[A study on the concentration quenching of Tm3+ upconversion luminescence].
Identifieur interne : 001F70 ( Main/Exploration ); précédent : 001F69; suivant : 001F71[A study on the concentration quenching of Tm3+ upconversion luminescence].
Auteurs : B. Chen [République populaire de Chine] ; H. Wang ; S. HuangSource :
- Guang pu xue yu guang pu fen xi = Guang pu [ 1000-0593 ] ; 2001.
Descripteurs français
- KwdFr :
- MESH :
English descriptors
- KwdEn :
- MESH :
- chemical , chemistry : Tellurium, Thulium.
- chemistry : Glass.
- methods : Spectrometry, Fluorescence, Spectrum Analysis, Raman.
- Attention, Luminescence.
Abstract
In this work, we have a designation and preparation of MFT glasses for upconversion, the glasses consisted of TeO2 and fluoride: PbF2, AlF3, BaF2, NaF and the impurity Tm2O3. In this glass system the oxide improve forming ability, the fluorides improve the microscopic environment around RE ions in glasses. In this glass host the content of Tm2O3 achieves to 4% mol and crystallization no occurred. A detail study on the concentration quenching of upconversion luminescence for 1G4-->3H6 and 1D2-->3H4 transitions was completed. The experimental results directed that the quenching concentration was 0.6 mol.% and higher 3 times than in other glasses materials. The cross relaxation and mechanism of concentration quenching were discussed.
PubMed: 12947647
Affiliations:
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Le document en format XML
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<term>Spectrometry, Fluorescence (methods)</term>
<term>Spectrum Analysis, Raman (methods)</term>
<term>Tellurium (chemistry)</term>
<term>Thulium (chemistry)</term>
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<keywords scheme="KwdFr" xml:lang="fr"><term>Analyse spectrale Raman ()</term>
<term>Attention</term>
<term>Luminescence</term>
<term>Spectrométrie de fluorescence ()</term>
<term>Tellure ()</term>
<term>Thulium ()</term>
<term>Verre ()</term>
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<keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Tellurium</term>
<term>Thulium</term>
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<keywords scheme="MESH" qualifier="chemistry" xml:lang="en"><term>Glass</term>
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<keywords scheme="MESH" qualifier="methods" xml:lang="en"><term>Spectrometry, Fluorescence</term>
<term>Spectrum Analysis, Raman</term>
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<keywords scheme="MESH" xml:lang="en"><term>Attention</term>
<term>Luminescence</term>
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<term>Attention</term>
<term>Luminescence</term>
<term>Spectrométrie de fluorescence</term>
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<front><div type="abstract" xml:lang="en">In this work, we have a designation and preparation of MFT glasses for upconversion, the glasses consisted of TeO2 and fluoride: PbF2, AlF3, BaF2, NaF and the impurity Tm2O3. In this glass system the oxide improve forming ability, the fluorides improve the microscopic environment around RE ions in glasses. In this glass host the content of Tm2O3 achieves to 4% mol and crystallization no occurred. A detail study on the concentration quenching of upconversion luminescence for 1G4-->3H6 and 1D2-->3H4 transitions was completed. The experimental results directed that the quenching concentration was 0.6 mol.% and higher 3 times than in other glasses materials. The cross relaxation and mechanism of concentration quenching were discussed.</div>
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<name sortKey="Wang, H" sort="Wang, H" uniqKey="Wang H" first="H" last="Wang">H. Wang</name>
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<country name="République populaire de Chine"><region name="Jilin"><name sortKey="Chen, B" sort="Chen, B" uniqKey="Chen B" first="B" last="Chen">B. Chen</name>
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