Determination of thermoluminescence kinetic parameters of thulium doped lithium calcium borate
Identifieur interne : 000165 ( Pascal/Corpus ); précédent : 000164; suivant : 000166Determination of thermoluminescence kinetic parameters of thulium doped lithium calcium borate
Auteurs : M. T. Jose ; S. R. Anishia ; O. Annalakshmi ; V. RamasamySource :
- Radiation measurements [ 1350-4487 ] ; 2011.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
For the first time kinetic parameters of thulium doped Lithium calcium borate (LCB) Thermoluminescence (TL) material are reported here. Irradiated LCB:Tm3+ powder has revealed two intense TL glow peaks one at 510 (peak 1) and the other at 660 K (peak 2). Activation energy (E), frequency factor (s) and order of kinetics (b) of these peaks were determined by various heating rate (VHR), initial rise (IR), and peak shape (PS) methods. The trap depth and frequency factor determined for peaks 1 and 2 of LCB:Tm phosphor using VHR and IR methods are in good agreement. The average activation energy of peaks 1 and 2 obtained by these methods is 1.62 and 1.91 eV respectively. The frequency factors of peaks 1 and 2 are in the range of 1013-16 and 1012-14 sec-1 respectively. The E and s values estimated using the glow peak shape dependent parameters are relatively less compared to the values obtained from other methods. The large difference in these values is due to the complex nature of the glow curves. The order of the kinetics process for complex glow curve peaks could not be assigned on the basis of shape parameters alone but Tm response on absorbed dose is to be considered for final confirmation. Glow peaks 1 and 2 of LCB:Tm3+ obey first and general order kinetics respectively.
Notice en format standard (ISO 2709)
Pour connaître la documentation sur le format Inist Standard.
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Format Inist (serveur)
NO : | PASCAL 12-0144695 INIST |
---|---|
ET : | Determination of thermoluminescence kinetic parameters of thulium doped lithium calcium borate |
AU : | JOSE (M. T.); ANISHIA (S. R.); ANNALAKSHMI (O.); RAMASAMY (V.) |
AF : | Radiological Safety Division, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102/Tamil Nadu/Inde (1 aut., 2 aut., 3 aut., 4 aut.); Department of Physics, Annamalai University, Chidambaram/Tamil Nadu/Inde (2 aut., 4 aut.) |
DT : | Publication en série; Niveau analytique |
SO : | Radiation measurements; ISSN 1350-4487; Royaume-Uni; Da. 2011; Vol. 46; No. 10; Pp. 1026-1032; Bibl. 1/4 p. |
LA : | Anglais |
EA : | For the first time kinetic parameters of thulium doped Lithium calcium borate (LCB) Thermoluminescence (TL) material are reported here. Irradiated LCB:Tm3+ powder has revealed two intense TL glow peaks one at 510 (peak 1) and the other at 660 K (peak 2). Activation energy (E), frequency factor (s) and order of kinetics (b) of these peaks were determined by various heating rate (VHR), initial rise (IR), and peak shape (PS) methods. The trap depth and frequency factor determined for peaks 1 and 2 of LCB:Tm phosphor using VHR and IR methods are in good agreement. The average activation energy of peaks 1 and 2 obtained by these methods is 1.62 and 1.91 eV respectively. The frequency factors of peaks 1 and 2 are in the range of 1013-16 and 1012-14 sec-1 respectively. The E and s values estimated using the glow peak shape dependent parameters are relatively less compared to the values obtained from other methods. The large difference in these values is due to the complex nature of the glow curves. The order of the kinetics process for complex glow curve peaks could not be assigned on the basis of shape parameters alone but Tm response on absorbed dose is to be considered for final confirmation. Glow peaks 1 and 2 of LCB:Tm3+ obey first and general order kinetics respectively. |
CC : | 001E01C02; 220C02 |
FD : | Thermoluminescence; Cinétique; Thulium; Lithium; Calcium; Borate; Matériau; Energie activation; Fréquence; Piège; Profondeur |
ED : | thermoluminescence; kinetics; thulium; lithium; calcium; borates; materials; activation energy; frequency; traps; depth |
SD : | Termoluminescencia; Cinética; Tulio; Litio; Calcio; Borato; Energía activación; Frecuencia; Trampa; Profundidad |
LO : | INIST-17536.354000505509050010 |
ID : | 12-0144695 |
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Pascal:12-0144695Le document en format XML
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Determination of thermoluminescence kinetic parameters of thulium doped lithium calcium borate</title>
<author><name sortKey="Jose, M T" sort="Jose, M T" uniqKey="Jose M" first="M. T." last="Jose">M. T. Jose</name>
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<series><title level="j" type="main">Radiation measurements</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>activation energy</term>
<term>borates</term>
<term>calcium</term>
<term>depth</term>
<term>frequency</term>
<term>kinetics</term>
<term>lithium</term>
<term>materials</term>
<term>thermoluminescence</term>
<term>thulium</term>
<term>traps</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Thermoluminescence</term>
<term>Cinétique</term>
<term>Thulium</term>
<term>Lithium</term>
<term>Calcium</term>
<term>Borate</term>
<term>Matériau</term>
<term>Energie activation</term>
<term>Fréquence</term>
<term>Piège</term>
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<front><div type="abstract" xml:lang="en">For the first time kinetic parameters of thulium doped Lithium calcium borate (LCB) Thermoluminescence (TL) material are reported here. Irradiated LCB:Tm<sup>3+</sup>
powder has revealed two intense TL glow peaks one at 510 (peak 1) and the other at 660 K (peak 2). Activation energy (E), frequency factor (s) and order of kinetics (b) of these peaks were determined by various heating rate (VHR), initial rise (IR), and peak shape (PS) methods. The trap depth and frequency factor determined for peaks 1 and 2 of LCB:Tm phosphor using VHR and IR methods are in good agreement. The average activation energy of peaks 1 and 2 obtained by these methods is 1.62 and 1.91 eV respectively. The frequency factors of peaks 1 and 2 are in the range of 10<sup>13-16</sup>
and 10<sup>12-14</sup>
sec<sup>-1</sup>
respectively. The E and s values estimated using the glow peak shape dependent parameters are relatively less compared to the values obtained from other methods. The large difference in these values is due to the complex nature of the glow curves. The order of the kinetics process for complex glow curve peaks could not be assigned on the basis of shape parameters alone but T<sub>m</sub>
response on absorbed dose is to be considered for final confirmation. Glow peaks 1 and 2 of LCB:Tm<sup>3+</sup>
obey first and general order kinetics respectively.</div>
</front>
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<fA08 i1="01" i2="1" l="ENG"><s1>Determination of thermoluminescence kinetic parameters of thulium doped lithium calcium borate</s1>
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<fA11 i1="01" i2="1"><s1>JOSE (M. T.)</s1>
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<fA11 i1="02" i2="1"><s1>ANISHIA (S. R.)</s1>
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<fA11 i1="03" i2="1"><s1>ANNALAKSHMI (O.)</s1>
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<s2>Tamil Nadu</s2>
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<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<fA14 i1="02"><s1>Department of Physics, Annamalai University, Chidambaram</s1>
<s2>Tamil Nadu</s2>
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<sZ>2 aut.</sZ>
<sZ>4 aut.</sZ>
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<fA20><s1>1026-1032</s1>
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<fA66 i1="01"><s0>GBR</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>For the first time kinetic parameters of thulium doped Lithium calcium borate (LCB) Thermoluminescence (TL) material are reported here. Irradiated LCB:Tm<sup>3+</sup>
powder has revealed two intense TL glow peaks one at 510 (peak 1) and the other at 660 K (peak 2). Activation energy (E), frequency factor (s) and order of kinetics (b) of these peaks were determined by various heating rate (VHR), initial rise (IR), and peak shape (PS) methods. The trap depth and frequency factor determined for peaks 1 and 2 of LCB:Tm phosphor using VHR and IR methods are in good agreement. The average activation energy of peaks 1 and 2 obtained by these methods is 1.62 and 1.91 eV respectively. The frequency factors of peaks 1 and 2 are in the range of 10<sup>13-16</sup>
and 10<sup>12-14</sup>
sec<sup>-1</sup>
respectively. The E and s values estimated using the glow peak shape dependent parameters are relatively less compared to the values obtained from other methods. The large difference in these values is due to the complex nature of the glow curves. The order of the kinetics process for complex glow curve peaks could not be assigned on the basis of shape parameters alone but T<sub>m</sub>
response on absorbed dose is to be considered for final confirmation. Glow peaks 1 and 2 of LCB:Tm<sup>3+</sup>
obey first and general order kinetics respectively.</s0>
</fC01>
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</fC02>
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<fC03 i1="01" i2="2" l="FRE"><s0>Thermoluminescence</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="2" l="ENG"><s0>thermoluminescence</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="2" l="SPA"><s0>Termoluminescencia</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="2" l="FRE"><s0>Cinétique</s0>
<s5>02</s5>
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<fC03 i1="02" i2="2" l="ENG"><s0>kinetics</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="2" l="SPA"><s0>Cinética</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="2" l="FRE"><s0>Thulium</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="2" l="ENG"><s0>thulium</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="2" l="SPA"><s0>Tulio</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="2" l="FRE"><s0>Lithium</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="2" l="ENG"><s0>lithium</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="2" l="SPA"><s0>Litio</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="2" l="FRE"><s0>Calcium</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="2" l="ENG"><s0>calcium</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="2" l="SPA"><s0>Calcio</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="2" l="FRE"><s0>Borate</s0>
<s2>NZ</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="2" l="ENG"><s0>borates</s0>
<s2>NZ</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="2" l="SPA"><s0>Borato</s0>
<s2>NZ</s2>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="2" l="FRE"><s0>Matériau</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="2" l="ENG"><s0>materials</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="2" l="FRE"><s0>Energie activation</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="2" l="ENG"><s0>activation energy</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="2" l="SPA"><s0>Energía activación</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="2" l="FRE"><s0>Fréquence</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="2" l="ENG"><s0>frequency</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="2" l="SPA"><s0>Frecuencia</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="2" l="FRE"><s0>Piège</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="2" l="ENG"><s0>traps</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="2" l="SPA"><s0>Trampa</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="2" l="FRE"><s0>Profondeur</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="2" l="ENG"><s0>depth</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="2" l="SPA"><s0>Profundidad</s0>
<s5>11</s5>
</fC03>
<fN21><s1>114</s1>
</fN21>
<fN44 i1="01"><s1>OTO</s1>
</fN44>
<fN82><s1>OTO</s1>
</fN82>
</pA>
</standard>
<server><NO>PASCAL 12-0144695 INIST</NO>
<ET>Determination of thermoluminescence kinetic parameters of thulium doped lithium calcium borate</ET>
<AU>JOSE (M. T.); ANISHIA (S. R.); ANNALAKSHMI (O.); RAMASAMY (V.)</AU>
<AF>Radiological Safety Division, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102/Tamil Nadu/Inde (1 aut., 2 aut., 3 aut., 4 aut.); Department of Physics, Annamalai University, Chidambaram/Tamil Nadu/Inde (2 aut., 4 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Radiation measurements; ISSN 1350-4487; Royaume-Uni; Da. 2011; Vol. 46; No. 10; Pp. 1026-1032; Bibl. 1/4 p.</SO>
<LA>Anglais</LA>
<EA>For the first time kinetic parameters of thulium doped Lithium calcium borate (LCB) Thermoluminescence (TL) material are reported here. Irradiated LCB:Tm<sup>3+</sup>
powder has revealed two intense TL glow peaks one at 510 (peak 1) and the other at 660 K (peak 2). Activation energy (E), frequency factor (s) and order of kinetics (b) of these peaks were determined by various heating rate (VHR), initial rise (IR), and peak shape (PS) methods. The trap depth and frequency factor determined for peaks 1 and 2 of LCB:Tm phosphor using VHR and IR methods are in good agreement. The average activation energy of peaks 1 and 2 obtained by these methods is 1.62 and 1.91 eV respectively. The frequency factors of peaks 1 and 2 are in the range of 10<sup>13-16</sup>
and 10<sup>12-14</sup>
sec<sup>-1</sup>
respectively. The E and s values estimated using the glow peak shape dependent parameters are relatively less compared to the values obtained from other methods. The large difference in these values is due to the complex nature of the glow curves. The order of the kinetics process for complex glow curve peaks could not be assigned on the basis of shape parameters alone but T<sub>m</sub>
response on absorbed dose is to be considered for final confirmation. Glow peaks 1 and 2 of LCB:Tm<sup>3+</sup>
obey first and general order kinetics respectively.</EA>
<CC>001E01C02; 220C02</CC>
<FD>Thermoluminescence; Cinétique; Thulium; Lithium; Calcium; Borate; Matériau; Energie activation; Fréquence; Piège; Profondeur</FD>
<ED>thermoluminescence; kinetics; thulium; lithium; calcium; borates; materials; activation energy; frequency; traps; depth</ED>
<SD>Termoluminescencia; Cinética; Tulio; Litio; Calcio; Borato; Energía activación; Frecuencia; Trampa; Profundidad</SD>
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