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Anti-Stokes emission in LaAlO3 crystal doped with Tm3+ ions

Identifieur interne : 000683 ( Pascal/Checkpoint ); précédent : 000682; suivant : 000684

Anti-Stokes emission in LaAlO3 crystal doped with Tm3+ ions

Auteurs : P. J. Deren [Pologne] ; Ph. Goldner [France] ; O. Guillot-Noël [France]

Source :

RBID : Pascal:08-0378792

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English descriptors

Abstract

LaAlO3 single crystal doped with Tm3+ ions was investigated. After continuous wave excitation of the 3F2 level (at about 15,115cm-1) strong violet and UV light was observed which corresponds to the 1D23F4 (22,000 cm-1) and the 1D23H6 (27,700 cm-1) as well as the 3 P03F4 (28,600 cm-1) transition, respectively. Emission and excitation spectra of the Stokes and anti-Stokes emission were measured. Excitation spectrum was compared with absorption one. Power dependence of the anti-Stokes emission was recorded and analyzed. Possible mechanisms of three or more photons excited state absorption (ESA) and cross-relaxation are discussed.


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Pascal:08-0378792

Le document en format XML

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<title xml:lang="en" level="a">Anti-Stokes emission in LaAlO
<sub>3</sub>
crystal doped with Tm
<sup>3+</sup>
ions</title>
<author>
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<s1>Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410</s1>
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<s3>POL</s3>
<sZ>1 aut.</sZ>
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<s2>75231 Paris</s2>
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<name sortKey="Guillot Noel, O" sort="Guillot Noel, O" uniqKey="Guillot Noel O" first="O." last="Guillot-Noël">O. Guillot-Noël</name>
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<title xml:lang="en" level="a">Anti-Stokes emission in LaAlO
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crystal doped with Tm
<sup>3+</sup>
ions</title>
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<name sortKey="Deren, P J" sort="Deren, P J" uniqKey="Deren P" first="P. J." last="Deren">P. J. Deren</name>
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<s1>Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410</s1>
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<author>
<name sortKey="Guillot Noel, O" sort="Guillot Noel, O" uniqKey="Guillot Noel O" first="O." last="Guillot-Noël">O. Guillot-Noël</name>
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<s1>Laboratoire de Chimie Appliquée de l'Etat Solide, CNRS-UMR 7574, ENSCP, 11 rue Curie</s1>
<s2>75231 Paris</s2>
<s3>FRA</s3>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>France</country>
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<placeName>
<settlement type="city">Paris</settlement>
<region type="région" nuts="2">Île-de-France</region>
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<title level="j" type="main">Journal of alloys and compounds</title>
<title level="j" type="abbreviated">J. alloys compd.</title>
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<title level="j" type="main">Journal of alloys and compounds</title>
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<term>Aluminium oxide</term>
<term>Continuous wave</term>
<term>Cross relaxation</term>
<term>Doping</term>
<term>Energy-level transitions</term>
<term>Excitation spectrum</term>
<term>Excited states</term>
<term>Impurities</term>
<term>Lanthanum oxide</term>
<term>Monocrystals</term>
<term>Multi-photon processes</term>
<term>Perovskites</term>
<term>Photoluminescence</term>
<term>Thulium additions</term>
<term>Ultraviolet radiation</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Processus n photons</term>
<term>Dopage</term>
<term>Onde entretenue</term>
<term>Rayonnement UV</term>
<term>Photoluminescence</term>
<term>Spectre excitation</term>
<term>Etat excité</term>
<term>Relaxation croisée</term>
<term>Transition niveau énergie</term>
<term>Impureté</term>
<term>Addition thulium</term>
<term>Oxyde de lanthane</term>
<term>Oxyde d'aluminium</term>
<term>Monocristal</term>
<term>Perovskites</term>
<term>LaAlO3</term>
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<front>
<div type="abstract" xml:lang="en">LaAlO
<sub>3</sub>
single crystal doped with Tm
<sup>3+</sup>
ions was investigated. After continuous wave excitation of the
<sup>3</sup>
F
<sub>2</sub>
level (at about 15,115cm
<sup>-1</sup>
) strong violet and UV light was observed which corresponds to the
<sup>1</sup>
D
<sub>2</sub>
<sup>3</sup>
F
<sub>4</sub>
(22,000 cm
<sup>-1</sup>
) and the
<sup>1</sup>
D
<sub>2</sub>
<sup>3</sup>
H
<sub>6</sub>
(27,700 cm
<sup>-1</sup>
) as well as the
<sup>3</sup>
P
<sub>0</sub>
<sup>3</sup>
F
<sub>4</sub>
(28,600 cm
<sup>-1</sup>
) transition, respectively. Emission and excitation spectra of the Stokes and anti-Stokes emission were measured. Excitation spectrum was compared with absorption one. Power dependence of the anti-Stokes emission was recorded and analyzed. Possible mechanisms of three or more photons excited state absorption (ESA) and cross-relaxation are discussed.</div>
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<s0>LaAlO
<sub>3</sub>
single crystal doped with Tm
<sup>3+</sup>
ions was investigated. After continuous wave excitation of the
<sup>3</sup>
F
<sub>2</sub>
level (at about 15,115cm
<sup>-1</sup>
) strong violet and UV light was observed which corresponds to the
<sup>1</sup>
D
<sub>2</sub>
<sup>3</sup>
F
<sub>4</sub>
(22,000 cm
<sup>-1</sup>
) and the
<sup>1</sup>
D
<sub>2</sub>
<sup>3</sup>
H
<sub>6</sub>
(27,700 cm
<sup>-1</sup>
) as well as the
<sup>3</sup>
P
<sub>0</sub>
<sup>3</sup>
F
<sub>4</sub>
(28,600 cm
<sup>-1</sup>
) transition, respectively. Emission and excitation spectra of the Stokes and anti-Stokes emission were measured. Excitation spectrum was compared with absorption one. Power dependence of the anti-Stokes emission was recorded and analyzed. Possible mechanisms of three or more photons excited state absorption (ESA) and cross-relaxation are discussed.</s0>
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<s5>08</s5>
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<s5>09</s5>
</fC03>
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<s0>Cross relaxation</s0>
<s5>09</s5>
</fC03>
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<s0>Relajación cruzada</s0>
<s5>09</s5>
</fC03>
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<s5>10</s5>
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<s5>10</s5>
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<s0>Impureté</s0>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG">
<s0>Impurities</s0>
<s5>11</s5>
</fC03>
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<s0>Addition thulium</s0>
<s5>12</s5>
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<s5>12</s5>
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<s5>15</s5>
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<s0>Monocristal</s0>
<s5>17</s5>
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<s5>17</s5>
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<s4>INC</s4>
<s5>52</s5>
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<fN21>
<s1>245</s1>
</fN21>
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