Rare-earth ionic size effects on Tc in the series RBa2Cu3O7-δ
Identifieur interne : 002A85 ( Main/Exploration ); précédent : 002A84; suivant : 002A86Rare-earth ionic size effects on Tc in the series RBa2Cu3O7-δ
Auteurs : X. Chen [République populaire de Chine] ; J. Sha [République populaire de Chine] ; Z. Xu [République populaire de Chine] ; Z. Jiao [République populaire de Chine] ; Q. Zhang [République populaire de Chine]Source :
- Physica. C. Superconductivity [ 0921-4534 ] ; 1997.
Descripteurs français
- Pascal (Inist)
- Etude expérimentale, Effet dimensionnel, Rayon ionique, Température transition, Supraconductivité, Densité porteur charge, Yttrium oxyde, Lanthane oxyde, Néodyme oxyde, Samarium oxyde, Dysprosium oxyde, Holmium oxyde, Erbium oxyde, Thulium oxyde, Ytterbium oxyde, 7462Y, 7472J, Baryum oxyde, Cuivre oxyde.
English descriptors
- KwdEn :
Abstract
Copyright (c) 1997 Elsevier Science B.V. All rights reserved. The rare-earth ionic size effects on Tc are investigated in terms of bond valence sums using the neutron diffraction data for nearly optimal doped RBa2Cu3O7-δ (R = Y, La, Nd, Sm, Dy, Ho, Er, Tm, and Yd) and PrBa2Cu3O7-δ systems. The optimal hole concentration in CuO2 planes is found to decrease systematically with increasing rare-earth ionic radius except Pr-123 in the R-123 phases, which is confirmed by the two similar inverted parabolic curves of Tc vs hole concentration for Y-123 and Er-123. The anomalous property of Pr-123 is due to the depletion of hole concentration. The increase in Tc as R3+ ionic radius is interpreted as both the increase of hole distribution on the in-plane O sites relative to the in-plane Cu sites and the interplanar coupling.
Affiliations:
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Le document en format XML
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Rare-earth ionic size effects on T<sub>c</sub>
in the series RBa<sub>2</sub>
Cu<sub>3</sub>
O<sub>7-δ</sub>
</title>
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<series><title level="j" type="main">Physica. C. Superconductivity</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Barium oxides</term>
<term>Carrier density</term>
<term>Copper oxides</term>
<term>Dysprosium oxides</term>
<term>Erbium oxides</term>
<term>Experimental study</term>
<term>Holmium oxides</term>
<term>Ionic radius</term>
<term>Lanthanum oxides</term>
<term>Neodymium oxides</term>
<term>Samarium oxides</term>
<term>Size effect</term>
<term>Superconductivity</term>
<term>Thulium oxides</term>
<term>Transition temperature</term>
<term>Ytterbium oxides</term>
<term>Yttrium oxides</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Effet dimensionnel</term>
<term>Rayon ionique</term>
<term>Température transition</term>
<term>Supraconductivité</term>
<term>Densité porteur charge</term>
<term>Yttrium oxyde</term>
<term>Lanthane oxyde</term>
<term>Néodyme oxyde</term>
<term>Samarium oxyde</term>
<term>Dysprosium oxyde</term>
<term>Holmium oxyde</term>
<term>Erbium oxyde</term>
<term>Thulium oxyde</term>
<term>Ytterbium oxyde</term>
<term>7462Y</term>
<term>7472J</term>
<term>Baryum oxyde</term>
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</keywords>
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<front><div type="abstract" xml:lang="en">Copyright (c) 1997 Elsevier Science B.V. All rights reserved. The rare-earth ionic size effects on T<sub>c</sub>
are investigated in terms of bond valence sums using the neutron diffraction data for nearly optimal doped RBa<sub>2</sub>
Cu<sub>3</sub>
O<sub>7-δ</sub>
(R = Y, La, Nd, Sm, Dy, Ho, Er, Tm, and Yd) and PrBa<sub>2</sub>
Cu<sub>3</sub>
O<sub>7-δ</sub>
systems. The optimal hole concentration in CuO<sub>2</sub>
planes is found to decrease systematically with increasing rare-earth ionic radius except Pr-123 in the R-123 phases, which is confirmed by the two similar inverted parabolic curves of T<sub>c</sub>
vs hole concentration for Y-123 and Er-123. The anomalous property of Pr-123 is due to the depletion of hole concentration. The increase in T<sub>c</sub>
as R<sup>3+</sup>
ionic radius is interpreted as both the increase of hole distribution on the in-plane O sites relative to the in-plane Cu sites and the interplanar coupling.</div>
</front>
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<affiliations><list><country><li>République populaire de Chine</li>
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<orgName><li>Université de Zhejiang</li>
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<tree><country name="République populaire de Chine"><region name="Zhejiang"><name sortKey="Chen, X" sort="Chen, X" uniqKey="Chen X" first="X." last="Chen">X. Chen</name>
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<name sortKey="Jiao, Z" sort="Jiao, Z" uniqKey="Jiao Z" first="Z." last="Jiao">Z. Jiao</name>
<name sortKey="Sha, J" sort="Sha, J" uniqKey="Sha J" first="J." last="Sha">J. Sha</name>
<name sortKey="Xu, Z" sort="Xu, Z" uniqKey="Xu Z" first="Z." last="Xu">Z. Xu</name>
<name sortKey="Zhang, Q" sort="Zhang, Q" uniqKey="Zhang Q" first="Q." last="Zhang">Q. Zhang</name>
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