; Pp. 587-595; Bibl. 16 ref.</SO>
<LA>Anglais</LA>
<EA>The optical properties of Tm
<sup>3+</sup>
doped KLa(MoO
<sub>4</sub>
)
<sub>2</sub>
single crystals have been measured at various temperatures between 10 and 298 K. All the observed bands are inhomogeneously broadened as an effect of the random distribution of the K
<sup>+</sup>
and La
<sup>3+</sup>
(Tm
<sup>3+</sup>
) ions in the scheelite crystal lattice. The intensities of the absorption transitions have been analyzed by means of the Judd-Ofelt theory. The spontaneous transition probability, the branching ratios and the radiative lifetimes have been determined for the most important emitting states using the calculated intensity parameters. They are in good agreement with the experimental results. A structural analysis of the crystal lattice is also reported.</EA>
<CC>001B70H55H; 001B70H30H; 001B70H40H; 001B70A55H</CC>
<FD>Etude expérimentale; Matériau dopé; Addition thulium; Monocristal; Potassium Molybdate; Lanthane Molybdate; Composé quaternaire; Effet Judd Ofelt; Spectre absorption; Emission spontanée; Luminescence; Rayonnement visible; Etat impureté; Spectre IR; Spectre visible; 7855H; 7830H; 7840H; 7155H; KLa(MoO4)2:Tm; K La Mo O</FD>
<FG>Composé minéral; Lanthanide composé; Métal transition composé</FG>
<ED>Experimental study; Doped materials; Thulium additions; Monocrystals; Potassium Molybdates; Lanthanum Molybdates; Quaternary compounds; Judd Ofelt effect; Absorption spectra; Spontaneous emission; Luminescence; Visible radiation; Impurity states; Infrared spectra; Visible spectra</ED>
<EG>Inorganic compounds; Rare earth compounds; Transition element compounds</EG>
<SD>Efecto Judd Ofelt</SD>
<LO>INIST-8204.354000064663210080</LO>
<ID>97-0232732</ID>
</server>
</inist>
</record>

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