Observation and interpretation of the Tm3+ free ion spectrum
Identifieur interne : 000753 ( Pascal/Checkpoint ); précédent : 000752; suivant : 000754Observation and interpretation of the Tm3+ free ion spectrum
Auteurs : A. Meftah [France] ; J.-F. Wyart [France] ; N. Champion [France] ; W.-U. L. Tchang-Brillet [France]Source :
- The European physical journal. D, Atomic, molecular and optical physics [ 1434-6060 ] ; 2007.
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Abstract
The emission spectrum of thulium produced by a vacuum spark source was observed in the wavelength range from 700 to 2320 Å on the 10.7 m normal-incidence vacuum ultraviolet spectrograph at the Paris-Meudon observatory. In the unknown spectrum of Tm IV, more than 760 lines have been identified for the first time as transitions between 157 levels of 4f115d, 33 levels of 4f116p, 9 levels of 4f116s and 10 levels of the 4f12 ground configuration. A parametric interpretation of the levels has been carried out using the Cowan codes. Configuration interaction effects are discussed, in particular with the core-excited configurations 5p54f13 and 5p54f125d. Radial Slater parameters derived from 4f12 levels are larger than those pertaining to trivalent Tm ions in compounds. A selection of 105 prominent lines is given.
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Meftah</name><affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Laboratoire Aimé Cotton, CNRS (UPR3321), bâtiment 505, Université Paris-Sud</s1><s2>91405 Orsay</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Orsay</settlement><settlement type="city">Orsay</settlement></placeName><orgName type="university">Université Paris-Sud</orgName></affiliation></author><author><name sortKey="Wyart, J F" sort="Wyart, J F" uniqKey="Wyart J" first="J.-F." last="Wyart">J.-F. 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D, Atomic, molecular and optical physics</title><title level="j" type="abbreviated">Eur. phys. j., D At. mol. opt. phys.</title><idno type="ISSN">1434-6060</idno><imprint><date when="2007">2007</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">The European physical journal. D, Atomic, molecular and optical physics</title><title level="j" type="abbreviated">Eur. phys. j., D At. mol. opt. phys.</title><idno type="ISSN">1434-6060</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Configuration interaction</term><term>Emission spectra</term><term>Energy levels</term><term>Multicharged ions</term><term>Positive ions</term><term>Thulium Atomic ions</term><term>Transition probabilities</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Interaction configuration</term><term>Spectre émission</term><term>Niveau énergie</term><term>Thulium Ion atomique</term><term>Ion positif</term><term>Ion multichargé</term><term>Probabilité transition</term><term>3115M</term><term>Tm ip 3</term><term>3270C</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The emission spectrum of thulium produced by a vacuum spark source was observed in the wavelength range from 700 to 2320 Å on the 10.7 m normal-incidence vacuum ultraviolet spectrograph at the Paris-Meudon observatory. In the unknown spectrum of Tm IV, more than 760 lines have been identified for the first time as transitions between 157 levels of 4f<sup>11</sup>5d, 33 levels of 4f<sup>11</sup>6p, 9 levels of 4f<sup>11</sup>6s and 10 levels of the 4f<sup>12</sup> ground configuration. A parametric interpretation of the levels has been carried out using the Cowan codes. Configuration interaction effects are discussed, in particular with the core-excited configurations 5p<sup>5</sup>4f<sup>13</sup> and 5p<sup>5</sup>4f<sup>12</sup>5d. Radial Slater parameters derived from 4f<sup>12</sup> levels are larger than those pertaining to trivalent Tm ions in compounds. A selection of 105 prominent lines is given.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>1434-6060</s0></fA01><fA03 i2="1"><s0>Eur. phys. j., D At. mol. opt. phys.</s0></fA03><fA05><s2>44</s2></fA05><fA06><s2>1</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Observation and interpretation of the Tm<sup>3+</sup> free ion spectrum</s1></fA08><fA11 i1="01" i2="1"><s1>MEFTAH (A.)</s1></fA11><fA11 i1="02" i2="1"><s1>WYART (J.-F.)</s1></fA11><fA11 i1="03" i2="1"><s1>CHAMPION (N.)</s1></fA11><fA11 i1="04" i2="1"><s1>TCHANG-BRILLET (W.-U. L.)</s1></fA11><fA14 i1="01"><s1>Laboratoire Aimé Cotton, CNRS (UPR3321), bâtiment 505, Université Paris-Sud</s1><s2>91405 Orsay</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></fA14><fA14 i1="02"><s1>LERMA, UMR8112 du CNRS, Observatoire de Paris-Meudon</s1><s2>92195 Meudon</s2><s3>FRA</s3><sZ>3 aut.</sZ><sZ>4 aut.</sZ></fA14><fA14 i1="03"><s1>Université Pierre et Marie Curie-Paris6</s1><s2>75005 Paris</s2><s3>FRA</s3><sZ>3 aut.</sZ><sZ>4 aut.</sZ></fA14><fA20><s1>35-45</s1></fA20><fA21><s1>2007</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>26689</s2><s5>354000162462180050</s5></fA43><fA44><s0>0000</s0><s1>© 2007 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>26 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>07-0460039</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>The European physical journal. D, Atomic, molecular and optical physics</s0></fA64><fA66 i1="01"><s0>FRA</s0></fA66><fC01 i1="01" l="ENG"><s0>The emission spectrum of thulium produced by a vacuum spark source was observed in the wavelength range from 700 to 2320 Å on the 10.7 m normal-incidence vacuum ultraviolet spectrograph at the Paris-Meudon observatory. In the unknown spectrum of Tm IV, more than 760 lines have been identified for the first time as transitions between 157 levels of 4f<sup>11</sup>5d, 33 levels of 4f<sup>11</sup>6p, 9 levels of 4f<sup>11</sup>6s and 10 levels of the 4f<sup>12</sup> ground configuration. A parametric interpretation of the levels has been carried out using the Cowan codes. Configuration interaction effects are discussed, in particular with the core-excited configurations 5p<sup>5</sup>4f<sup>13</sup> and 5p<sup>5</sup>4f<sup>12</sup>5d. Radial Slater parameters derived from 4f<sup>12</sup> levels are larger than those pertaining to trivalent Tm ions in compounds. A selection of 105 prominent lines is given.</s0></fC01><fC02 i1="01" i2="3"><s0>001B30A15M</s0></fC02><fC02 i1="02" i2="3"><s0>001B30B70C</s0></fC02><fC03 i1="01" i2="3" l="FRE"><s0>Interaction configuration</s0><s5>23</s5></fC03><fC03 i1="01" i2="3" l="ENG"><s0>Configuration interaction</s0><s5>23</s5></fC03><fC03 i1="02" i2="3" l="FRE"><s0>Spectre émission</s0><s5>41</s5></fC03><fC03 i1="02" i2="3" l="ENG"><s0>Emission spectra</s0><s5>41</s5></fC03><fC03 i1="03" i2="3" l="FRE"><s0>Niveau énergie</s0><s5>42</s5></fC03><fC03 i1="03" i2="3" l="ENG"><s0>Energy levels</s0><s5>42</s5></fC03><fC03 i1="04" i2="3" l="FRE"><s0>Thulium Ion atomique</s0><s2>NC</s2><s5>61</s5></fC03><fC03 i1="04" i2="3" l="ENG"><s0>Thulium Atomic ions</s0><s2>NC</s2><s5>61</s5></fC03><fC03 i1="05" i2="3" l="FRE"><s0>Ion positif</s0><s5>62</s5></fC03><fC03 i1="05" i2="3" l="ENG"><s0>Positive ions</s0><s5>62</s5></fC03><fC03 i1="06" i2="3" l="FRE"><s0>Ion multichargé</s0><s5>63</s5></fC03><fC03 i1="06" i2="3" l="ENG"><s0>Multicharged ions</s0><s5>63</s5></fC03><fC03 i1="07" i2="3" l="FRE"><s0>Probabilité transition</s0><s5>64</s5></fC03><fC03 i1="07" i2="3" l="ENG"><s0>Transition probabilities</s0><s5>64</s5></fC03><fC03 i1="08" i2="3" l="FRE"><s0>3115M</s0><s4>INC</s4><s5>83</s5></fC03><fC03 i1="09" i2="3" l="FRE"><s0>Tm ip 3</s0><s4>INC</s4><s5>84</s5></fC03><fC03 i1="10" i2="3" l="FRE"><s0>3270C</s0><s4>INC</s4><s5>85</s5></fC03><fN21><s1>302</s1></fN21></pA></standard></inist><affiliations><list><country><li>France</li></country><region><li>Île-de-France</li></region><settlement><li>Meudon</li><li>Orsay</li><li>Paris</li></settlement><orgName><li>Université Paris-Sud</li></orgName></list><tree><country name="France"><region name="Île-de-France"><name sortKey="Meftah, A" sort="Meftah, A" uniqKey="Meftah A" first="A." last="Meftah">A. Meftah</name></region><name sortKey="Champion, N" sort="Champion, N" uniqKey="Champion N" first="N." last="Champion">N. Champion</name><name sortKey="Champion, N" sort="Champion, N" uniqKey="Champion N" first="N." last="Champion">N. Champion</name><name sortKey="Tchang Brillet, W U L" sort="Tchang Brillet, W U L" uniqKey="Tchang Brillet W" first="W.-U. L." last="Tchang-Brillet">W.-U. L. Tchang-Brillet</name><name sortKey="Tchang Brillet, W U L" sort="Tchang Brillet, W U L" uniqKey="Tchang Brillet W" first="W.-U. L." last="Tchang-Brillet">W.-U. L. Tchang-Brillet</name><name sortKey="Wyart, J F" sort="Wyart, J F" uniqKey="Wyart J" first="J.-F." last="Wyart">J.-F. Wyart</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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