Rare-earth-metal dialkynyl dimethyl aluminates.
Identifieur interne : 000676 ( Ncbi/Curation ); précédent : 000675; suivant : 000677Rare-earth-metal dialkynyl dimethyl aluminates.
Auteurs : Anja Nieland [Allemagne] ; Andreas Mix ; Beate Neumann ; Hans-Georg Stammler ; Norbert W. MitzelSource :
- Chemistry (Weinheim an der Bergstrasse, Germany) [ 1521-3765 ] ; 2013.
Abstract
A new class of rare-earth-metal alkynyl complexes has been prepared. The reactions of the tris(tetramethylaluminate)s of lanthanum, praseodymium, samarium, yttrium, holmium, and thulium, [Ln(AlMe₄)₃], with phenylacetylene afforded compounds [Ln{(μ-C≡CPh)₂AlMe₂}₃] (Ln=La (1), Pr (2), Sm (3), Y (4), Ho (5), Tm (6)). All of these compounds have been characterized by NMR spectroscopy, X-ray crystallography, and by elemental analysis. NMR spectroscopic studies of the series of para- magnetic compounds [Ln(AlMe₄)₃] and [Ln{(μ-C≡CPh)₂AlMe₂}₃] have also been performed.
DOI: 10.1002/chem.201300465
PubMed: 23616205
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