Thulium nickel/lithium distannide, TmNi1−xLixSn2 (x = 0.035)
Identifieur interne : 000786 ( Ncbi/Curation ); précédent : 000785; suivant : 000787Thulium nickel/lithium distannide, TmNi1−xLixSn2 (x = 0.035)
Auteurs : Andrij Stetskiv [Ukraine] ; Ivan Tarasiuk [Ukraine] ; Renata Misztal [Pologne] ; Volodymyr Pavlyuk [Ukraine, Pologne]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.
Abstract
The quaternary thulium nickel/lithium distannide, TmNi1−
Url:
DOI: 10.1107/S1600536813027335
PubMed: 24454012
PubMed Central: 3884236
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PMC:3884236Le document en format XML
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</sub>
Li<sub><italic>x</italic>
</sub>
Sn<sub>2</sub>
(<italic>x</italic>
= 0.035)</title>
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<country xml:lang="fr">Ukraine</country>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Thulium nickel/lithium distannide, TmNi<sub>1−<italic>x</italic>
</sub>
Li<sub><italic>x</italic>
</sub>
Sn<sub>2</sub>
(<italic>x</italic>
= 0.035)</title>
<author><name sortKey="Stetskiv, Andrij" sort="Stetskiv, Andrij" uniqKey="Stetskiv A" first="Andrij" last="Stetskiv">Andrij Stetskiv</name>
<affiliation wicri:level="1"><nlm:aff id="a">Ivano-Frankivsk National Medical University, Department of Chemistry, Galytska str. 2, 76018 Ivano-Frankivsk,<country>Ukraine</country>
</nlm:aff>
<country xml:lang="fr">Ukraine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Tarasiuk, Ivan" sort="Tarasiuk, Ivan" uniqKey="Tarasiuk I" first="Ivan" last="Tarasiuk">Ivan Tarasiuk</name>
<affiliation wicri:level="1"><nlm:aff id="b">Department of Inorganic Chemistry, Ivan Franko Lviv National University, Kyryla and Mefodiya str. 6, 79005 Lviv,<country>Ukraine</country>
</nlm:aff>
<country xml:lang="fr">Ukraine</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Misztal, Renata" sort="Misztal, Renata" uniqKey="Misztal R" first="Renata" last="Misztal">Renata Misztal</name>
<affiliation wicri:level="1"><nlm:aff id="c">Institute of Chemistry, Environment Protection and Biotechnology, Jan Dlugosz University, al. Armii Krajowej 13/15, 42-200 Czestochowa,<country>Poland</country>
</nlm:aff>
<country xml:lang="fr">Pologne</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Pavlyuk, Volodymyr" sort="Pavlyuk, Volodymyr" uniqKey="Pavlyuk V" first="Volodymyr" last="Pavlyuk">Volodymyr Pavlyuk</name>
<affiliation wicri:level="1"><nlm:aff id="b">Department of Inorganic Chemistry, Ivan Franko Lviv National University, Kyryla and Mefodiya str. 6, 79005 Lviv,<country>Ukraine</country>
</nlm:aff>
<country xml:lang="fr">Ukraine</country>
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</nlm:aff>
<country xml:lang="fr">Pologne</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<front><div type="abstract" xml:lang="en"><p>The quaternary thulium nickel/lithium distannide, TmNi<sub>1−<italic>x</italic>
</sub>
Li<sub><italic>x</italic>
</sub>
Sn<sub>2</sub>
(<italic>x</italic>
= 0.035), crystallizes in the orthorhombic LuNiSn<sub>2</sub>
structure type. The asymmetric unit contains three Tm sites, six Sn sites, two Ni sites and one Ni/Li site [relative occupancies = 0.895 (8):0.185 (8)]. Site symmetries are .<italic>m</italic>
. for all atoms. The 17-, 18- and 19-vertex distorted pseudo-Frank–Kasper polyhedra are typical for all Tm atoms. Four Sn atoms are enclosed in a 12-vertex deformed cubooctahedron, and another Sn atom is enclosed in a pentagonal prism with three added atoms. A tricapped trigonal prism is typical for a further Sn atom. The coordination number for all Ni atoms and Ni/Li statistical mixtures is 12 (fourcapped trigonal prism [Ni/LiTm<sub>5</sub>
Sn<sub>5</sub>
]). Tm atoms form the base of a prism and Ni/Li atoms are at the centres of the side faces of an [SnTm<sub>6</sub>
Ni/Li<sub>3</sub>
] prism. These isolated prisms are implemented into three-dimensional-nets built out of Sn atoms. Electronic structure calculations using TB-LMTO-ASA suggest that the Tm and Ni/Li atoms form positively charged <italic>n</italic>
[TmNi/Li]<sup><italic>m</italic>
+</sup>
polycations which compensate the negative charge of 2<italic>n</italic>
[Sn]<sup><italic>m</italic>
−</sup>
polyanions. Analysis of the interatomic distances and electronic structure calculations indicate the dominance of a metallic type of bonding.</p>
</div>
</front>
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