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Yb3+-Er3+-Tm3+ co-doped nano-glass-ceramics tuneable up-conversion phosphor

Identifieur interne : 000610 ( Pascal/Corpus ); précédent : 000609; suivant : 000611

Yb3+-Er3+-Tm3+ co-doped nano-glass-ceramics tuneable up-conversion phosphor

Auteurs : J. Mendez-Ramos ; V. D. Rodriguez ; V. K. Tikhomirov ; J. Del-Castillo ; A. C. Yanes

Source :

RBID : Pascal:08-0427611

Descripteurs français

English descriptors

Abstract

Transparent Yb3+-Er3+-Tm3+ co-doped nano-glass-ceramics have been prepared, 32(SiO2) 9(AlO1.5) 31.5(CdF2) 18.5(PbF2) 5.5(ZnF2): 3.5(Yb-Er-TmF3) mol%, where the co-dopants partition mostly to the fluoride PbF2-based nano-crystals. A comparative study of the up-conversion luminescence in nano-glass-ceramics and its precursor glass indicates that these materials can be used as blue/green/red tuneable up-conversion phosphor, in particular for white light generation. A ratio between blue, green and red emission bands of the Tm3+ and Er3+ can be widely varied with nano-ceramming of the precursor glass and with changing a pump power of luminescence. The change in the ratio between the blue, green and red emission bands is explained to be due to substantial lowering phonon energy and shortening of inter-dopant distances with nano-ceramming of the precursor glass and due to change in the ratio of 2-and 3-photon up-conversion processes with pump power.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 1286-0042
A03   1    @0 EPJ, Appl. phys. : (Print)
A05       @2 43
A06       @2 2
A08 01  1  ENG  @1 Yb3+-Er3+-Tm3+ co-doped nano-glass-ceramics tuneable up-conversion phosphor
A11 01  1    @1 MENDEZ-RAMOS (J.)
A11 02  1    @1 RODRIGUEZ (V. D.)
A11 03  1    @1 TIKHOMIROV (V. K.)
A11 04  1    @1 DEL-CASTILLO (J.)
A11 05  1    @1 YANES (A. C.)
A14 01      @1 Dpto. Física Fundamental y Experimental, Electrónica y Sistemas, Universidad de La Laguna @2 38206 La Laguna, Tenerife @3 ESP @Z 1 aut. @Z 2 aut.
A14 02      @1 Chemistry Department, Katholieke Universiteit Leuven @2 Leuven, 3001 @3 BEL @Z 3 aut.
A14 03      @1 Dpto. Física Bàsica, Universidad de La Laguna @2 38206 La Laguna, Tenerife @3 ESP @Z 4 aut. @Z 5 aut.
A20       @1 149-153
A21       @1 2008
A23 01      @0 ENG
A43 01      @1 INIST @2 26690 @5 354000197431460020
A44       @0 0000 @1 © 2008 INIST-CNRS. All rights reserved.
A45       @0 22 ref.
A47 01  1    @0 08-0427611
A60       @1 P
A61       @0 A
A64 01  1    @0 EPJ. Applied physics : (Print)
A66 01      @0 FRA
C01 01    ENG  @0 Transparent Yb3+-Er3+-Tm3+ co-doped nano-glass-ceramics have been prepared, 32(SiO2) 9(AlO1.5) 31.5(CdF2) 18.5(PbF2) 5.5(ZnF2): 3.5(Yb-Er-TmF3) mol%, where the co-dopants partition mostly to the fluoride PbF2-based nano-crystals. A comparative study of the up-conversion luminescence in nano-glass-ceramics and its precursor glass indicates that these materials can be used as blue/green/red tuneable up-conversion phosphor, in particular for white light generation. A ratio between blue, green and red emission bands of the Tm3+ and Er3+ can be widely varied with nano-ceramming of the precursor glass and with changing a pump power of luminescence. The change in the ratio between the blue, green and red emission bands is explained to be due to substantial lowering phonon energy and shortening of inter-dopant distances with nano-ceramming of the precursor glass and due to change in the ratio of 2-and 3-photon up-conversion processes with pump power.
C02 01  3    @0 001B80A05Z
C02 02  3    @0 001B60A46
C03 01  3  FRE  @0 Conversion fréquence optique @5 01
C03 01  3  ENG  @0 Optical frequency conversion @5 01
C03 02  3  FRE  @0 Luminescence @5 03
C03 02  3  ENG  @0 Luminescence @5 03
C03 03  X  FRE  @0 Lumière blanche @5 37
C03 03  X  ENG  @0 White light @5 37
C03 03  X  SPA  @0 Luz blanca @5 37
C03 04  3  FRE  @0 Spectre émission @5 41
C03 04  3  ENG  @0 Emission spectra @5 41
C03 05  3  FRE  @0 Matériau dopé @5 50
C03 05  3  ENG  @0 Doped materials @5 50
C03 06  X  FRE  @0 Codopage @5 57
C03 06  X  ENG  @0 Codoping @5 57
C03 06  X  SPA  @0 Codrogado @5 57
C03 07  3  FRE  @0 Matériau luminescent @5 58
C03 07  3  ENG  @0 Phosphors @5 58
C03 08  3  FRE  @0 Verre @5 61
C03 08  3  ENG  @0 Glass @5 61
C03 09  3  FRE  @0 Céramique @5 62
C03 09  3  ENG  @0 Ceramics @5 62
C03 10  3  FRE  @0 Addition ytterbium @5 63
C03 10  3  ENG  @0 Ytterbium additions @5 63
C03 11  3  FRE  @0 Addition erbium @5 64
C03 11  3  ENG  @0 Erbium additions @5 64
C03 12  3  FRE  @0 Addition thulium @5 65
C03 12  3  ENG  @0 Thulium additions @5 65
C03 13  3  FRE  @0 SiO2 @4 INC @5 83
C03 14  3  FRE  @0 8105P @4 INC @5 84
C03 15  3  FRE  @0 6146 @4 INC @5 85
C03 16  3  FRE  @0 Upconversion @4 CD @5 96
C03 16  3  ENG  @0 Upconversion @4 CD @5 96
N21       @1 280

Format Inist (serveur)

NO : PASCAL 08-0427611 INIST
ET : Yb3+-Er3+-Tm3+ co-doped nano-glass-ceramics tuneable up-conversion phosphor
AU : MENDEZ-RAMOS (J.); RODRIGUEZ (V. D.); TIKHOMIROV (V. K.); DEL-CASTILLO (J.); YANES (A. C.)
AF : Dpto. Física Fundamental y Experimental, Electrónica y Sistemas, Universidad de La Laguna/38206 La Laguna, Tenerife/Espagne (1 aut., 2 aut.); Chemistry Department, Katholieke Universiteit Leuven/Leuven, 3001/Belgique (3 aut.); Dpto. Física Bàsica, Universidad de La Laguna/38206 La Laguna, Tenerife/Espagne (4 aut., 5 aut.)
DT : Publication en série; Niveau analytique
SO : EPJ. Applied physics : (Print); ISSN 1286-0042; France; Da. 2008; Vol. 43; No. 2; Pp. 149-153; Bibl. 22 ref.
LA : Anglais
EA : Transparent Yb3+-Er3+-Tm3+ co-doped nano-glass-ceramics have been prepared, 32(SiO2) 9(AlO1.5) 31.5(CdF2) 18.5(PbF2) 5.5(ZnF2): 3.5(Yb-Er-TmF3) mol%, where the co-dopants partition mostly to the fluoride PbF2-based nano-crystals. A comparative study of the up-conversion luminescence in nano-glass-ceramics and its precursor glass indicates that these materials can be used as blue/green/red tuneable up-conversion phosphor, in particular for white light generation. A ratio between blue, green and red emission bands of the Tm3+ and Er3+ can be widely varied with nano-ceramming of the precursor glass and with changing a pump power of luminescence. The change in the ratio between the blue, green and red emission bands is explained to be due to substantial lowering phonon energy and shortening of inter-dopant distances with nano-ceramming of the precursor glass and due to change in the ratio of 2-and 3-photon up-conversion processes with pump power.
CC : 001B80A05Z; 001B60A46
FD : Conversion fréquence optique; Luminescence; Lumière blanche; Spectre émission; Matériau dopé; Codopage; Matériau luminescent; Verre; Céramique; Addition ytterbium; Addition erbium; Addition thulium; SiO2; 8105P; 6146; Upconversion
ED : Optical frequency conversion; Luminescence; White light; Emission spectra; Doped materials; Codoping; Phosphors; Glass; Ceramics; Ytterbium additions; Erbium additions; Thulium additions; Upconversion
SD : Luz blanca; Codrogado
LO : INIST-26690.354000197431460020
ID : 08-0427611

Links to Exploration step

Pascal:08-0427611

Le document en format XML

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<term>Glass</term>
<term>Luminescence</term>
<term>Optical frequency conversion</term>
<term>Phosphors</term>
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<term>Codopage</term>
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<div type="abstract" xml:lang="en">Transparent Yb
<sup>3+</sup>
-Er
<sup>3+</sup>
-Tm
<sup>3+</sup>
co-doped nano-glass-ceramics have been prepared, 32(SiO
<sub>2</sub>
) 9(AlO
<sub>1.5</sub>
) 31.5(CdF
<sub>2</sub>
) 18.5(PbF
<sub>2</sub>
) 5.5(ZnF
<sub>2</sub>
): 3.5(Yb-Er-TmF
<sub>3</sub>
) mol%, where the co-dopants partition mostly to the fluoride PbF
<sub>2</sub>
-based nano-crystals. A comparative study of the up-conversion luminescence in nano-glass-ceramics and its precursor glass indicates that these materials can be used as blue/green/red tuneable up-conversion phosphor, in particular for white light generation. A ratio between blue, green and red emission bands of the Tm
<sup>3+</sup>
and Er
<sup>3+</sup>
can be widely varied with nano-ceramming of the precursor glass and with changing a pump power of luminescence. The change in the ratio between the blue, green and red emission bands is explained to be due to substantial lowering phonon energy and shortening of inter-dopant distances with nano-ceramming of the precursor glass and due to change in the ratio of 2-and 3-photon up-conversion processes with pump power.</div>
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-Er
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-Tm
<sup>3+</sup>
co-doped nano-glass-ceramics tuneable up-conversion phosphor</s1>
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<fC01 i1="01" l="ENG">
<s0>Transparent Yb
<sup>3+</sup>
-Er
<sup>3+</sup>
-Tm
<sup>3+</sup>
co-doped nano-glass-ceramics have been prepared, 32(SiO
<sub>2</sub>
) 9(AlO
<sub>1.5</sub>
) 31.5(CdF
<sub>2</sub>
) 18.5(PbF
<sub>2</sub>
) 5.5(ZnF
<sub>2</sub>
): 3.5(Yb-Er-TmF
<sub>3</sub>
) mol%, where the co-dopants partition mostly to the fluoride PbF
<sub>2</sub>
-based nano-crystals. A comparative study of the up-conversion luminescence in nano-glass-ceramics and its precursor glass indicates that these materials can be used as blue/green/red tuneable up-conversion phosphor, in particular for white light generation. A ratio between blue, green and red emission bands of the Tm
<sup>3+</sup>
and Er
<sup>3+</sup>
can be widely varied with nano-ceramming of the precursor glass and with changing a pump power of luminescence. The change in the ratio between the blue, green and red emission bands is explained to be due to substantial lowering phonon energy and shortening of inter-dopant distances with nano-ceramming of the precursor glass and due to change in the ratio of 2-and 3-photon up-conversion processes with pump power.</s0>
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<fC02 i1="02" i2="3">
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<s5>01</s5>
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<s5>01</s5>
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<s5>03</s5>
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<s5>03</s5>
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<s5>37</s5>
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<s5>37</s5>
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<s5>37</s5>
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<s5>41</s5>
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<s5>41</s5>
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<s0>Matériau dopé</s0>
<s5>50</s5>
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<s0>Doped materials</s0>
<s5>50</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE">
<s0>Codopage</s0>
<s5>57</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG">
<s0>Codoping</s0>
<s5>57</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA">
<s0>Codrogado</s0>
<s5>57</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE">
<s0>Matériau luminescent</s0>
<s5>58</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG">
<s0>Phosphors</s0>
<s5>58</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE">
<s0>Verre</s0>
<s5>61</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG">
<s0>Glass</s0>
<s5>61</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE">
<s0>Céramique</s0>
<s5>62</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG">
<s0>Ceramics</s0>
<s5>62</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE">
<s0>Addition ytterbium</s0>
<s5>63</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG">
<s0>Ytterbium additions</s0>
<s5>63</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE">
<s0>Addition erbium</s0>
<s5>64</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG">
<s0>Erbium additions</s0>
<s5>64</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE">
<s0>Addition thulium</s0>
<s5>65</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG">
<s0>Thulium additions</s0>
<s5>65</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE">
<s0>SiO2</s0>
<s4>INC</s4>
<s5>83</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE">
<s0>8105P</s0>
<s4>INC</s4>
<s5>84</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE">
<s0>6146</s0>
<s4>INC</s4>
<s5>85</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE">
<s0>Upconversion</s0>
<s4>CD</s4>
<s5>96</s5>
</fC03>
<fC03 i1="16" i2="3" l="ENG">
<s0>Upconversion</s0>
<s4>CD</s4>
<s5>96</s5>
</fC03>
<fN21>
<s1>280</s1>
</fN21>
</pA>
</standard>
<server>
<NO>PASCAL 08-0427611 INIST</NO>
<ET>Yb
<sup>3+</sup>
-Er
<sup>3+</sup>
-Tm
<sup>3+</sup>
co-doped nano-glass-ceramics tuneable up-conversion phosphor</ET>
<AU>MENDEZ-RAMOS (J.); RODRIGUEZ (V. D.); TIKHOMIROV (V. K.); DEL-CASTILLO (J.); YANES (A. C.)</AU>
<AF>Dpto. Física Fundamental y Experimental, Electrónica y Sistemas, Universidad de La Laguna/38206 La Laguna, Tenerife/Espagne (1 aut., 2 aut.); Chemistry Department, Katholieke Universiteit Leuven/Leuven, 3001/Belgique (3 aut.); Dpto. Física Bàsica, Universidad de La Laguna/38206 La Laguna, Tenerife/Espagne (4 aut., 5 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>EPJ. Applied physics : (Print); ISSN 1286-0042; France; Da. 2008; Vol. 43; No. 2; Pp. 149-153; Bibl. 22 ref.</SO>
<LA>Anglais</LA>
<EA>Transparent Yb
<sup>3+</sup>
-Er
<sup>3+</sup>
-Tm
<sup>3+</sup>
co-doped nano-glass-ceramics have been prepared, 32(SiO
<sub>2</sub>
) 9(AlO
<sub>1.5</sub>
) 31.5(CdF
<sub>2</sub>
) 18.5(PbF
<sub>2</sub>
) 5.5(ZnF
<sub>2</sub>
): 3.5(Yb-Er-TmF
<sub>3</sub>
) mol%, where the co-dopants partition mostly to the fluoride PbF
<sub>2</sub>
-based nano-crystals. A comparative study of the up-conversion luminescence in nano-glass-ceramics and its precursor glass indicates that these materials can be used as blue/green/red tuneable up-conversion phosphor, in particular for white light generation. A ratio between blue, green and red emission bands of the Tm
<sup>3+</sup>
and Er
<sup>3+</sup>
can be widely varied with nano-ceramming of the precursor glass and with changing a pump power of luminescence. The change in the ratio between the blue, green and red emission bands is explained to be due to substantial lowering phonon energy and shortening of inter-dopant distances with nano-ceramming of the precursor glass and due to change in the ratio of 2-and 3-photon up-conversion processes with pump power.</EA>
<CC>001B80A05Z; 001B60A46</CC>
<FD>Conversion fréquence optique; Luminescence; Lumière blanche; Spectre émission; Matériau dopé; Codopage; Matériau luminescent; Verre; Céramique; Addition ytterbium; Addition erbium; Addition thulium; SiO2; 8105P; 6146; Upconversion</FD>
<ED>Optical frequency conversion; Luminescence; White light; Emission spectra; Doped materials; Codoping; Phosphors; Glass; Ceramics; Ytterbium additions; Erbium additions; Thulium additions; Upconversion</ED>
<SD>Luz blanca; Codrogado</SD>
<LO>INIST-26690.354000197431460020</LO>
<ID>08-0427611</ID>
</server>
</inist>
</record>

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