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Energy transfer and population inversion in heavy metal oxide glasses doped with Tm3+ and Tb3+

Identifieur interne : 001C16 ( Main/Merge ); précédent : 001C15; suivant : 001C17

Energy transfer and population inversion in heavy metal oxide glasses doped with Tm3+ and Tb3+

Auteurs : JAY HYOK SONG [Corée du Sud] ; Jong Heo [Corée du Sud]

Source :

RBID : Pascal:05-0033113

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English descriptors

Abstract

Emission properties and energy transfer of PbO-Bi2O3-Ga2O3-GeO2 glasses codoped with Tm3+ and Tb3+ ions were investigated. The 1.48-μm emission due to the Tm3+:3H43F4 transition can be used to amplify the S-band (1460-1530-nm) signal light. With Tb3+ addition, the lifetime and emission intensity of the Tm3+:3F4 level decreased sharply via the Tm3+:3F4→Tb3+:7F0,1,2 energy transfer. Population densities of the 3F4 and 3H4 levels in Tm3+ calculated from rate equations clearly verified that population inversion in Tm3+ ions became possible with as little as 0.1 mol% of Tb3+ addition.

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Pascal:05-0033113

Le document en format XML

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<title xml:lang="en" level="a">Energy transfer and population inversion in heavy metal oxide glasses doped with Tm
<sup>3+</sup>
and Tb
<sup>3+</sup>
</title>
<author>
<name sortKey="Jay Hyok Song" sort="Jay Hyok Song" uniqKey="Jay Hyok Song" last="Jay Hyok Song">JAY HYOK SONG</name>
<affiliation wicri:level="1">
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<s1>Center for Information Materials and Department of Materials Science and Engineering, Pohang University of Science and Technology, San 31, Hyoja-dong, Nam-gu</s1>
<s2>Pohang, Gyeongbuk 790-784</s2>
<s3>KOR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<country>Corée du Sud</country>
<wicri:noRegion>Pohang, Gyeongbuk 790-784</wicri:noRegion>
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</author>
<author>
<name sortKey="Heo, Jong" sort="Heo, Jong" uniqKey="Heo J" first="Jong" last="Heo">Jong Heo</name>
<affiliation wicri:level="1">
<inist:fA14 i1="01">
<s1>Center for Information Materials and Department of Materials Science and Engineering, Pohang University of Science and Technology, San 31, Hyoja-dong, Nam-gu</s1>
<s2>Pohang, Gyeongbuk 790-784</s2>
<s3>KOR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<country>Corée du Sud</country>
<wicri:noRegion>Pohang, Gyeongbuk 790-784</wicri:noRegion>
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<analytic>
<title xml:lang="en" level="a">Energy transfer and population inversion in heavy metal oxide glasses doped with Tm
<sup>3+</sup>
and Tb
<sup>3+</sup>
</title>
<author>
<name sortKey="Jay Hyok Song" sort="Jay Hyok Song" uniqKey="Jay Hyok Song" last="Jay Hyok Song">JAY HYOK SONG</name>
<affiliation wicri:level="1">
<inist:fA14 i1="01">
<s1>Center for Information Materials and Department of Materials Science and Engineering, Pohang University of Science and Technology, San 31, Hyoja-dong, Nam-gu</s1>
<s2>Pohang, Gyeongbuk 790-784</s2>
<s3>KOR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Corée du Sud</country>
<wicri:noRegion>Pohang, Gyeongbuk 790-784</wicri:noRegion>
</affiliation>
</author>
<author>
<name sortKey="Heo, Jong" sort="Heo, Jong" uniqKey="Heo J" first="Jong" last="Heo">Jong Heo</name>
<affiliation wicri:level="1">
<inist:fA14 i1="01">
<s1>Center for Information Materials and Department of Materials Science and Engineering, Pohang University of Science and Technology, San 31, Hyoja-dong, Nam-gu</s1>
<s2>Pohang, Gyeongbuk 790-784</s2>
<s3>KOR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Corée du Sud</country>
<wicri:noRegion>Pohang, Gyeongbuk 790-784</wicri:noRegion>
</affiliation>
</author>
</analytic>
<series>
<title level="j" type="main">Journal of the American Ceramic Society</title>
<title level="j" type="abbreviated">J. Am. Ceram. Soc.</title>
<idno type="ISSN">0002-7820</idno>
<imprint>
<date when="2004">2004</date>
</imprint>
</series>
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<seriesStmt>
<title level="j" type="main">Journal of the American Ceramic Society</title>
<title level="j" type="abbreviated">J. Am. Ceram. Soc.</title>
<idno type="ISSN">0002-7820</idno>
</seriesStmt>
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<textClass>
<keywords scheme="KwdEn" xml:lang="en">
<term>Absorption spectra</term>
<term>Bismuth Oxides</term>
<term>Codoping</term>
<term>Doping</term>
<term>Emission spectra</term>
<term>Energy transfer</term>
<term>Experimental study</term>
<term>Fluorescence spectrum</term>
<term>Gallium oxides</term>
<term>Germanate glasses</term>
<term>Germanium oxides</term>
<term>Lead Oxides</term>
<term>Optical properties</term>
<term>Population inversion</term>
<term>Quaternary systems</term>
<term>Terbium additions</term>
<term>Thulium additions</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Etude expérimentale</term>
<term>Verre germanate</term>
<term>Système quaternaire</term>
<term>Plomb Oxyde</term>
<term>Bismuth Oxyde</term>
<term>Gallium oxyde</term>
<term>Germanium oxyde</term>
<term>Dopage</term>
<term>Addition terbium</term>
<term>Addition thulium</term>
<term>Propriété optique</term>
<term>Transfert énergie</term>
<term>Inversion population</term>
<term>Spectre fluorescence</term>
<term>Spectre émission</term>
<term>Spectre absorption</term>
<term>Codopage</term>
<term>Système Bi2O3 Ga2O3 GeO2 PbO</term>
<term>Bi Ga Ge O Pb</term>
<term>7855Q</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr">
<term>Dopage</term>
</keywords>
</textClass>
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<front>
<div type="abstract" xml:lang="en">Emission properties and energy transfer of PbO-Bi
<sub>2</sub>
O
<sub>3</sub>
-Ga
<sub>2</sub>
O
<sub>3</sub>
-GeO
<sub>2</sub>
glasses codoped with Tm
<sup>3+</sup>
and Tb
<sup>3+</sup>
ions were investigated. The 1.48-μm emission due to the Tm
<sup>3+</sup>
:
<sup>3</sup>
H
<sub>4</sub>
<sup>3</sup>
F
<sub>4</sub>
transition can be used to amplify the S-band (1460-1530-nm) signal light. With Tb
<sup>3+</sup>
addition, the lifetime and emission intensity of the Tm
<sup>3+</sup>
:
<sup>3</sup>
F
<sub>4</sub>
level decreased sharply via the Tm
<sup>3+</sup>
:
<sup>3</sup>
F
<sub>4</sub>
→Tb
<sup>3+</sup>
:
<sup>7</sup>
F
<sub>0,1,2</sub>
energy transfer. Population densities of the
<sup>3</sup>
F
<sub>4</sub>
and
<sup>3</sup>
H
<sub>4</sub>
levels in Tm
<sup>3+</sup>
calculated from rate equations clearly verified that population inversion in Tm
<sup>3+</sup>
ions became possible with as little as 0.1 mol% of Tb
<sup>3+</sup>
addition.</div>
</front>
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<list>
<country>
<li>Corée du Sud</li>
</country>
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<tree>
<country name="Corée du Sud">
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<name sortKey="Jay Hyok Song" sort="Jay Hyok Song" uniqKey="Jay Hyok Song" last="Jay Hyok Song">JAY HYOK SONG</name>
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<name sortKey="Heo, Jong" sort="Heo, Jong" uniqKey="Heo J" first="Jong" last="Heo">Jong Heo</name>
</country>
</tree>
</affiliations>
</record>

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   |texte=   Energy transfer and population inversion in heavy metal oxide glasses doped with Tm3+ and Tb3+
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