Study of the magnetic susceptibility and anisotropy properties of Tm3+ diglycollate crystal for evaluating crystal field effects
Identifieur interne : 002754 ( Main/Merge ); précédent : 002753; suivant : 002755Study of the magnetic susceptibility and anisotropy properties of Tm3+ diglycollate crystal for evaluating crystal field effects
Auteurs : A. Nag [Inde] ; A. Sengupta [Inde] ; D. Ghosh [Inde]Source :
- Solid state communications [ 0038-1098 ] ; 1999.
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Abstract
The thermal characteristics between 300 and 26 K of the molecular magnetic susceptibilities K∥ and K⊥, obtained from the experimental studies of susceptibility K of the powdered sample and the anisotropy ΔK = K⊥ - K∥ of a single crystal of Tm diglycollate (TmDG), were utilised to determine the crystal field parameters (CFP) and thereby to calculate the CF levels of the visible and UV spectra, electronic Schonky specific heat and the nuclear quadrupole splitting of 169Tm in TmDG. No phase change was observed up to 26 K.
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Sengupta</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Solid State Physics Department, Indian Association for the Cultivation of Science, Jadavpur</s1><s2>Calcutta 700 032</s2><s3>IND</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Inde</country><wicri:noRegion>Calcutta 700 032</wicri:noRegion></affiliation></author><author><name sortKey="Ghosh, D" sort="Ghosh, D" uniqKey="Ghosh D" first="D." last="Ghosh">D. 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Nag</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Solid State Physics Department, Indian Association for the Cultivation of Science, Jadavpur</s1><s2>Calcutta 700 032</s2><s3>IND</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Inde</country><wicri:noRegion>Calcutta 700 032</wicri:noRegion></affiliation></author><author><name sortKey="Sengupta, A" sort="Sengupta, A" uniqKey="Sengupta A" first="A." last="Sengupta">A. Sengupta</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Solid State Physics Department, Indian Association for the Cultivation of Science, Jadavpur</s1><s2>Calcutta 700 032</s2><s3>IND</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Inde</country><wicri:noRegion>Calcutta 700 032</wicri:noRegion></affiliation></author><author><name sortKey="Ghosh, D" sort="Ghosh, D" uniqKey="Ghosh D" first="D." last="Ghosh">D. Ghosh</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Solid State Physics Department, Indian Association for the Cultivation of Science, Jadavpur</s1><s2>Calcutta 700 032</s2><s3>IND</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Inde</country><wicri:noRegion>Calcutta 700 032</wicri:noRegion></affiliation></author></analytic><series><title level="j" type="main">Solid state communications</title><title level="j" type="abbreviated">Solid state commun.</title><idno type="ISSN">0038-1098</idno><imprint><date when="1999">1999</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Solid state communications</title><title level="j" type="abbreviated">Solid state commun.</title><idno type="ISSN">0038-1098</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Absorption spectra</term><term>Crystal field</term><term>Electronic specific heat</term><term>Experimental study</term><term>Magnetic anisotropy</term><term>Magnetic susceptibility</term><term>Quadrupolar splitting</term><term>Thulium complexes</term><term>Ultraviolet spectra</term><term>Visible spectra</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term><term>Susceptibilité magnétique</term><term>Anisotropie magnétique</term><term>Champ cristallin</term><term>Spectre absorption</term><term>Spectre visible</term><term>Spectre UV</term><term>Décomposition quadripolaire</term><term>Chaleur massique électronique</term><term>Thulium complexe</term><term>Glycolate</term><term>7530C</term><term>7530G</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The thermal characteristics between 300 and 26 K of the molecular magnetic susceptibilities K∥ and K⊥, obtained from the experimental studies of susceptibility K of the powdered sample and the anisotropy ΔK = K⊥ - K∥ of a single crystal of Tm diglycollate (TmDG), were utilised to determine the crystal field parameters (CFP) and thereby to calculate the CF levels of the visible and UV spectra, electronic Schonky specific heat and the nuclear quadrupole splitting of <sup>169</sup>Tm in TmDG. No phase change was observed up to 26 K.</div></front></TEI><affiliations><list><country><li>Inde</li></country></list><tree><country name="Inde"><noRegion><name sortKey="Nag, A" sort="Nag, A" uniqKey="Nag A" first="A." last="Nag">A. Nag</name></noRegion><name sortKey="Ghosh, D" sort="Ghosh, D" uniqKey="Ghosh D" first="D." last="Ghosh">D. Ghosh</name><name sortKey="Sengupta, A" sort="Sengupta, A" uniqKey="Sengupta A" first="A." last="Sengupta">A. Sengupta</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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