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Au nanorod decoration on NaYF₄:Yb/Tm nanoparticles for enhanced emission and wavelength-dependent biomolecular sensing.

Identifieur interne : 000526 ( Main/Exploration ); précédent : 000525; suivant : 000527

Au nanorod decoration on NaYF₄:Yb/Tm nanoparticles for enhanced emission and wavelength-dependent biomolecular sensing.

Auteurs : Palanisamy Kannan ; Ferhan Abdul Rahim ; Rui Chen ; Xue Teng ; Ling Huang ; Handong Sun ; Dong-Hwan Kim

Source :

RBID : pubmed:23591121

Descripteurs français

English descriptors

Abstract

We introduce gold nanorods (GNRs) decoration on NaYF4:Yb/Tm upconversion nanocrystals (UCNCs) by functionalizing the UCNCs with polyamidoamine generation 1 (PAMAM G1) dendrimer, followed by a single-step seed-mediated growth of long-range GNRs to enhance "biological window" upconversion emission. The up-conversion emission of GNR-decorated UCNCs can be enhanced beyond the level typically obtainable using shell-like structures up to 27-fold enhancement. Also, the enhancement can be tuned at different wavelength regions by varying the GNR aspect ratio. The GNR-decorated UCNC is further modified with 2-thiouracil for nonenzymatic detection of uric acid, revealing a detection limit as 1 pM.

DOI: 10.1021/am4007758
PubMed: 23591121


Affiliations:


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Le document en format XML

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<term>Limit of Detection</term>
<term>Metal Nanoparticles (chemistry)</term>
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<div type="abstract" xml:lang="en">We introduce gold nanorods (GNRs) decoration on NaYF4:Yb/Tm upconversion nanocrystals (UCNCs) by functionalizing the UCNCs with polyamidoamine generation 1 (PAMAM G1) dendrimer, followed by a single-step seed-mediated growth of long-range GNRs to enhance "biological window" upconversion emission. The up-conversion emission of GNR-decorated UCNCs can be enhanced beyond the level typically obtainable using shell-like structures up to 27-fold enhancement. Also, the enhancement can be tuned at different wavelength regions by varying the GNR aspect ratio. The GNR-decorated UCNC is further modified with 2-thiouracil for nonenzymatic detection of uric acid, revealing a detection limit as 1 pM.</div>
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