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Reforming of Pd-lanthanide catalysts

Identifieur interne : 002C79 ( Main/Merge ); précédent : 002C78; suivant : 002C80

Reforming of Pd-lanthanide catalysts

Auteurs : N. Mahalakshmi Sita [Inde]

Source :

RBID : Pascal:97-0441293

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English descriptors

Abstract

The reforming reactions of cyclohexane, methyl cyclopentane and n-heptane on the Pd/γ-Al2O3 and Pd-Ln/γ-Al2O3 (Ln=Dy, Ho, Tm) catalysts have been investigated. The results demonstrate that Pd-Ln/γ-Al2O3 catalysts evince high activity and stability compared to Pd/γ-Al2O3 catalysts. Owing to the different lanthanide content in the catalysts, the aromatisation and isomerization yields are different in the reforming reactions of n-heptane and cyclopentane. It is interesting to investigate the optimum content of lanthanides which gives the maximum aromatisation and isomerization yield.

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Pascal:97-0441293

Le document en format XML

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<term>Active site</term>
<term>Alumina</term>
<term>Catalyst activity</term>
<term>Catalytic reforming</term>
<term>Cyclohexane</term>
<term>Dysprosium</term>
<term>Experimental study</term>
<term>Heptane</term>
<term>Heterogeneous catalysis</term>
<term>Holmium</term>
<term>Hydrocarbon</term>
<term>Kinetics</term>
<term>Mixed catalyst</term>
<term>Palladium</term>
<term>Supported catalyst</term>
<term>Thulium</term>
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<term>Reformage catalytique</term>
<term>Hydrocarbure</term>
<term>Cyclohexane</term>
<term>Heptane</term>
<term>Cyclopentane(méthyl)</term>
<term>Catalyse hétérogène</term>
<term>Catalyseur sur support</term>
<term>Catalyseur mixte</term>
<term>Alumine</term>
<term>Palladium</term>
<term>Dysprosium</term>
<term>Holmium</term>
<term>Thulium</term>
<term>Activité catalytique</term>
<term>Site actif</term>
<term>Cinétique</term>
<term>Etude expérimentale</term>
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<div type="abstract" xml:lang="en">The reforming reactions of cyclohexane, methyl cyclopentane and n-heptane on the Pd/γ-Al
<sub>2</sub>
O
<sub>3</sub>
and Pd-Ln/γ-Al
<sub>2</sub>
O
<sub>3</sub>
(Ln=Dy, Ho, Tm) catalysts have been investigated. The results demonstrate that Pd-Ln/γ-Al
<sub>2</sub>
O
<sub>3</sub>
catalysts evince high activity and stability compared to Pd/γ-Al
<sub>2</sub>
O
<sub>3</sub>
catalysts. Owing to the different lanthanide content in the catalysts, the aromatisation and isomerization yields are different in the reforming reactions of n-heptane and cyclopentane. It is interesting to investigate the optimum content of lanthanides which gives the maximum aromatisation and isomerization yield.</div>
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