ThuliumV1, Pascal, Corpus, bibRecord, 000162

Effect of surface preparation and R-group size on the stabilization of lithium metal anodes with silanes

Identifieur interne : 000162 ( Pascal/Corpus ); précédent : 000161; suivant : 000163

Effect of surface preparation and R-group size on the stabilization of lithium metal anodes with silanes

Auteurs : Susanna Neuhold ; David J. Schroeder ; John T. Vaughey

Source :

Journal of power sources [ 0378-7753 ] ; 2012.

RBID : Pascal:12-0170302

Descripteurs français

Pascal (Inist)
- Préparation surface, Anode, Batterie lithium, Etude comparative, Compatibilité électromagnétique, Electrolyte, Accumulateur électrochimique, Revêtement, Lithium, Soufre, Sulfure de thulium, TmS, Batterie lithium-air.

English descriptors

KwdEn :
- Anode, Coatings, Comparative study, Electrolyte, Electromagnetic compatibility, Lithium, Lithium battery, Lithium-air battery, Secondary cell, Sulfur, Surface preparation, Thulium sulfides.

Abstract

As new applications for lithium-ion batteries emerge into the marketplace, a new emphasis is being placed on developing higher capacity electrodes. Two of the higher capacity technologies under development are lithium-sulfur and lithium-air batteries, both of which, in most configurations, use a lithium metal anode. Building on our previous work extending the cycle life of lithium metal anodes via surface functionalization with silane groups, we have identified two separate regimes for the cycle life enhancements based on size of the silane R-groups. Very small R-groups (TMS) and R-groups bulkier than triphenyl show enhanced cycle life compared to control samples while R-groups between these in size show reduced cycle life. Additionally, we present a comparison between different cleaning methods to optimize the hydroxyl functionalized layer on the lithium metal and the influence of these methods on the stability of lithium metal in EC:EMC electrolyte. A solvent based cleaning approach is shown to substantially improve stability when combined with chlorotrimethyl silane treatment.

Notice en format standard (ISO 2709)

Pour connaître la documentation sur le format Inist Standard.

A01	`01`	`1`		`@0 0378-7753`
A02	`01`			`@0 JPSODZ`
A03		`1`		`@0 J. power sources`
A05				`@2 206`
A08	`01`	`1`	`ENG`	`@1 Effect of surface preparation and R-group size on the stabilization of lithium metal anodes with silanes`
A11	`01`	`1`		`@1 NEUHOLD (Susanna)`
A11	`02`	`1`		`@1 SCHROEDER (David J.)`
A11	`03`	`1`		`@1 VAUGHEY (John T.)`
A14	`01`			`@1 Chemical Sciences and Engineering Division Argonne National Laboratory @2 Argonne, IL 60439 @3 USA @Z 1 aut. @Z 3 aut.`
A14	`02`			`@1 Department of Engineering Technology Northern Illinois University @2 DeKalb, IL 60115 @3 USA @Z 2 aut.`
A20				`@1 295-300`
A21				`@1 2012`
A23	`01`			`@0 ENG`
A43	`01`			`@1 INIST @2 17113 @5 354000509777690390`
A44				`@0 0000 @1 © 2012 INIST-CNRS. All rights reserved.`
A45				`@0 23 ref.`
A47	`01`	`1`		`@0 12-0170302`
A60				`@1 P`
A61				`@0 A`
A64	`01`	`1`		`@0 Journal of power sources`
A66	`01`			`@0 NLD`
C01	`01`		`ENG`	@0 As new applications for lithium-ion batteries emerge into the marketplace, a new emphasis is being placed on developing higher capacity electrodes. Two of the higher capacity technologies under development are lithium-sulfur and lithium-air batteries, both of which, in most configurations, use a lithium metal anode. Building on our previous work extending the cycle life of lithium metal anodes via surface functionalization with silane groups, we have identified two separate regimes for the cycle life enhancements based on size of the silane R-groups. Very small R-groups (TMS) and R-groups bulkier than triphenyl show enhanced cycle life compared to control samples while R-groups between these in size show reduced cycle life. Additionally, we present a comparison between different cleaning methods to optimize the hydroxyl functionalized layer on the lithium metal and the influence of these methods on the stability of lithium metal in EC:EMC electrolyte. A solvent based cleaning approach is shown to substantially improve stability when combined with chlorotrimethyl silane treatment.
C02	`01`	`X`		`@0 001D05I03E`
C03	`01`	`X`	`FRE`	`@0 Préparation surface @5 01`
C03	`01`	`X`	`ENG`	`@0 Surface preparation @5 01`
C03	`01`	`X`	`SPA`	`@0 Preparación superficie @5 01`
C03	`02`	`X`	`FRE`	`@0 Anode @5 02`
C03	`02`	`X`	`ENG`	`@0 Anode @5 02`
C03	`02`	`X`	`SPA`	`@0 Anodo @5 02`
C03	`03`	`3`	`FRE`	`@0 Batterie lithium @5 03`
C03	`03`	`3`	`ENG`	`@0 Lithium battery @5 03`
C03	`04`	`X`	`FRE`	`@0 Etude comparative @5 04`
C03	`04`	`X`	`ENG`	`@0 Comparative study @5 04`
C03	`04`	`X`	`SPA`	`@0 Estudio comparativo @5 04`
C03	`05`	`X`	`FRE`	`@0 Compatibilité électromagnétique @5 05`
C03	`05`	`X`	`ENG`	`@0 Electromagnetic compatibility @5 05`
C03	`05`	`X`	`SPA`	`@0 Compatibilidad electromagnética @5 05`
C03	`06`	`X`	`FRE`	`@0 Electrolyte @5 06`
C03	`06`	`X`	`ENG`	`@0 Electrolyte @5 06`
C03	`06`	`X`	`SPA`	`@0 Electrólito @5 06`
C03	`07`	`X`	`FRE`	`@0 Accumulateur électrochimique @5 07`
C03	`07`	`X`	`ENG`	`@0 Secondary cell @5 07`
C03	`07`	`X`	`SPA`	`@0 Acumulador electroquímico @5 07`
C03	`08`	`X`	`FRE`	`@0 Revêtement @5 08`
C03	`08`	`X`	`ENG`	`@0 Coatings @5 08`
C03	`08`	`X`	`SPA`	`@0 Revestimiento @5 08`
C03	`09`	`X`	`FRE`	`@0 Lithium @2 NC @5 22`
C03	`09`	`X`	`ENG`	`@0 Lithium @2 NC @5 22`
C03	`09`	`X`	`SPA`	`@0 Litio @2 NC @5 22`
C03	`10`	`X`	`FRE`	`@0 Soufre @2 NC @2 FX @5 23`
C03	`10`	`X`	`ENG`	`@0 Sulfur @2 NC @2 FX @5 23`
C03	`10`	`X`	`SPA`	`@0 Azufre @2 NC @2 FX @5 23`
C03	`11`	`3`	`FRE`	`@0 Sulfure de thulium @2 NK @5 24`
C03	`11`	`3`	`ENG`	`@0 Thulium sulfides @2 NK @5 24`
C03	`12`	`X`	`FRE`	`@0 TmS @4 INC @5 82`
C03	`13`	`X`	`FRE`	`@0 Batterie lithium-air @4 CD @5 96`
C03	`13`	`X`	`ENG`	`@0 Lithium-air battery @4 CD @5 96`
C07	`01`	`X`	`FRE`	`@0 Accumulateur alcalin @5 09`
C07	`01`	`X`	`ENG`	`@0 Alkaline storage battery @5 09`
C07	`01`	`X`	`SPA`	`@0 Acumulador alcalino @5 09`
N21				`@1 129`
N44	`01`			`@1 OTO`
N82				`@1 OTO`

Format Inist (serveur)

NO :	PASCAL 12-0170302 INIST
ET :	Effect of surface preparation and R-group size on the stabilization of lithium metal anodes with silanes
AU :	NEUHOLD (Susanna); SCHROEDER (David J.); VAUGHEY (John T.)
AF :	Chemical Sciences and Engineering Division Argonne National Laboratory/Argonne, IL 60439/Etats-Unis (1 aut., 3 aut.); Department of Engineering Technology Northern Illinois University/DeKalb, IL 60115/Etats-Unis (2 aut.)
DT :	Publication en série; Niveau analytique
SO :	Journal of power sources; ISSN 0378-7753; Coden JPSODZ; Pays-Bas; Da. 2012; Vol. 206; Pp. 295-300; Bibl. 23 ref.
LA :	Anglais
EA :	As new applications for lithium-ion batteries emerge into the marketplace, a new emphasis is being placed on developing higher capacity electrodes. Two of the higher capacity technologies under development are lithium-sulfur and lithium-air batteries, both of which, in most configurations, use a lithium metal anode. Building on our previous work extending the cycle life of lithium metal anodes via surface functionalization with silane groups, we have identified two separate regimes for the cycle life enhancements based on size of the silane R-groups. Very small R-groups (TMS) and R-groups bulkier than triphenyl show enhanced cycle life compared to control samples while R-groups between these in size show reduced cycle life. Additionally, we present a comparison between different cleaning methods to optimize the hydroxyl functionalized layer on the lithium metal and the influence of these methods on the stability of lithium metal in EC:EMC electrolyte. A solvent based cleaning approach is shown to substantially improve stability when combined with chlorotrimethyl silane treatment.
CC :	001D05I03E
FD :	Préparation surface; Anode; Batterie lithium; Etude comparative; Compatibilité électromagnétique; Electrolyte; Accumulateur électrochimique; Revêtement; Lithium; Soufre; Sulfure de thulium; TmS; Batterie lithium-air
FG :	Accumulateur alcalin
ED :	Surface preparation; Anode; Lithium battery; Comparative study; Electromagnetic compatibility; Electrolyte; Secondary cell; Coatings; Lithium; Sulfur; Thulium sulfides; Lithium-air battery
EG :	Alkaline storage battery
SD :	Preparación superficie; Anodo; Estudio comparativo; Compatibilidad electromagnética; Electrólito; Acumulador electroquímico; Revestimiento; Litio; Azufre
LO :	INIST-17113.354000509777690390
ID :	12-0170302

Links to Exploration step

Pascal:12-0170302

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Effect of surface preparation and R-group size on the stabilization of lithium metal anodes with silanes</title>
<author><name sortKey="Neuhold, Susanna" sort="Neuhold, Susanna" uniqKey="Neuhold S" first="Susanna" last="Neuhold">Susanna Neuhold</name>
<affiliation><inist:fA14 i1="01"><s1>Chemical Sciences and Engineering Division Argonne National Laboratory</s1>
<s2>Argonne, IL 60439</s2>
<s3>USA</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author><name sortKey="Schroeder, David J" sort="Schroeder, David J" uniqKey="Schroeder D" first="David J." last="Schroeder">David J. Schroeder</name>
<affiliation><inist:fA14 i1="02"><s1>Department of Engineering Technology Northern Illinois University</s1>
<s2>DeKalb, IL 60115</s2>
<s3>USA</s3>
<sZ>2 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author><name sortKey="Vaughey, John T" sort="Vaughey, John T" uniqKey="Vaughey J" first="John T." last="Vaughey">John T. Vaughey</name>
<affiliation><inist:fA14 i1="01"><s1>Chemical Sciences and Engineering Division Argonne National Laboratory</s1>
<s2>Argonne, IL 60439</s2>
<s3>USA</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">INIST</idno>
<idno type="inist">12-0170302</idno>
<date when="2012">2012</date>
<idno type="stanalyst">PASCAL 12-0170302 INIST</idno>
<idno type="RBID">Pascal:12-0170302</idno>
<idno type="wicri:Area/Pascal/Corpus">000162</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Effect of surface preparation and R-group size on the stabilization of lithium metal anodes with silanes</title>
<author><name sortKey="Neuhold, Susanna" sort="Neuhold, Susanna" uniqKey="Neuhold S" first="Susanna" last="Neuhold">Susanna Neuhold</name>
<affiliation><inist:fA14 i1="01"><s1>Chemical Sciences and Engineering Division Argonne National Laboratory</s1>
<s2>Argonne, IL 60439</s2>
<s3>USA</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author><name sortKey="Schroeder, David J" sort="Schroeder, David J" uniqKey="Schroeder D" first="David J." last="Schroeder">David J. Schroeder</name>
<affiliation><inist:fA14 i1="02"><s1>Department of Engineering Technology Northern Illinois University</s1>
<s2>DeKalb, IL 60115</s2>
<s3>USA</s3>
<sZ>2 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
<author><name sortKey="Vaughey, John T" sort="Vaughey, John T" uniqKey="Vaughey J" first="John T." last="Vaughey">John T. Vaughey</name>
<affiliation><inist:fA14 i1="01"><s1>Chemical Sciences and Engineering Division Argonne National Laboratory</s1>
<s2>Argonne, IL 60439</s2>
<s3>USA</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Journal of power sources</title>
<title level="j" type="abbreviated">J. power sources</title>
<idno type="ISSN">0378-7753</idno>
<imprint><date when="2012">2012</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><title level="j" type="main">Journal of power sources</title>
<title level="j" type="abbreviated">J. power sources</title>
<idno type="ISSN">0378-7753</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Anode</term>
<term>Coatings</term>
<term>Comparative study</term>
<term>Electrolyte</term>
<term>Electromagnetic compatibility</term>
<term>Lithium</term>
<term>Lithium battery</term>
<term>Lithium-air battery</term>
<term>Secondary cell</term>
<term>Sulfur</term>
<term>Surface preparation</term>
<term>Thulium sulfides</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Préparation surface</term>
<term>Anode</term>
<term>Batterie lithium</term>
<term>Etude comparative</term>
<term>Compatibilité électromagnétique</term>
<term>Electrolyte</term>
<term>Accumulateur électrochimique</term>
<term>Revêtement</term>
<term>Lithium</term>
<term>Soufre</term>
<term>Sulfure de thulium</term>
<term>TmS</term>
<term>Batterie lithium-air</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">As new applications for lithium-ion batteries emerge into the marketplace, a new emphasis is being placed on developing higher capacity electrodes. Two of the higher capacity technologies under development are lithium-sulfur and lithium-air batteries, both of which, in most configurations, use a lithium metal anode. Building on our previous work extending the cycle life of lithium metal anodes via surface functionalization with silane groups, we have identified two separate regimes for the cycle life enhancements based on size of the silane R-groups. Very small R-groups (TMS) and R-groups bulkier than triphenyl show enhanced cycle life compared to control samples while R-groups between these in size show reduced cycle life. Additionally, we present a comparison between different cleaning methods to optimize the hydroxyl functionalized layer on the lithium metal and the influence of these methods on the stability of lithium metal in EC:EMC electrolyte. A solvent based cleaning approach is shown to substantially improve stability when combined with chlorotrimethyl silane treatment.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0378-7753</s0>
</fA01>
<fA02 i1="01"><s0>JPSODZ</s0>
</fA02>
<fA03 i2="1"><s0>J. power sources</s0>
</fA03>
<fA05><s2>206</s2>
</fA05>
<fA08 i1="01" i2="1" l="ENG"><s1>Effect of surface preparation and R-group size on the stabilization of lithium metal anodes with silanes</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>NEUHOLD (Susanna)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>SCHROEDER (David J.)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>VAUGHEY (John T.)</s1>
</fA11>
<fA14 i1="01"><s1>Chemical Sciences and Engineering Division Argonne National Laboratory</s1>
<s2>Argonne, IL 60439</s2>
<s3>USA</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Department of Engineering Technology Northern Illinois University</s1>
<s2>DeKalb, IL 60115</s2>
<s3>USA</s3>
<sZ>2 aut.</sZ>
</fA14>
<fA20><s1>295-300</s1>
</fA20>
<fA21><s1>2012</s1>
</fA21>
<fA23 i1="01"><s0>ENG</s0>
</fA23>
<fA43 i1="01"><s1>INIST</s1>
<s2>17113</s2>
<s5>354000509777690390</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2012 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>23 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>12-0170302</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Journal of power sources</s0>
</fA64>
<fA66 i1="01"><s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>As new applications for lithium-ion batteries emerge into the marketplace, a new emphasis is being placed on developing higher capacity electrodes. Two of the higher capacity technologies under development are lithium-sulfur and lithium-air batteries, both of which, in most configurations, use a lithium metal anode. Building on our previous work extending the cycle life of lithium metal anodes via surface functionalization with silane groups, we have identified two separate regimes for the cycle life enhancements based on size of the silane R-groups. Very small R-groups (TMS) and R-groups bulkier than triphenyl show enhanced cycle life compared to control samples while R-groups between these in size show reduced cycle life. Additionally, we present a comparison between different cleaning methods to optimize the hydroxyl functionalized layer on the lithium metal and the influence of these methods on the stability of lithium metal in EC:EMC electrolyte. A solvent based cleaning approach is shown to substantially improve stability when combined with chlorotrimethyl silane treatment.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001D05I03E</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Préparation surface</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Surface preparation</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Preparación superficie</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Anode</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Anode</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Anodo</s0>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE"><s0>Batterie lithium</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG"><s0>Lithium battery</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Etude comparative</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Comparative study</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Estudio comparativo</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Compatibilité électromagnétique</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Electromagnetic compatibility</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Compatibilidad electromagnética</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Electrolyte</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Electrolyte</s0>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Electrólito</s0>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Accumulateur électrochimique</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Secondary cell</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Acumulador electroquímico</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Revêtement</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Coatings</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Revestimiento</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Lithium</s0>
<s2>NC</s2>
<s5>22</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Lithium</s0>
<s2>NC</s2>
<s5>22</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Litio</s0>
<s2>NC</s2>
<s5>22</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Soufre</s0>
<s2>NC</s2>
<s2>FX</s2>
<s5>23</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Sulfur</s0>
<s2>NC</s2>
<s2>FX</s2>
<s5>23</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Azufre</s0>
<s2>NC</s2>
<s2>FX</s2>
<s5>23</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE"><s0>Sulfure de thulium</s0>
<s2>NK</s2>
<s5>24</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG"><s0>Thulium sulfides</s0>
<s2>NK</s2>
<s5>24</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>TmS</s0>
<s4>INC</s4>
<s5>82</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Batterie lithium-air</s0>
<s4>CD</s4>
<s5>96</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Lithium-air battery</s0>
<s4>CD</s4>
<s5>96</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE"><s0>Accumulateur alcalin</s0>
<s5>09</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG"><s0>Alkaline storage battery</s0>
<s5>09</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA"><s0>Acumulador alcalino</s0>
<s5>09</s5>
</fC07>
<fN21><s1>129</s1>
</fN21>
<fN44 i1="01"><s1>OTO</s1>
</fN44>
<fN82><s1>OTO</s1>
</fN82>
</pA>
</standard>
<server><NO>PASCAL 12-0170302 INIST</NO>
<ET>Effect of surface preparation and R-group size on the stabilization of lithium metal anodes with silanes</ET>
<AU>NEUHOLD (Susanna); SCHROEDER (David J.); VAUGHEY (John T.)</AU>
<AF>Chemical Sciences and Engineering Division Argonne National Laboratory/Argonne, IL 60439/Etats-Unis (1 aut., 3 aut.); Department of Engineering Technology Northern Illinois University/DeKalb, IL 60115/Etats-Unis (2 aut.)</AF>
<DT>Publication en série; Niveau analytique</DT>
<SO>Journal of power sources; ISSN 0378-7753; Coden JPSODZ; Pays-Bas; Da. 2012; Vol. 206; Pp. 295-300; Bibl. 23 ref.</SO>
<LA>Anglais</LA>
<EA>As new applications for lithium-ion batteries emerge into the marketplace, a new emphasis is being placed on developing higher capacity electrodes. Two of the higher capacity technologies under development are lithium-sulfur and lithium-air batteries, both of which, in most configurations, use a lithium metal anode. Building on our previous work extending the cycle life of lithium metal anodes via surface functionalization with silane groups, we have identified two separate regimes for the cycle life enhancements based on size of the silane R-groups. Very small R-groups (TMS) and R-groups bulkier than triphenyl show enhanced cycle life compared to control samples while R-groups between these in size show reduced cycle life. Additionally, we present a comparison between different cleaning methods to optimize the hydroxyl functionalized layer on the lithium metal and the influence of these methods on the stability of lithium metal in EC:EMC electrolyte. A solvent based cleaning approach is shown to substantially improve stability when combined with chlorotrimethyl silane treatment.</EA>
<CC>001D05I03E</CC>
<FD>Préparation surface; Anode; Batterie lithium; Etude comparative; Compatibilité électromagnétique; Electrolyte; Accumulateur électrochimique; Revêtement; Lithium; Soufre; Sulfure de thulium; TmS; Batterie lithium-air</FD>
<FG>Accumulateur alcalin</FG>
<ED>Surface preparation; Anode; Lithium battery; Comparative study; Electromagnetic compatibility; Electrolyte; Secondary cell; Coatings; Lithium; Sulfur; Thulium sulfides; Lithium-air battery</ED>
<EG>Alkaline storage battery</EG>
<SD>Preparación superficie; Anodo; Estudio comparativo; Compatibilidad electromagnética; Electrólito; Acumulador electroquímico; Revestimiento; Litio; Azufre</SD>
<LO>INIST-17113.354000509777690390</LO>
<ID>12-0170302</ID>
</server>
</inist>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/ThuliumV1/Data/Pascal/Corpus

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000162 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Pascal/Corpus/biblio.hfd -nk 000162 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Terre
   |area=    ThuliumV1
   |flux=    Pascal
   |étape=   Corpus
   |type=    RBID
   |clé=     Pascal:12-0170302
   |texte=   Effect of surface preparation and R-group size on the stabilization of lithium metal anodes with silanes
}}

This area was generated with Dilib version V0.6.21.
Data generation: Thu May 12 08:27:09 2016. Site generation: Thu Mar 7 22:33:44 2024

	Serveur d'exploration sur le thulium
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur le thulium

Effect of surface preparation and R-group size on the stabilization of lithium metal anodes with silanes

Effect of surface preparation and R-group size on the stabilization of lithium metal anodes with silanes

Source :

Descripteurs français

English descriptors

Abstract

Notice en format standard (ISO 2709)

Format Inist (serveur)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri