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Electron-vibrational shift of f-levels in CaF2 and SrF2 crystals with Tm2+ ions

Identifieur interne : 001342 ( Pascal/Checkpoint ); précédent : 001341; suivant : 001343

Electron-vibrational shift of f-levels in CaF2 and SrF2 crystals with Tm2+ ions

Auteurs : I. Ignatev [Russie] ; V. Ovsyankin [Russie]

Source :

RBID : Pascal:97-0389788

Descripteurs français

English descriptors

Abstract

Copyright (c) 1997 Elsevier Science B.V. All rights reserved.The nonparametric calculations of f-level shifts in CaF2:Tm2+ and SrF2:Tm2+ crystals are performed in the frame of the electron-vibrational coupling (EVC) model, thoroughly tested previously by analysis of vibronic spectra and suppression of electron transitions in these crystals. It is found that EVC is able to cause large (in few tenths of cm-1) level shifts provided that the Stark splitting is less than phonon spectrum width. This fact should be taken into account when analysing the rare-earth ion levels Stark splitting by phenomenological crystal-field models.


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Pascal:97-0389788

Le document en format XML

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<title xml:lang="en" level="a">Electron-vibrational shift of f-levels in CaF
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and SrF
<sub>2</sub>
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ions</title>
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<div type="abstract" xml:lang="en">Copyright (c) 1997 Elsevier Science B.V. All rights reserved.The nonparametric calculations of f-level shifts in CaF
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   |texte=   Electron-vibrational shift of f-levels in CaF2 and SrF2 crystals with Tm2+ ions
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