Strong visible up-conversion emission in Tb3+, Tm3+ and Tb3+-Tm3+ co-doped tellurite glasses sensitized by Yb3+.
Identifieur interne : 001468 ( Main/Exploration ); précédent : 001467; suivant : 001469Strong visible up-conversion emission in Tb3+, Tm3+ and Tb3+-Tm3+ co-doped tellurite glasses sensitized by Yb3+.
Auteurs : Xunsi Wang [République populaire de Chine] ; Liren Liu ; Qiuhua Nie ; Tiefeng Xu ; Xiang Shen ; Shixun Dai ; Xianghua ZhangSource :
- Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy [ 1386-1425 ] ; 2007.
Descripteurs français
- KwdFr :
- MESH :
English descriptors
- KwdEn :
- MESH :
- chemical , chemistry : Tellurium, Terbium, Thulium, Ytterbium.
- chemical : Ions.
- chemistry : Glass.
- methods : Spectrophotometry.
- Luminescence, Time Factors.
Abstract
Up-conversion luminescence characteristics under 975 nm excitation have been investigated with Tb3+/Tm3+/Yb3+ triply doped tellurite glasses. Here, green (547 nm: (5)D(4)-->(7)F(4)) and red (660 nm: (5)D(4)-->(7)F(2)) up-conversion (UC) luminescence originating from Tb3+ is observed strongly, because of the quadratic dependences of emission intensities on the excitation power. Especially, the UC luminescence was intensified violently with the energy transfer from the Tm3+ ions involves in the Tb3+ excitation. To the Tb3+/Tm3+/Yb3+ triply doped glass system, a novel up-conversion mechanism is proposed as follows: the energy of (3)G(4) level (Tm3+) was transferred to (5)D(4) (Tb(3+)) and the 477-nm UC luminescence of Tm3+ was nearly quenched.
DOI: 10.1016/j.saa.2006.09.023
PubMed: 17110158
Affiliations:
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Le document en format XML
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<author><name sortKey="Shen, Xiang" sort="Shen, Xiang" uniqKey="Shen X" first="Xiang" last="Shen">Xiang Shen</name>
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<term>Spectrophotometry (methods)</term>
<term>Tellurium (chemistry)</term>
<term>Terbium (chemistry)</term>
<term>Thulium (chemistry)</term>
<term>Time Factors</term>
<term>Ytterbium (chemistry)</term>
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<term>Ions</term>
<term>Luminescence</term>
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<term>Tellure ()</term>
<term>Terbium ()</term>
<term>Thulium ()</term>
<term>Verre ()</term>
<term>Ytterbium ()</term>
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<term>Terbium</term>
<term>Thulium</term>
<term>Ytterbium</term>
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<keywords scheme="MESH" type="chemical" xml:lang="en"><term>Ions</term>
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<term>Ions</term>
<term>Luminescence</term>
<term>Spectrophotométrie</term>
<term>Tellure</term>
<term>Terbium</term>
<term>Thulium</term>
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<front><div type="abstract" xml:lang="en">Up-conversion luminescence characteristics under 975 nm excitation have been investigated with Tb3+/Tm3+/Yb3+ triply doped tellurite glasses. Here, green (547 nm: (5)D(4)-->(7)F(4)) and red (660 nm: (5)D(4)-->(7)F(2)) up-conversion (UC) luminescence originating from Tb3+ is observed strongly, because of the quadratic dependences of emission intensities on the excitation power. Especially, the UC luminescence was intensified violently with the energy transfer from the Tm3+ ions involves in the Tb3+ excitation. To the Tb3+/Tm3+/Yb3+ triply doped glass system, a novel up-conversion mechanism is proposed as follows: the energy of (3)G(4) level (Tm3+) was transferred to (5)D(4) (Tb(3+)) and the 477-nm UC luminescence of Tm3+ was nearly quenched.</div>
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<name sortKey="Nie, Qiuhua" sort="Nie, Qiuhua" uniqKey="Nie Q" first="Qiuhua" last="Nie">Qiuhua Nie</name>
<name sortKey="Shen, Xiang" sort="Shen, Xiang" uniqKey="Shen X" first="Xiang" last="Shen">Xiang Shen</name>
<name sortKey="Xu, Tiefeng" sort="Xu, Tiefeng" uniqKey="Xu T" first="Tiefeng" last="Xu">Tiefeng Xu</name>
<name sortKey="Zhang, Xianghua" sort="Zhang, Xianghua" uniqKey="Zhang X" first="Xianghua" last="Zhang">Xianghua Zhang</name>
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