Role of PbO substitution by Bi2O3 on 1.47 μm luminescence properties of Tm3+/Tb3+-doped Bi2O3-GeO2-Ga2O3 glass
Identifieur interne : 000E07 ( Main/Exploration ); précédent : 000E06; suivant : 000E08Role of PbO substitution by Bi2O3 on 1.47 μm luminescence properties of Tm3+/Tb3+-doped Bi2O3-GeO2-Ga2O3 glass
Auteurs : D. M. Shi [République populaire de Chine] ; Y. G. Zhao [République populaire de Chine] ; Q. Qian [République populaire de Chine] ; D. D. Chen [République populaire de Chine] ; Q. Y. Zhang [République populaire de Chine]Source :
- Journal of alloys and compounds [ 0925-8388 ] ; 2010.
Descripteurs français
- Pascal (Inist)
- Wicri :
English descriptors
- KwdEn :
Abstract
Spectroscopic properties and energy transfer (ET) in Bi2O3(PbO)-GeO2-Ga2O3 (BPGG) glass doped with Tm3+ and/orTb3+ have been investigated. It is noted that the Tm3+ single-doped BPGG glass exhibits broad 1.47-μm fluorescence peaked at 1465 nm with a full width at half-maximum (FWHM) of ∼134 nm. The incorporation of Tb3+ into Tm3+-doped BPGG glass could significantly decrease the 1.80 μm emission intensity and enhance the intensity ratio of 1.47-μm to 1.80-μm (I1.47/I1.80), which reveals that Tb3+ ion can be considered to be an effective sensitizer ion on improving the 1.47-μm emission. The products of FWHM x σpeake and τf x σpeake for the 1.47-μm fluorescence are in the range of 5.66-6.63 x 10-26 cm3 and 8.76-10.02 - 10-25 cm2 s. Effects of Bi2O3 substitution for PbO on spectroscopic properties, such as 1.47-μm emission of Tm3+, Judd-Ofelt intensity parameters Ωt (t = 2, 4, 6), and the lifetime of the 3H4 level of Tm3+, have also been investigated.
Affiliations:
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Le document en format XML
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O<sub>3</sub>
on 1.47 μm luminescence properties of Tm<sup>3+</sup>
/Tb<sup>3+</sup>
-doped Bi<sub>2</sub>
O<sub>3</sub>
-GeO<sub>2</sub>
-Ga<sub>2</sub>
O<sub>3</sub>
glass</title>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Role of PbO substitution by Bi<sub>2</sub>
O<sub>3</sub>
on 1.47 μm luminescence properties of Tm<sup>3+</sup>
/Tb<sup>3+</sup>
-doped Bi<sub>2</sub>
O<sub>3</sub>
-GeO<sub>2</sub>
-Ga<sub>2</sub>
O<sub>3</sub>
glass</title>
<author><name sortKey="Shi, D M" sort="Shi, D M" uniqKey="Shi D" first="D. M." last="Shi">D. M. Shi</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>MOE Key Lab of Specially Functional Materials and Institute of Optical Communication Materials, South China University of Technology</s1>
<s2>Guangzhou 510641</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<placeName><settlement type="city">Jiangmen</settlement>
<region type="province">Guangdong</region>
</placeName>
</affiliation>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Department of Materials Science and Engineering, Luoyang Institute of Science and Technology</s1>
<s2>Luoyang 471023</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<wicri:noRegion>Luoyang 471023</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Zhao, Y G" sort="Zhao, Y G" uniqKey="Zhao Y" first="Y. G." last="Zhao">Y. G. Zhao</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Department of Materials Science and Engineering, Luoyang Institute of Science and Technology</s1>
<s2>Luoyang 471023</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<wicri:noRegion>Luoyang 471023</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Qian, Q" sort="Qian, Q" uniqKey="Qian Q" first="Q." last="Qian">Q. Qian</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>MOE Key Lab of Specially Functional Materials and Institute of Optical Communication Materials, South China University of Technology</s1>
<s2>Guangzhou 510641</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
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<placeName><settlement type="city">Jiangmen</settlement>
<region type="province">Guangdong</region>
</placeName>
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<author><name sortKey="Chen, D D" sort="Chen, D D" uniqKey="Chen D" first="D. D." last="Chen">D. D. Chen</name>
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<s2>Luoyang 471023</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
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<author><name sortKey="Zhang, Q Y" sort="Zhang, Q Y" uniqKey="Zhang Q" first="Q. Y." last="Zhang">Q. Y. Zhang</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>MOE Key Lab of Specially Functional Materials and Institute of Optical Communication Materials, South China University of Technology</s1>
<s2>Guangzhou 510641</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
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<placeName><settlement type="city">Jiangmen</settlement>
<region type="province">Guangdong</region>
</placeName>
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</analytic>
<series><title level="j" type="main">Journal of alloys and compounds</title>
<title level="j" type="abbreviated">J. alloys compd.</title>
<idno type="ISSN">0925-8388</idno>
<imprint><date when="2010">2010</date>
</imprint>
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<seriesStmt><title level="j" type="main">Journal of alloys and compounds</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Bismuth oxide</term>
<term>Chemical composition</term>
<term>Doping</term>
<term>Energy transfer</term>
<term>Fluorescence</term>
<term>Gallium oxide</term>
<term>Germanium oxide</term>
<term>Glass</term>
<term>Impurities</term>
<term>Judd-Ofelt theory</term>
<term>Lead oxide</term>
<term>Lifetime</term>
<term>Photoluminescence</term>
<term>Quaternary systems</term>
<term>Terbium additions</term>
<term>Thulium additions</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Photoluminescence</term>
<term>Dopage</term>
<term>Transfert énergie</term>
<term>Fluorescence</term>
<term>Théorie Judd Ofelt</term>
<term>Durée vie</term>
<term>Composition chimique</term>
<term>Impureté</term>
<term>Addition terbium</term>
<term>Système quaternaire</term>
<term>Addition thulium</term>
<term>Oxyde de plomb</term>
<term>Oxyde de bismuth</term>
<term>Oxyde de germanium</term>
<term>Oxyde de gallium</term>
<term>Verre</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Dopage</term>
<term>Verre</term>
</keywords>
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<front><div type="abstract" xml:lang="en">Spectroscopic properties and energy transfer (ET) in Bi<sub>2</sub>
O<sub>3</sub>
(PbO)-GeO<sub>2</sub>
-Ga<sub>2</sub>
O<sub>3</sub>
(BPGG) glass doped with Tm<sup>3+</sup>
and/orTb<sup>3+</sup>
have been investigated. It is noted that the Tm<sup>3+</sup>
single-doped BPGG glass exhibits broad 1.47-μm fluorescence peaked at 1465 nm with a full width at half-maximum (FWHM) of ∼134 nm. The incorporation of Tb<sup>3+</sup>
into Tm<sup>3+</sup>
-doped BPGG glass could significantly decrease the 1.80 μm emission intensity and enhance the intensity ratio of 1.47-μm to 1.80-μm (I<sub>1.47</sub>
/I<sub>1.80</sub>
), which reveals that Tb<sup>3+</sup>
ion can be considered to be an effective sensitizer ion on improving the 1.47-μm emission. The products of FWHM x σ<sup>peak</sup>
<sub>e</sub>
and τ<sub>f</sub>
x σ<sup>peak</sup>
<sub>e</sub>
for the 1.47-μm fluorescence are in the range of 5.66-6.63 x 10<sup>-26</sup>
cm<sup>3</sup>
and 8.76-10.02 - 10<sup>-25</sup>
cm<sup>2</sup>
s. Effects of Bi<sub>2</sub>
O<sub>3</sub>
substitution for PbO on spectroscopic properties, such as 1.47-μm emission of Tm<sup>3+</sup>
, Judd-Ofelt intensity parameters Ω<sub>t</sub>
(t = 2, 4, 6), and the lifetime of the <sup>3</sup>
H<sub>4</sub>
level of Tm<sup>3+</sup>
, have also been investigated.</div>
</front>
</TEI>
<affiliations><list><country><li>République populaire de Chine</li>
</country>
<region><li>Guangdong</li>
</region>
<settlement><li>Jiangmen</li>
</settlement>
</list>
<tree><country name="République populaire de Chine"><region name="Guangdong"><name sortKey="Shi, D M" sort="Shi, D M" uniqKey="Shi D" first="D. M." last="Shi">D. M. Shi</name>
</region>
<name sortKey="Chen, D D" sort="Chen, D D" uniqKey="Chen D" first="D. D." last="Chen">D. D. Chen</name>
<name sortKey="Qian, Q" sort="Qian, Q" uniqKey="Qian Q" first="Q." last="Qian">Q. Qian</name>
<name sortKey="Shi, D M" sort="Shi, D M" uniqKey="Shi D" first="D. M." last="Shi">D. M. Shi</name>
<name sortKey="Zhang, Q Y" sort="Zhang, Q Y" uniqKey="Zhang Q" first="Q. Y." last="Zhang">Q. Y. Zhang</name>
<name sortKey="Zhao, Y G" sort="Zhao, Y G" uniqKey="Zhao Y" first="Y. G." last="Zhao">Y. G. Zhao</name>
</country>
</tree>
</affiliations>
</record>
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