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Investigation on the luminescence of RE3+ (RE = Ce, Tb, Eu and Tm) in KMGd(PO4)2 (M = Ca, Sr) phosphates

Identifieur interne : 001391 ( Main/Exploration ); précédent : 001390; suivant : 001392

Investigation on the luminescence of RE3+ (RE = Ce, Tb, Eu and Tm) in KMGd(PO4)2 (M = Ca, Sr) phosphates

Auteurs : Zhi-Jun Zhang [République populaire de Chine] ; Jun-Lin Yuan [République populaire de Chine] ; SHUANG CHEN [République populaire de Chine] ; Hao-Hong Chen [République populaire de Chine] ; Xin-Xin Yang [République populaire de Chine] ; Jing-Tai Zhao [République populaire de Chine] ; Guo-Bin Zhang [République populaire de Chine] ; Chao-Shu Shi [République populaire de Chine]

Source :

RBID : Pascal:08-0424123

Descripteurs français

English descriptors

Abstract

The VUV excited luminescent properties of Ce3+, Tb3+, Eu3+ and Tm3+ in the matrices of KMGd(PO4)2 (M = Ca, Sr) were investigated. The bands at about 165 nm and 155 nm in the VUV excitation spectra are attributed to host lattice absorptions of the two matrices. For Ce3+-doped samples, the Ce3+ 5d levels can be identified. As for Tb3+-doped samples, typical 4f-5d absorption bands in the region of 175-250 nm were observed. For Eu3+ and Tm3+-doped samples, the O2--Eu3+ and O2-Tm3+ CTBs are observed to be at about 229 nm and 177 nm, respectively. From the standpoints of color purity and luminescent efficiency, KCaGd(PO4)2:Tb3+ is an attractive candidate of green light PDP phosphor.


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Le document en format XML

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<sub>2</sub>
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<idno type="inist">08-0424123</idno>
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<analytic>
<title xml:lang="en" level="a">Investigation on the luminescence of RE
<sup>3+</sup>
(RE = Ce, Tb, Eu and Tm) in KMGd(PO
<sub>4</sub>
)
<sub>2</sub>
(M = Ca, Sr) phosphates</title>
<author>
<name sortKey="Zhang, Zhi Jun" sort="Zhang, Zhi Jun" uniqKey="Zhang Z" first="Zhi-Jun" last="Zhang">Zhi-Jun Zhang</name>
<affiliation wicri:level="1">
<inist:fA14 i1="01">
<s1>State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences</s1>
<s2>Shanghai 200050</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
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<wicri:noRegion>Shanghai 200050</wicri:noRegion>
</affiliation>
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</author>
<author>
<name sortKey="Yuan, Jun Lin" sort="Yuan, Jun Lin" uniqKey="Yuan J" first="Jun-Lin" last="Yuan">Jun-Lin Yuan</name>
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<sZ>1 aut.</sZ>
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<author>
<name sortKey="Shuang Chen" sort="Shuang Chen" uniqKey="Shuang Chen" last="Shuang Chen">SHUANG CHEN</name>
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<author>
<name sortKey="Chen, Hao Hong" sort="Chen, Hao Hong" uniqKey="Chen H" first="Hao-Hong" last="Chen">Hao-Hong Chen</name>
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<author>
<name sortKey="Yang, Xin Xin" sort="Yang, Xin Xin" uniqKey="Yang X" first="Xin-Xin" last="Yang">Xin-Xin Yang</name>
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</author>
<author>
<name sortKey="Zhao, Jing Tai" sort="Zhao, Jing Tai" uniqKey="Zhao J" first="Jing-Tai" last="Zhao">Jing-Tai Zhao</name>
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</author>
<author>
<name sortKey="Zhang, Guo Bin" sort="Zhang, Guo Bin" uniqKey="Zhang G" first="Guo-Bin" last="Zhang">Guo-Bin Zhang</name>
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<wicri:noRegion>Heifei 230026</wicri:noRegion>
</affiliation>
</author>
<author>
<name sortKey="Shi, Chao Shu" sort="Shi, Chao Shu" uniqKey="Shi C" first="Chao-Shu" last="Shi">Chao-Shu Shi</name>
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<inist:fA14 i1="03">
<s1>National Synchrotron Radiation Laboratory, University of Science and Technology of China</s1>
<s2>Heifei 230026</s2>
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<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
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<wicri:noRegion>Heifei 230026</wicri:noRegion>
</affiliation>
</author>
</analytic>
<series>
<title level="j" type="main">Optical materials : (Amsterdam)</title>
<title level="j" type="abbreviated">Opt. mater. : (Amst.)</title>
<idno type="ISSN">0925-3467</idno>
<imprint>
<date when="2008">2008</date>
</imprint>
</series>
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<title level="j" type="main">Optical materials : (Amsterdam)</title>
<title level="j" type="abbreviated">Opt. mater. : (Amst.)</title>
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<textClass>
<keywords scheme="KwdEn" xml:lang="en">
<term>Calcium Phosphates</term>
<term>Cerium additions</term>
<term>Doped materials</term>
<term>Europium additions</term>
<term>Excitation spectrum</term>
<term>Extreme ultraviolet spectra</term>
<term>Gadolinium Phosphates</term>
<term>Green light</term>
<term>Luminescence</term>
<term>Optical materials</term>
<term>Phosphors</term>
<term>Plasma display panel</term>
<term>Potassium Phosphates</term>
<term>Strontium Phosphates</term>
<term>Terbium additions</term>
<term>Thulium additions</term>
<term>Visible radiation</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Luminescence</term>
<term>Panneau affichage plasma</term>
<term>Lumière verte</term>
<term>Rayonnement visible</term>
<term>Spectre excitation</term>
<term>Spectre UV extrême</term>
<term>Matériau dopé</term>
<term>Matériau luminescent</term>
<term>Addition europium</term>
<term>Matériau optique</term>
<term>Calcium Phosphate</term>
<term>Addition cérium</term>
<term>Addition terbium</term>
<term>Addition thulium</term>
<term>Potassium Phosphate</term>
<term>Gadolinium Phosphate</term>
<term>Strontium Phosphate</term>
<term>4270</term>
<term>7855H</term>
<term>KCaGd(PO4)2</term>
<term>KSrGd(PO4)2</term>
</keywords>
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<front>
<div type="abstract" xml:lang="en">The VUV excited luminescent properties of Ce
<sup>3+</sup>
, Tb
<sup>3+</sup>
, Eu
<sup>3+</sup>
and Tm
<sup>3+</sup>
in the matrices of KMGd(PO
<sub>4</sub>
)
<sub>2</sub>
(M = Ca, Sr) were investigated. The bands at about 165 nm and 155 nm in the VUV excitation spectra are attributed to host lattice absorptions of the two matrices. For Ce
<sup>3+</sup>
-doped samples, the Ce
<sup>3+</sup>
5d levels can be identified. As for Tb
<sup>3+</sup>
-doped samples, typical 4f-5d absorption bands in the region of 175-250 nm were observed. For Eu
<sup>3+</sup>
and Tm
<sup>3+</sup>
-doped samples, the O
<sup>2-</sup>
-Eu
<sup>3+</sup>
and O
<sup>2</sup>
-Tm
<sup>3+</sup>
CTBs are observed to be at about 229 nm and 177 nm, respectively. From the standpoints of color purity and luminescent efficiency, KCaGd(PO
<sub>4</sub>
)
<sub>2</sub>
:Tb
<sup>3+</sup>
is an attractive candidate of green light PDP phosphor.</div>
</front>
</TEI>
<affiliations>
<list>
<country>
<li>République populaire de Chine</li>
</country>
<settlement>
<li>Pékin</li>
</settlement>
</list>
<tree>
<country name="République populaire de Chine">
<noRegion>
<name sortKey="Zhang, Zhi Jun" sort="Zhang, Zhi Jun" uniqKey="Zhang Z" first="Zhi-Jun" last="Zhang">Zhi-Jun Zhang</name>
</noRegion>
<name sortKey="Chen, Hao Hong" sort="Chen, Hao Hong" uniqKey="Chen H" first="Hao-Hong" last="Chen">Hao-Hong Chen</name>
<name sortKey="Chen, Hao Hong" sort="Chen, Hao Hong" uniqKey="Chen H" first="Hao-Hong" last="Chen">Hao-Hong Chen</name>
<name sortKey="Shi, Chao Shu" sort="Shi, Chao Shu" uniqKey="Shi C" first="Chao-Shu" last="Shi">Chao-Shu Shi</name>
<name sortKey="Shuang Chen" sort="Shuang Chen" uniqKey="Shuang Chen" last="Shuang Chen">SHUANG CHEN</name>
<name sortKey="Shuang Chen" sort="Shuang Chen" uniqKey="Shuang Chen" last="Shuang Chen">SHUANG CHEN</name>
<name sortKey="Yang, Xin Xin" sort="Yang, Xin Xin" uniqKey="Yang X" first="Xin-Xin" last="Yang">Xin-Xin Yang</name>
<name sortKey="Yang, Xin Xin" sort="Yang, Xin Xin" uniqKey="Yang X" first="Xin-Xin" last="Yang">Xin-Xin Yang</name>
<name sortKey="Yuan, Jun Lin" sort="Yuan, Jun Lin" uniqKey="Yuan J" first="Jun-Lin" last="Yuan">Jun-Lin Yuan</name>
<name sortKey="Yuan, Jun Lin" sort="Yuan, Jun Lin" uniqKey="Yuan J" first="Jun-Lin" last="Yuan">Jun-Lin Yuan</name>
<name sortKey="Zhang, Guo Bin" sort="Zhang, Guo Bin" uniqKey="Zhang G" first="Guo-Bin" last="Zhang">Guo-Bin Zhang</name>
<name sortKey="Zhang, Zhi Jun" sort="Zhang, Zhi Jun" uniqKey="Zhang Z" first="Zhi-Jun" last="Zhang">Zhi-Jun Zhang</name>
<name sortKey="Zhao, Jing Tai" sort="Zhao, Jing Tai" uniqKey="Zhao J" first="Jing-Tai" last="Zhao">Jing-Tai Zhao</name>
</country>
</tree>
</affiliations>
</record>

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