2.0 μm emission properties and energy transfer between Ho3+ and Tm3+ in PbO-Bi2O3-Ga2O3 glasses
Identifieur interne : 002450 ( Main/Exploration ); précédent : 002449; suivant : 0024512.0 μm emission properties and energy transfer between Ho3+ and Tm3+ in PbO-Bi2O3-Ga2O3 glasses
Auteurs : YONG BEOM SHIN [Corée du Sud] ; HYUNG TACK LIM [Corée du Sud] ; YONG GYU CHOI [Corée du Sud] ; YOU SONG KIM [Corée du Sud] ; J. Heo [Corée du Sud]Source :
- Journal of the American Ceramic Society [ 0002-7820 ] ; 2000.
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- topic : Verre.
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Abstract
Emission properties of 2.0 μm fluorescence and the energy transfer between Ho3+ and Tm3+ in 57PbO.25Bi2O3.18Ga2O3 (mol%) glass codoped with Ho3+ and Tm3+ were investigated. Cross-relaxation rates in Tm3+ increased approximately 5 times when the Tm2O3 concentration was increased from 1.0 to 1.5 wt%. Coefficients of the forward Tm3+ → Ho3+ energy transfer were about 15 times larger than those of the Tm3+ ← Ho3+ backward transfer. Analysis of the energy transfer and gain spectra indicated that the highest gain at the 2.0 μm wavelength region could be achieved from the glass with 1.5 wt% of Tm2O3 and 0.3 wt% of Ho2O3.
Affiliations:
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Le document en format XML
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O<sub>3</sub>
-Ga<sub>2</sub>
O<sub>3</sub>
glasses</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">2.0 μm emission properties and energy transfer between Ho<sup>3+</sup>
and Tm<sup>3+</sup>
in PbO-Bi<sub>2</sub>
O<sub>3</sub>
-Ga<sub>2</sub>
O<sub>3</sub>
glasses</title>
<author><name sortKey="Yong Beom Shin" sort="Yong Beom Shin" uniqKey="Yong Beom Shin" last="Yong Beom Shin">YONG BEOM SHIN</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Photonic Glasses Laboratory, Department of Materials Science and Engineering/School of Environmental Engineering, Pohang University of Science and Technology</s1>
<s2>Pohang</s2>
<s3>KOR</s3>
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<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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</inist:fA14>
<country>Corée du Sud</country>
<wicri:noRegion>Pohang</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Hyung Tack Lim" sort="Hyung Tack Lim" uniqKey="Hyung Tack Lim" last="Hyung Tack Lim">HYUNG TACK LIM</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Photonic Glasses Laboratory, Department of Materials Science and Engineering/School of Environmental Engineering, Pohang University of Science and Technology</s1>
<s2>Pohang</s2>
<s3>KOR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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</inist:fA14>
<country>Corée du Sud</country>
<wicri:noRegion>Pohang</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Yong Gyu Choi" sort="Yong Gyu Choi" uniqKey="Yong Gyu Choi" last="Yong Gyu Choi">YONG GYU CHOI</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Photonic Glasses Laboratory, Department of Materials Science and Engineering/School of Environmental Engineering, Pohang University of Science and Technology</s1>
<s2>Pohang</s2>
<s3>KOR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
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</inist:fA14>
<country>Corée du Sud</country>
<wicri:noRegion>Pohang</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="You Song Kim" sort="You Song Kim" uniqKey="You Song Kim" last="You Song Kim">YOU SONG KIM</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Photonic Glasses Laboratory, Department of Materials Science and Engineering/School of Environmental Engineering, Pohang University of Science and Technology</s1>
<s2>Pohang</s2>
<s3>KOR</s3>
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<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Corée du Sud</country>
<wicri:noRegion>Pohang</wicri:noRegion>
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</author>
<author><name sortKey="Heo, J" sort="Heo, J" uniqKey="Heo J" first="J." last="Heo">J. Heo</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Photonic Glasses Laboratory, Department of Materials Science and Engineering/School of Environmental Engineering, Pohang University of Science and Technology</s1>
<s2>Pohang</s2>
<s3>KOR</s3>
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<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Corée du Sud</country>
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</affiliation>
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</analytic>
<series><title level="j" type="main">Journal of the American Ceramic Society</title>
<title level="j" type="abbreviated">J. Am. Ceram. Soc.</title>
<idno type="ISSN">0002-7820</idno>
<imprint><date when="2000">2000</date>
</imprint>
</series>
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<seriesStmt><title level="j" type="main">Journal of the American Ceramic Society</title>
<title level="j" type="abbreviated">J. Am. Ceram. Soc.</title>
<idno type="ISSN">0002-7820</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Codoping</term>
<term>Cross relaxation</term>
<term>Doped materials</term>
<term>Energy-level transitions</term>
<term>Experimental study</term>
<term>Fluorescence</term>
<term>Gain</term>
<term>Glass</term>
<term>Holmium additions</term>
<term>Quantity ratio</term>
<term>Thulium additions</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Transition niveau énergie</term>
<term>Fluorescence</term>
<term>Relaxation croisée</term>
<term>Effet concentration</term>
<term>Gain</term>
<term>Matériau dopé</term>
<term>Codopage</term>
<term>Addition holmium</term>
<term>Addition thulium</term>
<term>Verre</term>
<term>Système Bi2O3 Ga2O3 PbO</term>
<term>Bi Ga O Pb</term>
<term>7855H</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Verre</term>
</keywords>
</textClass>
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</teiHeader>
<front><div type="abstract" xml:lang="en">Emission properties of 2.0 μm fluorescence and the energy transfer between Ho<sup>3+</sup>
and Tm<sup>3+</sup>
in 57PbO.25Bi<sub>2</sub>
O<sub>3</sub>
.18Ga<sub>2</sub>
O<sub>3</sub>
(mol%) glass codoped with Ho<sup>3+</sup>
and Tm<sup>3+</sup>
were investigated. Cross-relaxation rates in Tm<sup>3+</sup>
increased approximately 5 times when the Tm<sub>2</sub>
O<sub>3</sub>
concentration was increased from 1.0 to 1.5 wt%. Coefficients of the forward Tm<sup>3+</sup>
→ Ho<sup>3+</sup>
energy transfer were about 15 times larger than those of the Tm<sup>3+</sup>
← Ho<sup>3+</sup>
backward transfer. Analysis of the energy transfer and gain spectra indicated that the highest gain at the 2.0 μm wavelength region could be achieved from the glass with 1.5 wt% of Tm<sub>2</sub>
O<sub>3</sub>
and 0.3 wt% of Ho<sub>2</sub>
O<sub>3</sub>
.</div>
</front>
</TEI>
<affiliations><list><country><li>Corée du Sud</li>
</country>
</list>
<tree><country name="Corée du Sud"><noRegion><name sortKey="Yong Beom Shin" sort="Yong Beom Shin" uniqKey="Yong Beom Shin" last="Yong Beom Shin">YONG BEOM SHIN</name>
</noRegion>
<name sortKey="Heo, J" sort="Heo, J" uniqKey="Heo J" first="J." last="Heo">J. Heo</name>
<name sortKey="Hyung Tack Lim" sort="Hyung Tack Lim" uniqKey="Hyung Tack Lim" last="Hyung Tack Lim">HYUNG TACK LIM</name>
<name sortKey="Yong Gyu Choi" sort="Yong Gyu Choi" uniqKey="Yong Gyu Choi" last="Yong Gyu Choi">YONG GYU CHOI</name>
<name sortKey="You Song Kim" sort="You Song Kim" uniqKey="You Song Kim" last="You Song Kim">YOU SONG KIM</name>
</country>
</tree>
</affiliations>
</record>
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