Direct synthesis of hexagonal NaGdF₄ nanocrystals from a single-source precursor: upconverting NaGdF₄ :Yb³⁺ ,Tm³⁺ and its composites with TiO₂ for near-IR-driven photocatalysis.
Identifieur interne : 000848 ( Ncbi/Merge ); précédent : 000847; suivant : 000849Direct synthesis of hexagonal NaGdF₄ nanocrystals from a single-source precursor: upconverting NaGdF₄ :Yb³⁺ ,Tm³⁺ and its composites with TiO₂ for near-IR-driven photocatalysis.
Auteurs : Ying Chen ; Shashank Mishra ; Gilles Ledoux ; Erwann Jeanneau ; Marlene Daniel ; Jinlong Zhang ; Stéphane DanieleSource :
- Chemistry, an Asian journal [ 1861-471X ] ; 2014.
Descripteurs français
- KwdFr :
- MESH :
- synthèse chimique : Fluorures.
- Catalyse, Fluorures, Gadolinium, Nanoparticules, Processus photochimiques, Rayons infrarouges, Thulium, Titane, Ytterbium.
English descriptors
- KwdEn :
- MESH :
- chemical , chemical synthesis : Fluorides.
- chemical , chemistry : Fluorides, Gadolinium, Thulium, Titanium, Ytterbium.
- chemistry : Nanoparticles.
- Catalysis, Infrared Rays, Photochemical Processes.
Abstract
A novel single-source precursor NaGd(TFA)4 (diglyme) (TFA=trifluoroacetate) was synthesized, characterized thoroughly, and used to obtain the hexagonal phase of NaGdF4 nanoparticles as an efficient matrix for lanthanide-doped upconverting nanocrystals (NCs) that convert near-infrared radiation into shorter-wavelength UV/visible light. These NCs were then used to prepare well-characterized TiO2@NaGdF4:Yb(3+),Tm(3+) nanocomposites to extend the absorption range of the TiO2 photocatalyst from the UV to the IR region. While the visible/near IR part of the photoluminescent spectra remains almost unaffected by the presence of TiO2, the UV part is strongly quenched due to the absorption of TiO2 above its gap at approximately 380 nm by energy transfer or FRET. Preliminary results on the photocatalytic activity of the above obtained nanocomposites are presented.
DOI: 10.1002/asia.201402347
PubMed: 24910325
Links toward previous steps (curation, corpus...)
- to stream PubMed, to step Corpus: 000173
- to stream PubMed, to step Curation: 000173
- to stream PubMed, to step Checkpoint: 000173
Links to Exploration step
pubmed:24910325Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Direct synthesis of hexagonal NaGdF₄ nanocrystals from a single-source precursor: upconverting NaGdF₄ :Yb³⁺ ,Tm³⁺ and its composites with TiO₂ for near-IR-driven photocatalysis.</title><author><name sortKey="Chen, Ying" sort="Chen, Ying" uniqKey="Chen Y" first="Ying" last="Chen">Ying Chen</name><affiliation><nlm:affiliation>University of Lyon1, IRCELYON, 2 Avenue A. Einstein, 69626 Villeurbanne (France), Fax: (+33) 472445399; Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237 (China).</nlm:affiliation><wicri:noCountry code="subField">Shanghai 200237 (China)</wicri:noCountry></affiliation></author><author><name sortKey="Mishra, Shashank" sort="Mishra, Shashank" uniqKey="Mishra S" first="Shashank" last="Mishra">Shashank Mishra</name></author><author><name sortKey="Ledoux, Gilles" sort="Ledoux, Gilles" uniqKey="Ledoux G" first="Gilles" last="Ledoux">Gilles Ledoux</name></author><author><name sortKey="Jeanneau, Erwann" sort="Jeanneau, Erwann" uniqKey="Jeanneau E" first="Erwann" last="Jeanneau">Erwann Jeanneau</name></author><author><name sortKey="Daniel, Marlene" sort="Daniel, Marlene" uniqKey="Daniel M" first="Marlene" last="Daniel">Marlene Daniel</name></author><author><name sortKey="Zhang, Jinlong" sort="Zhang, Jinlong" uniqKey="Zhang J" first="Jinlong" last="Zhang">Jinlong Zhang</name></author><author><name sortKey="Daniele, Stephane" sort="Daniele, Stephane" uniqKey="Daniele S" first="Stéphane" last="Daniele">Stéphane Daniele</name></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2014">2014</date><idno type="RBID">pubmed:24910325</idno><idno type="pmid">24910325</idno><idno type="doi">10.1002/asia.201402347</idno><idno type="wicri:Area/PubMed/Corpus">000173</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000173</idno><idno type="wicri:Area/PubMed/Curation">000173</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">000173</idno><idno type="wicri:Area/PubMed/Checkpoint">000173</idno><idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">000173</idno><idno type="wicri:Area/Ncbi/Merge">000848</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Direct synthesis of hexagonal NaGdF₄ nanocrystals from a single-source precursor: upconverting NaGdF₄ :Yb³⁺ ,Tm³⁺ and its composites with TiO₂ for near-IR-driven photocatalysis.</title><author><name sortKey="Chen, Ying" sort="Chen, Ying" uniqKey="Chen Y" first="Ying" last="Chen">Ying Chen</name><affiliation><nlm:affiliation>University of Lyon1, IRCELYON, 2 Avenue A. Einstein, 69626 Villeurbanne (France), Fax: (+33) 472445399; Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237 (China).</nlm:affiliation><wicri:noCountry code="subField">Shanghai 200237 (China)</wicri:noCountry></affiliation></author><author><name sortKey="Mishra, Shashank" sort="Mishra, Shashank" uniqKey="Mishra S" first="Shashank" last="Mishra">Shashank Mishra</name></author><author><name sortKey="Ledoux, Gilles" sort="Ledoux, Gilles" uniqKey="Ledoux G" first="Gilles" last="Ledoux">Gilles Ledoux</name></author><author><name sortKey="Jeanneau, Erwann" sort="Jeanneau, Erwann" uniqKey="Jeanneau E" first="Erwann" last="Jeanneau">Erwann Jeanneau</name></author><author><name sortKey="Daniel, Marlene" sort="Daniel, Marlene" uniqKey="Daniel M" first="Marlene" last="Daniel">Marlene Daniel</name></author><author><name sortKey="Zhang, Jinlong" sort="Zhang, Jinlong" uniqKey="Zhang J" first="Jinlong" last="Zhang">Jinlong Zhang</name></author><author><name sortKey="Daniele, Stephane" sort="Daniele, Stephane" uniqKey="Daniele S" first="Stéphane" last="Daniele">Stéphane Daniele</name></author></analytic><series><title level="j">Chemistry, an Asian journal</title><idno type="eISSN">1861-471X</idno><imprint><date when="2014" type="published">2014</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Catalysis</term><term>Fluorides (chemical synthesis)</term><term>Fluorides (chemistry)</term><term>Gadolinium (chemistry)</term><term>Infrared Rays</term><term>Nanoparticles (chemistry)</term><term>Photochemical Processes</term><term>Thulium (chemistry)</term><term>Titanium (chemistry)</term><term>Ytterbium (chemistry)</term></keywords><keywords scheme="KwdFr" xml:lang="fr"><term>Catalyse</term><term>Fluorures ()</term><term>Fluorures (synthèse chimique)</term><term>Gadolinium ()</term><term>Nanoparticules ()</term><term>Processus photochimiques</term><term>Rayons infrarouges</term><term>Thulium ()</term><term>Titane ()</term><term>Ytterbium ()</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemical synthesis" xml:lang="en"><term>Fluorides</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Fluorides</term><term>Gadolinium</term><term>Thulium</term><term>Titanium</term><term>Ytterbium</term></keywords><keywords scheme="MESH" qualifier="chemistry" xml:lang="en"><term>Nanoparticles</term></keywords><keywords scheme="MESH" qualifier="synthèse chimique" xml:lang="fr"><term>Fluorures</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Catalysis</term><term>Infrared Rays</term><term>Photochemical Processes</term></keywords><keywords scheme="MESH" xml:lang="fr"><term>Catalyse</term><term>Fluorures</term><term>Gadolinium</term><term>Nanoparticules</term><term>Processus photochimiques</term><term>Rayons infrarouges</term><term>Thulium</term><term>Titane</term><term>Ytterbium</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">A novel single-source precursor NaGd(TFA)4 (diglyme) (TFA=trifluoroacetate) was synthesized, characterized thoroughly, and used to obtain the hexagonal phase of NaGdF4 nanoparticles as an efficient matrix for lanthanide-doped upconverting nanocrystals (NCs) that convert near-infrared radiation into shorter-wavelength UV/visible light. These NCs were then used to prepare well-characterized TiO2@NaGdF4:Yb(3+),Tm(3+) nanocomposites to extend the absorption range of the TiO2 photocatalyst from the UV to the IR region. While the visible/near IR part of the photoluminescent spectra remains almost unaffected by the presence of TiO2, the UV part is strongly quenched due to the absorption of TiO2 above its gap at approximately 380 nm by energy transfer or FRET. Preliminary results on the photocatalytic activity of the above obtained nanocomposites are presented.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="MEDLINE"><PMID Version="1">24910325</PMID><DateCreated><Year>2014</Year><Month>08</Month><Day>26</Day></DateCreated><DateCompleted><Year>2015</Year><Month>06</Month><Day>01</Day></DateCompleted><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1861-471X</ISSN><JournalIssue CitedMedium="Internet"><Volume>9</Volume><Issue>9</Issue><PubDate><Year>2014</Year><Month>Sep</Month></PubDate></JournalIssue><Title>Chemistry, an Asian journal</Title><ISOAbbreviation>Chem Asian J</ISOAbbreviation></Journal><ArticleTitle>Direct synthesis of hexagonal NaGdF₄ nanocrystals from a single-source precursor: upconverting NaGdF₄ :Yb³⁺ ,Tm³⁺ and its composites with TiO₂ for near-IR-driven photocatalysis.</ArticleTitle><Pagination><MedlinePgn>2415-21</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1002/asia.201402347</ELocationID><Abstract><AbstractText>A novel single-source precursor NaGd(TFA)4 (diglyme) (TFA=trifluoroacetate) was synthesized, characterized thoroughly, and used to obtain the hexagonal phase of NaGdF4 nanoparticles as an efficient matrix for lanthanide-doped upconverting nanocrystals (NCs) that convert near-infrared radiation into shorter-wavelength UV/visible light. These NCs were then used to prepare well-characterized TiO2@NaGdF4:Yb(3+),Tm(3+) nanocomposites to extend the absorption range of the TiO2 photocatalyst from the UV to the IR region. While the visible/near IR part of the photoluminescent spectra remains almost unaffected by the presence of TiO2, the UV part is strongly quenched due to the absorption of TiO2 above its gap at approximately 380 nm by energy transfer or FRET. Preliminary results on the photocatalytic activity of the above obtained nanocomposites are presented.</AbstractText><CopyrightInformation>© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</CopyrightInformation></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Chen</LastName><ForeName>Ying</ForeName><Initials>Y</Initials><AffiliationInfo><Affiliation>University of Lyon1, IRCELYON, 2 Avenue A. Einstein, 69626 Villeurbanne (France), Fax: (+33) 472445399; Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237 (China).</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Mishra</LastName><ForeName>Shashank</ForeName><Initials>S</Initials></Author><Author ValidYN="Y"><LastName>Ledoux</LastName><ForeName>Gilles</ForeName><Initials>G</Initials></Author><Author ValidYN="Y"><LastName>Jeanneau</LastName><ForeName>Erwann</ForeName><Initials>E</Initials></Author><Author ValidYN="Y"><LastName>Daniel</LastName><ForeName>Marlene</ForeName><Initials>M</Initials></Author><Author ValidYN="Y"><LastName>Zhang</LastName><ForeName>Jinlong</ForeName><Initials>J</Initials></Author><Author ValidYN="Y"><LastName>Daniele</LastName><ForeName>Stéphane</ForeName><Initials>S</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2014</Year><Month>06</Month><Day>06</Day></ArticleDate></Article><MedlineJournalInfo><Country>Germany</Country><MedlineTA>Chem Asian J</MedlineTA><NlmUniqueID>101294643</NlmUniqueID><ISSNLinking>1861-471X</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>15FIX9V2JP</RegistryNumber><NameOfSubstance UI="C009495">titanium dioxide</NameOfSubstance></Chemical><Chemical><RegistryNumber>8RKC5ATI4P</RegistryNumber><NameOfSubstance UI="D013932">Thulium</NameOfSubstance></Chemical><Chemical><RegistryNumber>AU0V1LM3JT</RegistryNumber><NameOfSubstance UI="D005682">Gadolinium</NameOfSubstance></Chemical><Chemical><RegistryNumber>D1JT611TNE</RegistryNumber><NameOfSubstance UI="D014025">Titanium</NameOfSubstance></Chemical><Chemical><RegistryNumber>MNQ4O4WSI1</RegistryNumber><NameOfSubstance UI="D015018">Ytterbium</NameOfSubstance></Chemical><Chemical><RegistryNumber>Q80VPU408O</RegistryNumber><NameOfSubstance UI="D005459">Fluorides</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName MajorTopicYN="N" UI="D002384">Catalysis</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D005459">Fluorides</DescriptorName><QualifierName MajorTopicYN="Y" UI="Q000138">chemical synthesis</QualifierName><QualifierName MajorTopicYN="Y" UI="Q000737">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D005682">Gadolinium</DescriptorName><QualifierName MajorTopicYN="Y" UI="Q000737">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="Y" UI="D007259">Infrared Rays</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D053758">Nanoparticles</DescriptorName><QualifierName MajorTopicYN="Y" UI="Q000737">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D055668">Photochemical Processes</DescriptorName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D013932">Thulium</DescriptorName><QualifierName MajorTopicYN="Y" UI="Q000737">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D014025">Titanium</DescriptorName><QualifierName MajorTopicYN="Y" UI="Q000737">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName MajorTopicYN="N" UI="D015018">Ytterbium</DescriptorName><QualifierName MajorTopicYN="Y" UI="Q000737">chemistry</QualifierName></MeshHeading></MeshHeadingList><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">doping</Keyword><Keyword MajorTopicYN="N">fluorides</Keyword><Keyword MajorTopicYN="N">nanoparticles</Keyword><Keyword MajorTopicYN="N">photocatalysis</Keyword><Keyword MajorTopicYN="N">upconversion</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2014</Year><Month>4</Month><Day>8</Day></PubMedPubDate><PubMedPubDate PubStatus="aheadofprint"><Year>2014</Year><Month>6</Month><Day>6</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2014</Year><Month>6</Month><Day>10</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2014</Year><Month>6</Month><Day>10</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2015</Year><Month>6</Month><Day>2</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">24910325</ArticleId><ArticleId IdType="doi">10.1002/asia.201402347</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list></list><tree><noCountry><name sortKey="Chen, Ying" sort="Chen, Ying" uniqKey="Chen Y" first="Ying" last="Chen">Ying Chen</name><name sortKey="Daniel, Marlene" sort="Daniel, Marlene" uniqKey="Daniel M" first="Marlene" last="Daniel">Marlene Daniel</name><name sortKey="Daniele, Stephane" sort="Daniele, Stephane" uniqKey="Daniele S" first="Stéphane" last="Daniele">Stéphane Daniele</name><name sortKey="Jeanneau, Erwann" sort="Jeanneau, Erwann" uniqKey="Jeanneau E" first="Erwann" last="Jeanneau">Erwann Jeanneau</name><name sortKey="Ledoux, Gilles" sort="Ledoux, Gilles" uniqKey="Ledoux G" first="Gilles" last="Ledoux">Gilles Ledoux</name><name sortKey="Mishra, Shashank" sort="Mishra, Shashank" uniqKey="Mishra S" first="Shashank" last="Mishra">Shashank Mishra</name><name sortKey="Zhang, Jinlong" sort="Zhang, Jinlong" uniqKey="Zhang J" first="Jinlong" last="Zhang">Jinlong Zhang</name></noCountry></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/ThuliumV1/Data/Ncbi/Merge
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000848 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Ncbi/Merge/biblio.hfd -nk 000848 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Terre
|area= ThuliumV1
|flux= Ncbi
|étape= Merge
|type= RBID
|clé= pubmed:24910325
|texte= Direct synthesis of hexagonal NaGdF₄ nanocrystals from a single-source precursor: upconverting NaGdF₄ :Yb³⁺ ,Tm³⁺ and its composites with TiO₂ for near-IR-driven photocatalysis.
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Ncbi/Merge/RBID.i -Sk "pubmed:24910325" \
| HfdSelect -Kh $EXPLOR_AREA/Data/Ncbi/Merge/biblio.hfd \
| NlmPubMed2Wicri -a ThuliumV1
| This area was generated with Dilib version V0.6.21. |  |