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Determination of thermoluminescence kinetic parameters of thulium doped lithium calcium borate

Identifieur interne : 000165 ( Pascal/Corpus ); précédent : 000164; suivant : 000166

Determination of thermoluminescence kinetic parameters of thulium doped lithium calcium borate

Auteurs : M. T. Jose ; S. R. Anishia ; O. Annalakshmi ; V. Ramasamy

Source :

RBID : Pascal:12-0144695

Descripteurs français

English descriptors

Abstract

For the first time kinetic parameters of thulium doped Lithium calcium borate (LCB) Thermoluminescence (TL) material are reported here. Irradiated LCB:Tm3+ powder has revealed two intense TL glow peaks one at 510 (peak 1) and the other at 660 K (peak 2). Activation energy (E), frequency factor (s) and order of kinetics (b) of these peaks were determined by various heating rate (VHR), initial rise (IR), and peak shape (PS) methods. The trap depth and frequency factor determined for peaks 1 and 2 of LCB:Tm phosphor using VHR and IR methods are in good agreement. The average activation energy of peaks 1 and 2 obtained by these methods is 1.62 and 1.91 eV respectively. The frequency factors of peaks 1 and 2 are in the range of 1013-16 and 1012-14 sec-1 respectively. The E and s values estimated using the glow peak shape dependent parameters are relatively less compared to the values obtained from other methods. The large difference in these values is due to the complex nature of the glow curves. The order of the kinetics process for complex glow curve peaks could not be assigned on the basis of shape parameters alone but Tm response on absorbed dose is to be considered for final confirmation. Glow peaks 1 and 2 of LCB:Tm3+ obey first and general order kinetics respectively.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

pA  
A01 01  1    @0 1350-4487
A03   1    @0 Radiat. meas.
A05       @2 46
A06       @2 10
A08 01  1  ENG  @1 Determination of thermoluminescence kinetic parameters of thulium doped lithium calcium borate
A11 01  1    @1 JOSE (M. T.)
A11 02  1    @1 ANISHIA (S. R.)
A11 03  1    @1 ANNALAKSHMI (O.)
A11 04  1    @1 RAMASAMY (V.)
A14 01      @1 Radiological Safety Division, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102 @2 Tamil Nadu @3 IND @Z 1 aut. @Z 2 aut. @Z 3 aut. @Z 4 aut.
A14 02      @1 Department of Physics, Annamalai University, Chidambaram @2 Tamil Nadu @3 IND @Z 2 aut. @Z 4 aut.
A20       @1 1026-1032
A21       @1 2011
A23 01      @0 ENG
A43 01      @1 INIST @2 17536 @5 354000505509050010
A44       @0 0000 @1 © 2012 INIST-CNRS. All rights reserved.
A45       @0 1/4 p.
A47 01  1    @0 12-0144695
A60       @1 P
A61       @0 A
A64 01  1    @0 Radiation measurements
A66 01      @0 GBR
C01 01    ENG  @0 For the first time kinetic parameters of thulium doped Lithium calcium borate (LCB) Thermoluminescence (TL) material are reported here. Irradiated LCB:Tm3+ powder has revealed two intense TL glow peaks one at 510 (peak 1) and the other at 660 K (peak 2). Activation energy (E), frequency factor (s) and order of kinetics (b) of these peaks were determined by various heating rate (VHR), initial rise (IR), and peak shape (PS) methods. The trap depth and frequency factor determined for peaks 1 and 2 of LCB:Tm phosphor using VHR and IR methods are in good agreement. The average activation energy of peaks 1 and 2 obtained by these methods is 1.62 and 1.91 eV respectively. The frequency factors of peaks 1 and 2 are in the range of 1013-16 and 1012-14 sec-1 respectively. The E and s values estimated using the glow peak shape dependent parameters are relatively less compared to the values obtained from other methods. The large difference in these values is due to the complex nature of the glow curves. The order of the kinetics process for complex glow curve peaks could not be assigned on the basis of shape parameters alone but Tm response on absorbed dose is to be considered for final confirmation. Glow peaks 1 and 2 of LCB:Tm3+ obey first and general order kinetics respectively.
C02 01  2    @0 001E01C02
C02 02  2    @0 220C02
C03 01  2  FRE  @0 Thermoluminescence @5 01
C03 01  2  ENG  @0 thermoluminescence @5 01
C03 01  2  SPA  @0 Termoluminescencia @5 01
C03 02  2  FRE  @0 Cinétique @5 02
C03 02  2  ENG  @0 kinetics @5 02
C03 02  2  SPA  @0 Cinética @5 02
C03 03  2  FRE  @0 Thulium @5 03
C03 03  2  ENG  @0 thulium @5 03
C03 03  2  SPA  @0 Tulio @5 03
C03 04  2  FRE  @0 Lithium @5 04
C03 04  2  ENG  @0 lithium @5 04
C03 04  2  SPA  @0 Litio @5 04
C03 05  2  FRE  @0 Calcium @5 05
C03 05  2  ENG  @0 calcium @5 05
C03 05  2  SPA  @0 Calcio @5 05
C03 06  2  FRE  @0 Borate @2 NZ @5 06
C03 06  2  ENG  @0 borates @2 NZ @5 06
C03 06  2  SPA  @0 Borato @2 NZ @5 06
C03 07  2  FRE  @0 Matériau @5 07
C03 07  2  ENG  @0 materials @5 07
C03 08  2  FRE  @0 Energie activation @5 08
C03 08  2  ENG  @0 activation energy @5 08
C03 08  2  SPA  @0 Energía activación @5 08
C03 09  2  FRE  @0 Fréquence @5 09
C03 09  2  ENG  @0 frequency @5 09
C03 09  2  SPA  @0 Frecuencia @5 09
C03 10  2  FRE  @0 Piège @5 10
C03 10  2  ENG  @0 traps @5 10
C03 10  2  SPA  @0 Trampa @5 10
C03 11  2  FRE  @0 Profondeur @5 11
C03 11  2  ENG  @0 depth @5 11
C03 11  2  SPA  @0 Profundidad @5 11
N21       @1 114
N44 01      @1 OTO
N82       @1 OTO

Format Inist (serveur)

NO : PASCAL 12-0144695 INIST
ET : Determination of thermoluminescence kinetic parameters of thulium doped lithium calcium borate
AU : JOSE (M. T.); ANISHIA (S. R.); ANNALAKSHMI (O.); RAMASAMY (V.)
AF : Radiological Safety Division, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102/Tamil Nadu/Inde (1 aut., 2 aut., 3 aut., 4 aut.); Department of Physics, Annamalai University, Chidambaram/Tamil Nadu/Inde (2 aut., 4 aut.)
DT : Publication en série; Niveau analytique
SO : Radiation measurements; ISSN 1350-4487; Royaume-Uni; Da. 2011; Vol. 46; No. 10; Pp. 1026-1032; Bibl. 1/4 p.
LA : Anglais
EA : For the first time kinetic parameters of thulium doped Lithium calcium borate (LCB) Thermoluminescence (TL) material are reported here. Irradiated LCB:Tm3+ powder has revealed two intense TL glow peaks one at 510 (peak 1) and the other at 660 K (peak 2). Activation energy (E), frequency factor (s) and order of kinetics (b) of these peaks were determined by various heating rate (VHR), initial rise (IR), and peak shape (PS) methods. The trap depth and frequency factor determined for peaks 1 and 2 of LCB:Tm phosphor using VHR and IR methods are in good agreement. The average activation energy of peaks 1 and 2 obtained by these methods is 1.62 and 1.91 eV respectively. The frequency factors of peaks 1 and 2 are in the range of 1013-16 and 1012-14 sec-1 respectively. The E and s values estimated using the glow peak shape dependent parameters are relatively less compared to the values obtained from other methods. The large difference in these values is due to the complex nature of the glow curves. The order of the kinetics process for complex glow curve peaks could not be assigned on the basis of shape parameters alone but Tm response on absorbed dose is to be considered for final confirmation. Glow peaks 1 and 2 of LCB:Tm3+ obey first and general order kinetics respectively.
CC : 001E01C02; 220C02
FD : Thermoluminescence; Cinétique; Thulium; Lithium; Calcium; Borate; Matériau; Energie activation; Fréquence; Piège; Profondeur
ED : thermoluminescence; kinetics; thulium; lithium; calcium; borates; materials; activation energy; frequency; traps; depth
SD : Termoluminescencia; Cinética; Tulio; Litio; Calcio; Borato; Energía activación; Frecuencia; Trampa; Profundidad
LO : INIST-17536.354000505509050010
ID : 12-0144695

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Pascal:12-0144695

Le document en format XML

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<term>frequency</term>
<term>kinetics</term>
<term>lithium</term>
<term>materials</term>
<term>thermoluminescence</term>
<term>thulium</term>
<term>traps</term>
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<term>Thermoluminescence</term>
<term>Cinétique</term>
<term>Thulium</term>
<term>Lithium</term>
<term>Calcium</term>
<term>Borate</term>
<term>Matériau</term>
<term>Energie activation</term>
<term>Fréquence</term>
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<div type="abstract" xml:lang="en">For the first time kinetic parameters of thulium doped Lithium calcium borate (LCB) Thermoluminescence (TL) material are reported here. Irradiated LCB:Tm
<sup>3+</sup>
powder has revealed two intense TL glow peaks one at 510 (peak 1) and the other at 660 K (peak 2). Activation energy (E), frequency factor (s) and order of kinetics (b) of these peaks were determined by various heating rate (VHR), initial rise (IR), and peak shape (PS) methods. The trap depth and frequency factor determined for peaks 1 and 2 of LCB:Tm phosphor using VHR and IR methods are in good agreement. The average activation energy of peaks 1 and 2 obtained by these methods is 1.62 and 1.91 eV respectively. The frequency factors of peaks 1 and 2 are in the range of 10
<sup>13-16</sup>
and 10
<sup>12-14</sup>
sec
<sup>-1</sup>
respectively. The E and s values estimated using the glow peak shape dependent parameters are relatively less compared to the values obtained from other methods. The large difference in these values is due to the complex nature of the glow curves. The order of the kinetics process for complex glow curve peaks could not be assigned on the basis of shape parameters alone but T
<sub>m</sub>
response on absorbed dose is to be considered for final confirmation. Glow peaks 1 and 2 of LCB:Tm
<sup>3+</sup>
obey first and general order kinetics respectively.</div>
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<s1>Determination of thermoluminescence kinetic parameters of thulium doped lithium calcium borate</s1>
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<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
</fA14>
<fA14 i1="02">
<s1>Department of Physics, Annamalai University, Chidambaram</s1>
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<s0>For the first time kinetic parameters of thulium doped Lithium calcium borate (LCB) Thermoluminescence (TL) material are reported here. Irradiated LCB:Tm
<sup>3+</sup>
powder has revealed two intense TL glow peaks one at 510 (peak 1) and the other at 660 K (peak 2). Activation energy (E), frequency factor (s) and order of kinetics (b) of these peaks were determined by various heating rate (VHR), initial rise (IR), and peak shape (PS) methods. The trap depth and frequency factor determined for peaks 1 and 2 of LCB:Tm phosphor using VHR and IR methods are in good agreement. The average activation energy of peaks 1 and 2 obtained by these methods is 1.62 and 1.91 eV respectively. The frequency factors of peaks 1 and 2 are in the range of 10
<sup>13-16</sup>
and 10
<sup>12-14</sup>
sec
<sup>-1</sup>
respectively. The E and s values estimated using the glow peak shape dependent parameters are relatively less compared to the values obtained from other methods. The large difference in these values is due to the complex nature of the glow curves. The order of the kinetics process for complex glow curve peaks could not be assigned on the basis of shape parameters alone but T
<sub>m</sub>
response on absorbed dose is to be considered for final confirmation. Glow peaks 1 and 2 of LCB:Tm
<sup>3+</sup>
obey first and general order kinetics respectively.</s0>
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<s5>01</s5>
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<s0>Cinétique</s0>
<s5>02</s5>
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<s0>kinetics</s0>
<s5>02</s5>
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<fC03 i1="02" i2="2" l="SPA">
<s0>Cinética</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="2" l="FRE">
<s0>Thulium</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="2" l="ENG">
<s0>thulium</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="2" l="SPA">
<s0>Tulio</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="2" l="FRE">
<s0>Lithium</s0>
<s5>04</s5>
</fC03>
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<s0>lithium</s0>
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<s0>Litio</s0>
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<fC03 i1="05" i2="2" l="FRE">
<s0>Calcium</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="2" l="ENG">
<s0>calcium</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="2" l="SPA">
<s0>Calcio</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="2" l="FRE">
<s0>Borate</s0>
<s2>NZ</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="2" l="ENG">
<s0>borates</s0>
<s2>NZ</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="2" l="SPA">
<s0>Borato</s0>
<s2>NZ</s2>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="2" l="FRE">
<s0>Matériau</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="2" l="ENG">
<s0>materials</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="2" l="FRE">
<s0>Energie activation</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="2" l="ENG">
<s0>activation energy</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="2" l="SPA">
<s0>Energía activación</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="2" l="FRE">
<s0>Fréquence</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="2" l="ENG">
<s0>frequency</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="2" l="SPA">
<s0>Frecuencia</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="2" l="FRE">
<s0>Piège</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="2" l="ENG">
<s0>traps</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="2" l="SPA">
<s0>Trampa</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="2" l="FRE">
<s0>Profondeur</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="2" l="ENG">
<s0>depth</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="2" l="SPA">
<s0>Profundidad</s0>
<s5>11</s5>
</fC03>
<fN21>
<s1>114</s1>
</fN21>
<fN44 i1="01">
<s1>OTO</s1>
</fN44>
<fN82>
<s1>OTO</s1>
</fN82>
</pA>
</standard>
<server>
<NO>PASCAL 12-0144695 INIST</NO>
<ET>Determination of thermoluminescence kinetic parameters of thulium doped lithium calcium borate</ET>
<AU>JOSE (M. T.); ANISHIA (S. R.); ANNALAKSHMI (O.); RAMASAMY (V.)</AU>
<AF>Radiological Safety Division, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102/Tamil Nadu/Inde (1 aut., 2 aut., 3 aut., 4 aut.); Department of Physics, Annamalai University, Chidambaram/Tamil Nadu/Inde (2 aut., 4 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Radiation measurements; ISSN 1350-4487; Royaume-Uni; Da. 2011; Vol. 46; No. 10; Pp. 1026-1032; Bibl. 1/4 p.</SO>
<LA>Anglais</LA>
<EA>For the first time kinetic parameters of thulium doped Lithium calcium borate (LCB) Thermoluminescence (TL) material are reported here. Irradiated LCB:Tm
<sup>3+</sup>
powder has revealed two intense TL glow peaks one at 510 (peak 1) and the other at 660 K (peak 2). Activation energy (E), frequency factor (s) and order of kinetics (b) of these peaks were determined by various heating rate (VHR), initial rise (IR), and peak shape (PS) methods. The trap depth and frequency factor determined for peaks 1 and 2 of LCB:Tm phosphor using VHR and IR methods are in good agreement. The average activation energy of peaks 1 and 2 obtained by these methods is 1.62 and 1.91 eV respectively. The frequency factors of peaks 1 and 2 are in the range of 10
<sup>13-16</sup>
and 10
<sup>12-14</sup>
sec
<sup>-1</sup>
respectively. The E and s values estimated using the glow peak shape dependent parameters are relatively less compared to the values obtained from other methods. The large difference in these values is due to the complex nature of the glow curves. The order of the kinetics process for complex glow curve peaks could not be assigned on the basis of shape parameters alone but T
<sub>m</sub>
response on absorbed dose is to be considered for final confirmation. Glow peaks 1 and 2 of LCB:Tm
<sup>3+</sup>
obey first and general order kinetics respectively.</EA>
<CC>001E01C02; 220C02</CC>
<FD>Thermoluminescence; Cinétique; Thulium; Lithium; Calcium; Borate; Matériau; Energie activation; Fréquence; Piège; Profondeur</FD>
<ED>thermoluminescence; kinetics; thulium; lithium; calcium; borates; materials; activation energy; frequency; traps; depth</ED>
<SD>Termoluminescencia; Cinética; Tulio; Litio; Calcio; Borato; Energía activación; Frecuencia; Trampa; Profundidad</SD>
<LO>INIST-17536.354000505509050010</LO>
<ID>12-0144695</ID>
</server>
</inist>
</record>

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