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Rare-earth ionic size effects on Tc in the series RBa2Cu3O7-δ

Identifieur interne : 002A85 ( Main/Exploration ); précédent : 002A84; suivant : 002A86

Rare-earth ionic size effects on Tc in the series RBa2Cu3O7-δ

Auteurs : X. Chen [République populaire de Chine] ; J. Sha [République populaire de Chine] ; Z. Xu [République populaire de Chine] ; Z. Jiao [République populaire de Chine] ; Q. Zhang [République populaire de Chine]

Source :

RBID : Pascal:97-0504291

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English descriptors

Abstract

Copyright (c) 1997 Elsevier Science B.V. All rights reserved. The rare-earth ionic size effects on Tc are investigated in terms of bond valence sums using the neutron diffraction data for nearly optimal doped RBa2Cu3O7-δ (R = Y, La, Nd, Sm, Dy, Ho, Er, Tm, and Yd) and PrBa2Cu3O7-δ systems. The optimal hole concentration in CuO2 planes is found to decrease systematically with increasing rare-earth ionic radius except Pr-123 in the R-123 phases, which is confirmed by the two similar inverted parabolic curves of Tc vs hole concentration for Y-123 and Er-123. The anomalous property of Pr-123 is due to the depletion of hole concentration. The increase in Tc as R3+ ionic radius is interpreted as both the increase of hole distribution on the in-plane O sites relative to the in-plane Cu sites and the interplanar coupling.


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Le document en format XML

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<title xml:lang="en" level="a">Rare-earth ionic size effects on T
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Cu
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<sub>7-δ</sub>
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<title xml:lang="en" level="a">Rare-earth ionic size effects on T
<sub>c</sub>
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<sub>2</sub>
Cu
<sub>3</sub>
O
<sub>7-δ</sub>
</title>
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<term>Dysprosium oxides</term>
<term>Erbium oxides</term>
<term>Experimental study</term>
<term>Holmium oxides</term>
<term>Ionic radius</term>
<term>Lanthanum oxides</term>
<term>Neodymium oxides</term>
<term>Samarium oxides</term>
<term>Size effect</term>
<term>Superconductivity</term>
<term>Thulium oxides</term>
<term>Transition temperature</term>
<term>Ytterbium oxides</term>
<term>Yttrium oxides</term>
</keywords>
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<term>Etude expérimentale</term>
<term>Effet dimensionnel</term>
<term>Rayon ionique</term>
<term>Température transition</term>
<term>Supraconductivité</term>
<term>Densité porteur charge</term>
<term>Yttrium oxyde</term>
<term>Lanthane oxyde</term>
<term>Néodyme oxyde</term>
<term>Samarium oxyde</term>
<term>Dysprosium oxyde</term>
<term>Holmium oxyde</term>
<term>Erbium oxyde</term>
<term>Thulium oxyde</term>
<term>Ytterbium oxyde</term>
<term>7462Y</term>
<term>7472J</term>
<term>Baryum oxyde</term>
<term>Cuivre oxyde</term>
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<front>
<div type="abstract" xml:lang="en">Copyright (c) 1997 Elsevier Science B.V. All rights reserved. The rare-earth ionic size effects on T
<sub>c</sub>
are investigated in terms of bond valence sums using the neutron diffraction data for nearly optimal doped RBa
<sub>2</sub>
Cu
<sub>3</sub>
O
<sub>7-δ</sub>
(R = Y, La, Nd, Sm, Dy, Ho, Er, Tm, and Yd) and PrBa
<sub>2</sub>
Cu
<sub>3</sub>
O
<sub>7-δ</sub>
systems. The optimal hole concentration in CuO
<sub>2</sub>
planes is found to decrease systematically with increasing rare-earth ionic radius except Pr-123 in the R-123 phases, which is confirmed by the two similar inverted parabolic curves of T
<sub>c</sub>
vs hole concentration for Y-123 and Er-123. The anomalous property of Pr-123 is due to the depletion of hole concentration. The increase in T
<sub>c</sub>
as R
<sup>3+</sup>
 ionic radius is interpreted as both the increase of hole distribution on the in-plane O sites relative to the in-plane Cu sites and the interplanar coupling.</div>
</front>
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