Linking the thermodynamic temperature to an optical frequency: recent advances in Doppler broadening thermometry
Identifieur interne : 000B15 ( Ncbi/Merge ); précédent : 000B14; suivant : 000B16Linking the thermodynamic temperature to an optical frequency: recent advances in Doppler broadening thermometry
Auteurs : Livio Gianfrani [Italie]Source :
- Philosophical transactions. Series A, Mathematical, physical, and engineering sciences [ 1364-503X ] ; 2016.
Abstract
Laser spectroscopy in the linear regime of radiation–matter interaction is a powerful tool for measuring thermodynamic quantities in a gas at thermodynamic equilibrium. In particular, the Doppler effect can be considered a gift of nature, linking the thermal energy to an optical frequency, namely the line centre frequency of an atomic or molecular spectral line. This is the basis of a relatively new method of primary gas thermometry, known as Doppler broadening thermometry (DBT). This paper reports on the efforts that have been carried out, in the last decade, worldwide, to the end of making DBT competitive with more consolidated and accurate methodologies, such as acoustic gas thermometry and dielectric constant gas thermometry. The main requirements for low-uncertainty DBT, of both theoretical and technical nature, will be discussed, with a special focus on those related to the line shape model and to the frequency scale. A deep comparison among the different molecules that have been selected in successful DBT implementations is also reported. Finally, for the first time, to the best of my knowledge, the influence of refractive index effects is discussed.
Url:
DOI: 10.1098/rsta.2015.0047
PubMed: 26903093
PubMed Central: 4760123
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Series A, Mathematical, physical, and engineering sciences</title><idno type="ISSN">1364-503X</idno><idno type="eISSN">1471-2962</idno><imprint><date when="2016">2016</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>Laser spectroscopy in the linear regime of radiation–matter interaction is a powerful tool for measuring thermodynamic quantities in a gas at thermodynamic equilibrium. In particular, the Doppler effect can be considered a gift of nature, linking the thermal energy to an optical frequency, namely the line centre frequency of an atomic or molecular spectral line. This is the basis of a relatively new method of primary gas thermometry, known as Doppler broadening thermometry (DBT). This paper reports on the efforts that have been carried out, in the last decade, worldwide, to the end of making DBT competitive with more consolidated and accurate methodologies, such as acoustic gas thermometry and dielectric constant gas thermometry. The main requirements for low-uncertainty DBT, of both theoretical and technical nature, will be discussed, with a special focus on those related to the line shape model and to the frequency scale. A deep comparison among the different molecules that have been selected in successful DBT implementations is also reported. Finally, for the first time, to the best of my knowledge, the influence of refractive index effects is discussed.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct><analytic><author><name sortKey="Tennyson, J" uniqKey="Tennyson J">J Tennyson</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Polyansky, O" uniqKey="Polyansky O">O Polyansky</name></author><author><name sortKey="Ovsyannikov, Ri" uniqKey="Ovsyannikov R">RI Ovsyannikov</name></author><author><name sortKey="Kyuberis, Aa" uniqKey="Kyuberis A">AA Kyuberis</name></author><author><name sortKey="Lodi, L" uniqKey="Lodi L">L Lodi</name></author><author><name sortKey="Tennyson, J" uniqKey="Tennyson J">J Tennyson</name></author><author><name sortKey="Zobov, Nf" uniqKey="Zobov N">NF Zobov</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Ghysels, M" uniqKey="Ghysels M">M Ghysels</name></author><author><name sortKey="Durry, G" uniqKey="Durry G">G 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<front><journal-meta><journal-id journal-id-type="nlm-ta">Philos Trans A Math Phys Eng Sci</journal-id><journal-id journal-id-type="iso-abbrev">Philos Trans A Math Phys Eng Sci</journal-id><journal-id journal-id-type="publisher-id">RSTA</journal-id><journal-id journal-id-type="hwp">roypta</journal-id><journal-title-group><journal-title>Philosophical transactions. Series A, Mathematical, physical, and engineering sciences</journal-title></journal-title-group><issn pub-type="ppub">1364-503X</issn><issn pub-type="epub">1471-2962</issn><publisher><publisher-name>The Royal Society Publishing</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="pmid">26903093</article-id><article-id pub-id-type="pmc">4760123</article-id><article-id pub-id-type="doi">10.1098/rsta.2015.0047</article-id><article-id pub-id-type="publisher-id">rsta20150047</article-id><article-categories><subj-group subj-group-type="hwp-journal-coll"><subject>1009</subject><subject>13</subject><subject>141</subject><subject>185</subject></subj-group><subj-group subj-group-type="heading"><subject>Articles</subject></subj-group><subj-group subj-group-type="leader"><subject>Review Articles</subject></subj-group></article-categories><title-group><article-title>Linking the thermodynamic temperature to an optical frequency: recent advances in Doppler broadening thermometry</article-title><alt-title alt-title-type="short">Temperature and frequency</alt-title></title-group><contrib-group><contrib contrib-type="author"><contrib-id contrib-id-type="orcid" authenticated="false">http://orcid.org/0000-0002-2241-7603</contrib-id><name><surname>Gianfrani</surname><given-names>Livio</given-names></name><xref ref-type="aff" rid="af1">1</xref><xref ref-type="aff" rid="af2">2</xref><xref ref-type="corresp" rid="cor1"></xref></contrib></contrib-group><aff id="af1"><label>1</label><addr-line>Dipartimento di Matematica e Fisica</addr-line>,<institution>Seconda Università degli studi di Napoli</institution>,<addr-line>Caserta, Italy</addr-line></aff><aff id="af2"><label>2</label><addr-line>INRIM, Istituto Nazionale di Ricerca Metrologica</addr-line>,<addr-line>Torino, Italy</addr-line></aff><author-notes><corresp id="cor1">e-mail: <email>livio.gianfrani@unina2.it</email></corresp><fn fn-type="other"><p>One contribution of 16 to a Theo Murphy meeting isssue ‘<ext-link ext-link-type="uri" xlink:href="http://rsta.royalsocietypublishing.org/content/374/2064.toc">Towards implementing the new kelvin</ext-link>’.</p></fn></author-notes><pub-date pub-type="ppub"><day>28</day><month>3</month><year>2016</year></pub-date><pub-date pub-type="pmc-release"><day>28</day><month>3</month><year>2016</year></pub-date><pmc-comment> PMC Release delay is 0 months and 0 days and was based on the
<volume>374</volume><issue>2064</issue><issue-title>Theo Murphy meeting issue ‘Towards implementing the new kelvin’ organised and edited by Graham Machin, Joachim Fischer, Peter Hänggi and Martin Trusler</issue-title><elocation-id>20150047</elocation-id><history><date date-type="accepted"><day>3</day><month>11</month><year>2015</year></date></history><permissions><copyright-statement>© 2016 The Authors.</copyright-statement><copyright-year>2016</copyright-year><license license-type="open-access" specific-use="vor" xlink:href="http://creativecommons.org/licenses/by/4.0/"><license-p>Published by the Royal Society under the terms of the Creative Commons Attribution License <ext-link ext-link-type="uri" xlink:href="http://creativecommons.org/licenses/by/4.0/">http://creativecommons.org/licenses/by/4.0/</ext-link>, which permits unrestricted use, provided the original author and source are credited.</license-p></license></permissions><self-uri content-type="pdf" xlink:href="rsta20150047.pdf"></self-uri><abstract><p>Laser spectroscopy in the linear regime of radiation–matter interaction is a powerful tool for measuring thermodynamic quantities in a gas at thermodynamic equilibrium. In particular, the Doppler effect can be considered a gift of nature, linking the thermal energy to an optical frequency, namely the line centre frequency of an atomic or molecular spectral line. This is the basis of a relatively new method of primary gas thermometry, known as Doppler broadening thermometry (DBT). This paper reports on the efforts that have been carried out, in the last decade, worldwide, to the end of making DBT competitive with more consolidated and accurate methodologies, such as acoustic gas thermometry and dielectric constant gas thermometry. The main requirements for low-uncertainty DBT, of both theoretical and technical nature, will be discussed, with a special focus on those related to the line shape model and to the frequency scale. A deep comparison among the different molecules that have been selected in successful DBT implementations is also reported. Finally, for the first time, to the best of my knowledge, the influence of refractive index effects is discussed.</p></abstract><kwd-group><kwd>laser absorption spectroscopy</kwd><kwd>Doppler effect</kwd><kwd>spectral line shapes</kwd><kwd>primary gas thermometry</kwd><kwd>molecular spectra</kwd><kwd>collisional effects</kwd></kwd-group><funding-group specific-use="FundRef"><award-group><funding-source><institution-wrap><institution>EMRP</institution></institution-wrap></funding-source><award-id>SIB01-REG3 and SIB01-REG4</award-id></award-group></funding-group><custom-meta-group><custom-meta><meta-name>cover-date</meta-name><meta-value>March 28, 2016</meta-value></custom-meta></custom-meta-group></article-meta></front></pmc><affiliations><list><country><li>Italie</li></country></list><tree><country name="Italie"><noRegion><name sortKey="Gianfrani, Livio" sort="Gianfrani, Livio" uniqKey="Gianfrani L" first="Livio" last="Gianfrani">Livio Gianfrani</name></noRegion><name sortKey="Gianfrani, Livio" sort="Gianfrani, Livio" uniqKey="Gianfrani L" first="Livio" last="Gianfrani">Livio Gianfrani</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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