Near-Infrared Photoluminescence Properties of Endohedral Mono- and Dithulium Metallofullerenes.
Identifieur interne : 000B28 ( Ncbi/Merge ); précédent : 000B27; suivant : 000B29Near-Infrared Photoluminescence Properties of Endohedral Mono- and Dithulium Metallofullerenes.
Auteurs : Zhiyong Wang [Japon] ; Noriko Izumi [Japon] ; Yusuke Nakanishi [Japon] ; Takeshi Koyama [Japon] ; Toshiki Sugai [Japon] ; Masayoshi Tange [Japon] ; Toshiya Okazaki [Japon] ; Hisanori Shinohara [Japon]Source :
- ACS nano [ 1936-086X ] ; 2016.
Abstract
The optical properties of endohedral metallofullerene molecules can be tuned by changing the fullerene size as well as the number of metal atoms inside the fullerene cages. In this work we have synthesized and isolated a series of mono- and dithulium metallofullerenes, including Tm@C82 (isomers I, II, III, IV), Tm@C88 (I-IV), Tm2@C82 (I-III), and (Tm2C2)@C82 (I-III). Near-infrared photoluminescence is observed from the thulium metallofullerenes. By changing the number of Tm ion in the fullerene cage, we have found that one can vary and tune the photoluminescence from 1200 to 1300-2000 nm observed for Tm(2+) (4f(13)) in Tm@C88 and Tm(3+) (4f(12)) in (Tm2C2)@C82, respectively. The photoluminescence intensity depends sensitively on the fullerene cages. (Tm2C2)@C82 (III) exhibits the highest photoluminescence intensity among the three structural isomers because of its large HOMO-LUMO energy gap.
DOI: 10.1021/acsnano.5b07780
PubMed: 27057619
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464-8602</wicri:regionArea><wicri:noRegion>Nagoya 464-8602</wicri:noRegion></affiliation></author><author><name sortKey="Izumi, Noriko" sort="Izumi, Noriko" uniqKey="Izumi N" first="Noriko" last="Izumi">Noriko Izumi</name><affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry and Institute for Advanced Research, Nagoya University , Nagoya 464-8602, Japan.</nlm:affiliation><country xml:lang="fr">Japon</country><wicri:regionArea>Department of Chemistry and Institute for Advanced Research, Nagoya University , Nagoya 464-8602</wicri:regionArea><wicri:noRegion>Nagoya 464-8602</wicri:noRegion></affiliation></author><author><name sortKey="Nakanishi, Yusuke" sort="Nakanishi, Yusuke" uniqKey="Nakanishi Y" first="Yusuke" last="Nakanishi">Yusuke Nakanishi</name><affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry and Institute for Advanced Research, Nagoya University , Nagoya 464-8602, Japan.</nlm:affiliation><country 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Japan.</nlm:affiliation><country xml:lang="fr">Japon</country><wicri:regionArea>Department of Chemistry and Institute for Advanced Research, Nagoya University , Nagoya 464-8602</wicri:regionArea><wicri:noRegion>Nagoya 464-8602</wicri:noRegion></affiliation></author><author><name sortKey="Tange, Masayoshi" sort="Tange, Masayoshi" uniqKey="Tange M" first="Masayoshi" last="Tange">Masayoshi Tange</name><affiliation wicri:level="1"><nlm:affiliation>Nanotube Research Center, National Institute of Advanced Industrial Science and Technology (AIST) , Tsukuba 305-8565, Japan.</nlm:affiliation><country xml:lang="fr">Japon</country><wicri:regionArea>Nanotube Research Center, National Institute of Advanced Industrial Science and Technology (AIST) , Tsukuba 305-8565</wicri:regionArea><wicri:noRegion>Tsukuba 305-8565</wicri:noRegion></affiliation></author><author><name sortKey="Okazaki, Toshiya" sort="Okazaki, Toshiya" uniqKey="Okazaki T" first="Toshiya" last="Okazaki">Toshiya Okazaki</name><affiliation wicri:level="1"><nlm:affiliation>Nanotube Research Center, National Institute of Advanced Industrial Science and Technology (AIST) , Tsukuba 305-8565, Japan.</nlm:affiliation><country xml:lang="fr">Japon</country><wicri:regionArea>Nanotube Research Center, National Institute of Advanced Industrial Science and Technology (AIST) , Tsukuba 305-8565</wicri:regionArea><wicri:noRegion>Tsukuba 305-8565</wicri:noRegion></affiliation></author><author><name sortKey="Shinohara, Hisanori" sort="Shinohara, Hisanori" uniqKey="Shinohara H" first="Hisanori" last="Shinohara">Hisanori Shinohara</name><affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry and Institute for Advanced Research, Nagoya University , Nagoya 464-8602, Japan.</nlm:affiliation><country xml:lang="fr">Japon</country><wicri:regionArea>Department of Chemistry and Institute for Advanced Research, Nagoya University , Nagoya 464-8602</wicri:regionArea><wicri:noRegion>Nagoya 464-8602</wicri:noRegion></affiliation></author></analytic><series><title level="j">ACS nano</title><idno type="eISSN">1936-086X</idno><imprint><date when="2016" type="published">2016</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The optical properties of endohedral metallofullerene molecules can be tuned by changing the fullerene size as well as the number of metal atoms inside the fullerene cages. In this work we have synthesized and isolated a series of mono- and dithulium metallofullerenes, including Tm@C82 (isomers I, II, III, IV), Tm@C88 (I-IV), Tm2@C82 (I-III), and (Tm2C2)@C82 (I-III). Near-infrared photoluminescence is observed from the thulium metallofullerenes. By changing the number of Tm ion in the fullerene cage, we have found that one can vary and tune the photoluminescence from 1200 to 1300-2000 nm observed for Tm(2+) (4f(13)) in Tm@C88 and Tm(3+) (4f(12)) in (Tm2C2)@C82, respectively. The photoluminescence intensity depends sensitively on the fullerene cages. (Tm2C2)@C82 (III) exhibits the highest photoluminescence intensity among the three structural isomers because of its large HOMO-LUMO energy gap.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="In-Data-Review"><PMID Version="1">27057619</PMID><DateCreated><Year>2016</Year><Month>04</Month><Day>26</Day></DateCreated><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1936-086X</ISSN><JournalIssue CitedMedium="Internet"><Volume>10</Volume><Issue>4</Issue><PubDate><Year>2016</Year><Month>Apr</Month><Day>26</Day></PubDate></JournalIssue><Title>ACS nano</Title><ISOAbbreviation>ACS Nano</ISOAbbreviation></Journal><ArticleTitle>Near-Infrared Photoluminescence Properties of Endohedral Mono- and Dithulium Metallofullerenes.</ArticleTitle><Pagination><MedlinePgn>4282-7</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1021/acsnano.5b07780</ELocationID><Abstract><AbstractText>The optical properties of endohedral metallofullerene molecules can be tuned by changing the fullerene size as well as the number of metal atoms inside the fullerene cages. In this work we have synthesized and isolated a series of mono- and dithulium metallofullerenes, including Tm@C82 (isomers I, II, III, IV), Tm@C88 (I-IV), Tm2@C82 (I-III), and (Tm2C2)@C82 (I-III). Near-infrared photoluminescence is observed from the thulium metallofullerenes. By changing the number of Tm ion in the fullerene cage, we have found that one can vary and tune the photoluminescence from 1200 to 1300-2000 nm observed for Tm(2+) (4f(13)) in Tm@C88 and Tm(3+) (4f(12)) in (Tm2C2)@C82, respectively. The photoluminescence intensity depends sensitively on the fullerene cages. (Tm2C2)@C82 (III) exhibits the highest photoluminescence intensity among the three structural isomers because of its large HOMO-LUMO energy gap.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Wang</LastName><ForeName>Zhiyong</ForeName><Initials>Z</Initials><AffiliationInfo><Affiliation>Department of Chemistry and Institute for Advanced Research, Nagoya University , Nagoya 464-8602, Japan.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Izumi</LastName><ForeName>Noriko</ForeName><Initials>N</Initials><AffiliationInfo><Affiliation>Department of Chemistry and Institute for Advanced Research, Nagoya University , Nagoya 464-8602, Japan.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Nakanishi</LastName><ForeName>Yusuke</ForeName><Initials>Y</Initials><AffiliationInfo><Affiliation>Department of Chemistry and Institute for Advanced Research, Nagoya University , Nagoya 464-8602, Japan.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Koyama</LastName><ForeName>Takeshi</ForeName><Initials>T</Initials><AffiliationInfo><Affiliation>Department of Applied Physics, Nagoya University , Nagoya 464-8603, Japan.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Sugai</LastName><ForeName>Toshiki</ForeName><Initials>T</Initials><AffiliationInfo><Affiliation>Department of Chemistry and Institute for Advanced Research, Nagoya University , Nagoya 464-8602, Japan.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Tange</LastName><ForeName>Masayoshi</ForeName><Initials>M</Initials><AffiliationInfo><Affiliation>Nanotube Research Center, National Institute of Advanced Industrial Science and Technology (AIST) , Tsukuba 305-8565, Japan.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Okazaki</LastName><ForeName>Toshiya</ForeName><Initials>T</Initials><AffiliationInfo><Affiliation>Nanotube Research Center, National Institute of Advanced Industrial Science and Technology (AIST) , Tsukuba 305-8565, Japan.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Shinohara</LastName><ForeName>Hisanori</ForeName><Initials>H</Initials><AffiliationInfo><Affiliation>Department of Chemistry and Institute for Advanced Research, Nagoya University , Nagoya 464-8602, Japan.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2016</Year><Month>04</Month><Day>11</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>ACS Nano</MedlineTA><NlmUniqueID>101313589</NlmUniqueID><ISSNLinking>1936-0851</ISSNLinking></MedlineJournalInfo><CitationSubset>IM</CitationSubset><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">fullerene</Keyword><Keyword MajorTopicYN="N">lanthanide</Keyword><Keyword MajorTopicYN="N">metallofullerene</Keyword><Keyword MajorTopicYN="N">photoluminescence</Keyword><Keyword MajorTopicYN="N">thulium</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="aheadofprint"><Year>2016</Year><Month>4</Month><Day>11</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2016</Year><Month>4</Month><Day>9</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2016</Year><Month>4</Month><Day>9</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2016</Year><Month>4</Month><Day>9</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">27057619</ArticleId><ArticleId IdType="doi">10.1021/acsnano.5b07780</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>Japon</li></country></list><tree><country name="Japon"><noRegion><name sortKey="Wang, Zhiyong" sort="Wang, Zhiyong" uniqKey="Wang Z" first="Zhiyong" last="Wang">Zhiyong Wang</name></noRegion><name sortKey="Izumi, Noriko" sort="Izumi, Noriko" uniqKey="Izumi N" first="Noriko" last="Izumi">Noriko Izumi</name><name sortKey="Koyama, Takeshi" sort="Koyama, Takeshi" uniqKey="Koyama T" first="Takeshi" last="Koyama">Takeshi Koyama</name><name sortKey="Nakanishi, Yusuke" sort="Nakanishi, Yusuke" uniqKey="Nakanishi Y" first="Yusuke" last="Nakanishi">Yusuke Nakanishi</name><name sortKey="Okazaki, Toshiya" sort="Okazaki, Toshiya" uniqKey="Okazaki T" first="Toshiya" last="Okazaki">Toshiya Okazaki</name><name sortKey="Shinohara, Hisanori" sort="Shinohara, Hisanori" uniqKey="Shinohara H" first="Hisanori" last="Shinohara">Hisanori Shinohara</name><name sortKey="Sugai, Toshiki" sort="Sugai, Toshiki" uniqKey="Sugai T" first="Toshiki" last="Sugai">Toshiki Sugai</name><name sortKey="Tange, Masayoshi" sort="Tange, Masayoshi" uniqKey="Tange M" first="Masayoshi" last="Tange">Masayoshi Tange</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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