Theoretical treatment of redox processes involving lanthanide(II) compounds: reactivity of organosamarium(II) and organothulium(II) complexes with CO2 and pyridine.
Identifieur interne : 000950 ( Main/Merge ); précédent : 000949; suivant : 000951Theoretical treatment of redox processes involving lanthanide(II) compounds: reactivity of organosamarium(II) and organothulium(II) complexes with CO2 and pyridine.
Auteurs : Stéphanie Labouille [France] ; François Nief ; Laurent MaronSource :
- The journal of physical chemistry. A [ 1520-5215 ] ; 2011.
Abstract
An effective methodology to deal with the theoretical treatment on the redox chemistry of divalent organolanthanide complexes is reported and has been tested on two representative substrates, pyridine and CO(2), with two different metals (samarium and thulium). An influence of the ancillary ligands, namely, C(5)Me(5) (Cp*) or (2,3,4,5-tetramethylphospholyl) (Tmp), on the one- or two-electron oxidation processes is observed. The theoretical results are in excellent agreement with the experimental observations indicating the efficiency of the method.
DOI: 10.1021/jp205144h
PubMed: 21675778
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