ThuliumV1, Main, Exploration, bibRecord, 001044

BaLn2Se4 (Ln = Er, Tm and Yb)

Identifieur interne : 001044 ( Main/Exploration ); précédent : 001043; suivant : 001045

BaLn2Se4 (Ln = Er, Tm and Yb)

Auteurs : Daniel E. Bugaris [États-Unis] ; James A. Ibers [États-Unis]

Source :

Acta Crystallographica Section C [ 0108-2701 ] ; 2009-09-15.

RBID : ISTEX:1967F9CA6F704632547ECFE5589EA15B97508DB0

English descriptors

KwdEn :
- Acta, Acta cryst, Alfa aesar, Bruker, Cation, Cell volume, Cryst, Crystal data, Data collection bruker apexii diffractometer absorption correction, Diffraction data, Dimer, Flahaut, Ibers, Ionic radii, Lanthanide, Mmol, Orthorhombic, Orthorhombic space group pnma, Pnma, Sadabs, Sheldrick, Structure type, Tmin tmax, Unit cell.
Teeft :
- Acta, Acta cryst, Alfa aesar, Bruker, Cation, Cell volume, Cryst, Crystal data, Data collection bruker apexii diffractometer absorption correction, Diffraction data, Dimer, Flahaut, Ibers, Ionic radii, Lanthanide, Mmol, Orthorhombic, Orthorhombic space group pnma, Pnma, Sadabs, Sheldrick, Structure type, Tmin tmax, Unit cell.

Abstract

The compounds BaLn2Se4 (Ln = rare‐earth metal = lanthanide = Er, Tm and Yb), namely barium di(erbium/thulium/ytterbium) tetraselenide, crystallize in the orthorhombic space group Pnma in the CaFe2O4 structure type. In this structure type, all atoms possess m symmetry. The Ln atoms are octahedrally coordinated by six Se atoms. A three‐dimensional channel structure is formed by the corner‐ and edge‐sharing of these LnSe6 octahedra. The Ba atoms are coordinated to eight Se atoms in a bicapped trigonal–prismatic arrangement, and they occupy the channels of the three‐dimensional framework.

Url:

https://api.istex.fr/document/1967F9CA6F704632547ECFE5589EA15B97508DB0/fulltext/pdf

DOI: 10.1107/S0108270109030571

Affiliations:

Le document en format XML

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<front><div type="abstract" xml:lang="en">The compounds BaLn2Se4 (Ln = rare‐earth metal = lanthanide = Er, Tm and Yb), namely barium di(erbium/thulium/ytterbium) tetraselenide, crystallize in the orthorhombic space group Pnma in the CaFe2O4 structure type. In this structure type, all atoms possess m symmetry. The Ln atoms are octahedrally coordinated by six Se atoms. A three‐dimensional channel structure is formed by the corner‐ and edge‐sharing of these LnSe6 octahedra. The Ba atoms are coordinated to eight Se atoms in a bicapped trigonal–prismatic arrangement, and they occupy the channels of the three‐dimensional framework.</div>
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BaLn2Se4 (Ln = Er, Tm and Yb)

BaLn2Se4 (Ln = Er, Tm and Yb)

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

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