Tm4B3C4: Preparation, crystal structure and physical properties
Identifieur interne : 000873 ( Main/Exploration ); précédent : 000872; suivant : 000874Tm4B3C4: Preparation, crystal structure and physical properties
Auteurs : Volodymyr Babizhetskyy [Ukraine] ; Kurt Hiebl [Autriche] ; Arndt Simon [Allemagne]Source :
- Solid state communications [ 0038-1098 ] ; 2012.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
Tm4B3C4 crystallizes in the triclinic Gd4B3C4 structure type, space group P1, a=3.4850(2), b= 3.5220(2), c=11.6972(6), α=92.86(1), β=96.43(1), γ=90.14(1) according to X-ray powder diffraction. The magnetic properties of the compound Tm4B3C4 have been measured in the temperature range 2 K < T< 300 K and in various external fields up to B=7T. The sample undergoes an anti-ferromagnetic transition at TN=3 K, and in fields B>0.1 T a meta-magnetic transition is encountered. The measurements of the temperature dependence of the electrical resistivity proves a poor metallic state of this compound.
Affiliations:
- Allemagne, Autriche, Ukraine
- Bade-Wurtemberg, District de Stuttgart, Vienne (Autriche)
- Stuttgart, Vienne (Autriche)
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Le document en format XML
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B<sub>3</sub>
C<sub>4</sub>
: Preparation, crystal structure and physical properties</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Tm<sub>4</sub>
B<sub>3</sub>
C<sub>4</sub>
: Preparation, crystal structure and physical properties</title>
<author><name sortKey="Babizhetskyy, Volodymyr" sort="Babizhetskyy, Volodymyr" uniqKey="Babizhetskyy V" first="Volodymyr" last="Babizhetskyy">Volodymyr Babizhetskyy</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla & Mefodiya Str. 6</s1>
<s2>79005 Lviv</s2>
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<author><name sortKey="Hiebl, Kurt" sort="Hiebl, Kurt" uniqKey="Hiebl K" first="Kurt" last="Hiebl">Kurt Hiebl</name>
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<s2>1090 Wien</s2>
<s3>AUT</s3>
<sZ>2 aut.</sZ>
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<country>Autriche</country>
<placeName><region type="land" nuts="2">Vienne (Autriche)</region>
<settlement type="city">Vienne (Autriche)</settlement>
</placeName>
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<author><name sortKey="Simon, Arndt" sort="Simon, Arndt" uniqKey="Simon A" first="Arndt" last="Simon">Arndt Simon</name>
<affiliation wicri:level="3"><inist:fA14 i1="03"><s1>Max-Planck-institut für Festkörperforschung, Heisenbergstrasse 1, Postfach 800665.</s1>
<s2>70569 Stuttgart</s2>
<s3>DEU</s3>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Allemagne</country>
<placeName><region type="land" nuts="1">Bade-Wurtemberg</region>
<region type="district" nuts="2">District de Stuttgart</region>
<settlement type="city">Stuttgart</settlement>
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<series><title level="j" type="main">Solid state communications</title>
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<imprint><date when="2012">2012</date>
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<seriesStmt><title level="j" type="main">Solid state communications</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Antiferromagnetism</term>
<term>Crystal structure</term>
<term>Electrical conductivity</term>
<term>Magnetic susceptibility</term>
<term>Magnetic transitions</term>
<term>Magnetization</term>
<term>Metamagnetism</term>
<term>Space groups</term>
<term>Thulium Borides carbides</term>
<term>Triclinic lattices</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Structure cristalline</term>
<term>Groupe espace</term>
<term>Diffraction RX</term>
<term>Métamagnétisme</term>
<term>Antiferromagnétisme</term>
<term>Transition magnétique</term>
<term>Conductivité électrique</term>
<term>Aimantation</term>
<term>Susceptibilité magnétique</term>
<term>Thulium Borocarbure</term>
<term>Réseau triclinique</term>
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<front><div type="abstract" xml:lang="en">Tm<sub>4</sub>
B<sub>3</sub>
C<sub>4</sub>
crystallizes in the triclinic Gd<sub>4</sub>
B<sub>3</sub>
C<sub>4</sub>
structure type, space group P1, a=3.4850(2), b= 3.5220(2), c=11.6972(6), α=92.86(1), β=96.43(1), γ=90.14(1) according to X-ray powder diffraction. The magnetic properties of the compound Tm<sub>4</sub>
B<sub>3</sub>
C<sub>4</sub>
have been measured in the temperature range 2 K < T< 300 K and in various external fields up to B=7T. The sample undergoes an anti-ferromagnetic transition at T<sub>N</sub>
=3 K, and in fields B>0.1 T a meta-magnetic transition is encountered. The measurements of the temperature dependence of the electrical resistivity proves a poor metallic state of this compound.</div>
</front>
</TEI>
<affiliations><list><country><li>Allemagne</li>
<li>Autriche</li>
<li>Ukraine</li>
</country>
<region><li>Bade-Wurtemberg</li>
<li>District de Stuttgart</li>
<li>Vienne (Autriche)</li>
</region>
<settlement><li>Stuttgart</li>
<li>Vienne (Autriche)</li>
</settlement>
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</noRegion>
</country>
<country name="Autriche"><region name="Vienne (Autriche)"><name sortKey="Hiebl, Kurt" sort="Hiebl, Kurt" uniqKey="Hiebl K" first="Kurt" last="Hiebl">Kurt Hiebl</name>
</region>
</country>
<country name="Allemagne"><region name="Bade-Wurtemberg"><name sortKey="Simon, Arndt" sort="Simon, Arndt" uniqKey="Simon A" first="Arndt" last="Simon">Arndt Simon</name>
</region>
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</tree>
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</record>
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