Reversible C-C coupling in phenanthroline complexes of divalent samarium and thulium.
Identifieur interne : 000949 ( Ncbi/Curation ); précédent : 000948; suivant : 000950Reversible C-C coupling in phenanthroline complexes of divalent samarium and thulium.
Auteurs : Grégory Nocton [France] ; Louis RicardSource :
- Chemical communications (Cambridge, England) [ 1364-548X ] ; 2015.
Abstract
The reaction of a series of organolanthanide fragments of samarium and thulium with phenanthroline is reported. All adducts couple in the 4-position of the phenanthroline ligand to yield the 4-4' dimers when they crystallize. The analysis of the solution structure revealed a thermally reversible C-C coupling in all cases.
DOI: 10.1039/c5cc00289c
PubMed: 25634655
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