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Role of PbO substitution by Bi2O3 on 1.47 μm luminescence properties of Tm3+/Tb3+-doped Bi2O3-GeO2-Ga2O3 glass

Identifieur interne : 000E07 ( Main/Exploration ); précédent : 000E06; suivant : 000E08

Role of PbO substitution by Bi2O3 on 1.47 μm luminescence properties of Tm3+/Tb3+-doped Bi2O3-GeO2-Ga2O3 glass

Auteurs : D. M. Shi [République populaire de Chine] ; Y. G. Zhao [République populaire de Chine] ; Q. Qian [République populaire de Chine] ; D. D. Chen [République populaire de Chine] ; Q. Y. Zhang [République populaire de Chine]

Source :

RBID : Pascal:10-0282132

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English descriptors

Abstract

Spectroscopic properties and energy transfer (ET) in Bi2O3(PbO)-GeO2-Ga2O3 (BPGG) glass doped with Tm3+ and/orTb3+ have been investigated. It is noted that the Tm3+ single-doped BPGG glass exhibits broad 1.47-μm fluorescence peaked at 1465 nm with a full width at half-maximum (FWHM) of ∼134 nm. The incorporation of Tb3+ into Tm3+-doped BPGG glass could significantly decrease the 1.80 μm emission intensity and enhance the intensity ratio of 1.47-μm to 1.80-μm (I1.47/I1.80), which reveals that Tb3+ ion can be considered to be an effective sensitizer ion on improving the 1.47-μm emission. The products of FWHM x σpeake and τf x σpeake for the 1.47-μm fluorescence are in the range of 5.66-6.63 x 10-26 cm3 and 8.76-10.02 - 10-25 cm2 s. Effects of Bi2O3 substitution for PbO on spectroscopic properties, such as 1.47-μm emission of Tm3+, Judd-Ofelt intensity parameters Ωt (t = 2, 4, 6), and the lifetime of the 3H4 level of Tm3+, have also been investigated.


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Le document en format XML

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<title xml:lang="en" level="a">Role of PbO substitution by Bi
<sub>2</sub>
O
<sub>3</sub>
on 1.47 μm luminescence properties of Tm
<sup>3+</sup>
/Tb
<sup>3+</sup>
-doped Bi
<sub>2</sub>
O
<sub>3</sub>
-GeO
<sub>2</sub>
-Ga
<sub>2</sub>
O
<sub>3</sub>
glass</title>
<author>
<name sortKey="Shi, D M" sort="Shi, D M" uniqKey="Shi D" first="D. M." last="Shi">D. M. Shi</name>
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<s1>MOE Key Lab of Specially Functional Materials and Institute of Optical Communication Materials, South China University of Technology</s1>
<s2>Guangzhou 510641</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
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<country>République populaire de Chine</country>
<placeName>
<settlement type="city">Jiangmen</settlement>
<region type="province">Guangdong</region>
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<s1>Department of Materials Science and Engineering, Luoyang Institute of Science and Technology</s1>
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<name sortKey="Zhao, Y G" sort="Zhao, Y G" uniqKey="Zhao Y" first="Y. G." last="Zhao">Y. G. Zhao</name>
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<region type="province">Guangdong</region>
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<idno type="wicri:source">INIST</idno>
<idno type="inist">10-0282132</idno>
<date when="2010">2010</date>
<idno type="stanalyst">PASCAL 10-0282132 INIST</idno>
<idno type="RBID">Pascal:10-0282132</idno>
<idno type="wicri:Area/Pascal/Corpus">000364</idno>
<idno type="wicri:Area/Pascal/Curation">000364</idno>
<idno type="wicri:Area/Pascal/Checkpoint">000305</idno>
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<sourceDesc>
<biblStruct>
<analytic>
<title xml:lang="en" level="a">Role of PbO substitution by Bi
<sub>2</sub>
O
<sub>3</sub>
on 1.47 μm luminescence properties of Tm
<sup>3+</sup>
/Tb
<sup>3+</sup>
-doped Bi
<sub>2</sub>
O
<sub>3</sub>
-GeO
<sub>2</sub>
-Ga
<sub>2</sub>
O
<sub>3</sub>
glass</title>
<author>
<name sortKey="Shi, D M" sort="Shi, D M" uniqKey="Shi D" first="D. M." last="Shi">D. M. Shi</name>
<affiliation wicri:level="1">
<inist:fA14 i1="01">
<s1>MOE Key Lab of Specially Functional Materials and Institute of Optical Communication Materials, South China University of Technology</s1>
<s2>Guangzhou 510641</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<placeName>
<settlement type="city">Jiangmen</settlement>
<region type="province">Guangdong</region>
</placeName>
</affiliation>
<affiliation wicri:level="1">
<inist:fA14 i1="02">
<s1>Department of Materials Science and Engineering, Luoyang Institute of Science and Technology</s1>
<s2>Luoyang 471023</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<wicri:noRegion>Luoyang 471023</wicri:noRegion>
</affiliation>
</author>
<author>
<name sortKey="Zhao, Y G" sort="Zhao, Y G" uniqKey="Zhao Y" first="Y. G." last="Zhao">Y. G. Zhao</name>
<affiliation wicri:level="1">
<inist:fA14 i1="02">
<s1>Department of Materials Science and Engineering, Luoyang Institute of Science and Technology</s1>
<s2>Luoyang 471023</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<wicri:noRegion>Luoyang 471023</wicri:noRegion>
</affiliation>
</author>
<author>
<name sortKey="Qian, Q" sort="Qian, Q" uniqKey="Qian Q" first="Q." last="Qian">Q. Qian</name>
<affiliation wicri:level="1">
<inist:fA14 i1="01">
<s1>MOE Key Lab of Specially Functional Materials and Institute of Optical Communication Materials, South China University of Technology</s1>
<s2>Guangzhou 510641</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<placeName>
<settlement type="city">Jiangmen</settlement>
<region type="province">Guangdong</region>
</placeName>
</affiliation>
</author>
<author>
<name sortKey="Chen, D D" sort="Chen, D D" uniqKey="Chen D" first="D. D." last="Chen">D. D. Chen</name>
<affiliation wicri:level="1">
<inist:fA14 i1="02">
<s1>Department of Materials Science and Engineering, Luoyang Institute of Science and Technology</s1>
<s2>Luoyang 471023</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<wicri:noRegion>Luoyang 471023</wicri:noRegion>
</affiliation>
</author>
<author>
<name sortKey="Zhang, Q Y" sort="Zhang, Q Y" uniqKey="Zhang Q" first="Q. Y." last="Zhang">Q. Y. Zhang</name>
<affiliation wicri:level="1">
<inist:fA14 i1="01">
<s1>MOE Key Lab of Specially Functional Materials and Institute of Optical Communication Materials, South China University of Technology</s1>
<s2>Guangzhou 510641</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<placeName>
<settlement type="city">Jiangmen</settlement>
<region type="province">Guangdong</region>
</placeName>
</affiliation>
</author>
</analytic>
<series>
<title level="j" type="main">Journal of alloys and compounds</title>
<title level="j" type="abbreviated">J. alloys compd.</title>
<idno type="ISSN">0925-8388</idno>
<imprint>
<date when="2010">2010</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt>
<title level="j" type="main">Journal of alloys and compounds</title>
<title level="j" type="abbreviated">J. alloys compd.</title>
<idno type="ISSN">0925-8388</idno>
</seriesStmt>
</fileDesc>
<profileDesc>
<textClass>
<keywords scheme="KwdEn" xml:lang="en">
<term>Bismuth oxide</term>
<term>Chemical composition</term>
<term>Doping</term>
<term>Energy transfer</term>
<term>Fluorescence</term>
<term>Gallium oxide</term>
<term>Germanium oxide</term>
<term>Glass</term>
<term>Impurities</term>
<term>Judd-Ofelt theory</term>
<term>Lead oxide</term>
<term>Lifetime</term>
<term>Photoluminescence</term>
<term>Quaternary systems</term>
<term>Terbium additions</term>
<term>Thulium additions</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Photoluminescence</term>
<term>Dopage</term>
<term>Transfert énergie</term>
<term>Fluorescence</term>
<term>Théorie Judd Ofelt</term>
<term>Durée vie</term>
<term>Composition chimique</term>
<term>Impureté</term>
<term>Addition terbium</term>
<term>Système quaternaire</term>
<term>Addition thulium</term>
<term>Oxyde de plomb</term>
<term>Oxyde de bismuth</term>
<term>Oxyde de germanium</term>
<term>Oxyde de gallium</term>
<term>Verre</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr">
<term>Dopage</term>
<term>Verre</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front>
<div type="abstract" xml:lang="en">Spectroscopic properties and energy transfer (ET) in Bi
<sub>2</sub>
O
<sub>3</sub>
(PbO)-GeO
<sub>2</sub>
-Ga
<sub>2</sub>
O
<sub>3</sub>
(BPGG) glass doped with Tm
<sup>3+</sup>
and/orTb
<sup>3+</sup>
have been investigated. It is noted that the Tm
<sup>3+</sup>
single-doped BPGG glass exhibits broad 1.47-μm fluorescence peaked at 1465 nm with a full width at half-maximum (FWHM) of ∼134 nm. The incorporation of Tb
<sup>3+</sup>
into Tm
<sup>3+</sup>
-doped BPGG glass could significantly decrease the 1.80 μm emission intensity and enhance the intensity ratio of 1.47-μm to 1.80-μm (I
<sub>1.47</sub>
/I
<sub>1.80</sub>
), which reveals that Tb
<sup>3+</sup>
ion can be considered to be an effective sensitizer ion on improving the 1.47-μm emission. The products of FWHM x σ
<sup>peak</sup>
<sub>e</sub>
and τ
<sub>f</sub>
x σ
<sup>peak</sup>
<sub>e</sub>
for the 1.47-μm fluorescence are in the range of 5.66-6.63 x 10
<sup>-26</sup>
cm
<sup>3</sup>
and 8.76-10.02 - 10
<sup>-25</sup>
cm
<sup>2</sup>
s. Effects of Bi
<sub>2</sub>
O
<sub>3</sub>
substitution for PbO on spectroscopic properties, such as 1.47-μm emission of Tm
<sup>3+</sup>
, Judd-Ofelt intensity parameters Ω
<sub>t</sub>
(t = 2, 4, 6), and the lifetime of the
<sup>3</sup>
H
<sub>4</sub>
level of Tm
<sup>3+</sup>
, have also been investigated.</div>
</front>
</TEI>
<affiliations>
<list>
<country>
<li>République populaire de Chine</li>
</country>
<region>
<li>Guangdong</li>
</region>
<settlement>
<li>Jiangmen</li>
</settlement>
</list>
<tree>
<country name="République populaire de Chine">
<region name="Guangdong">
<name sortKey="Shi, D M" sort="Shi, D M" uniqKey="Shi D" first="D. M." last="Shi">D. M. Shi</name>
</region>
<name sortKey="Chen, D D" sort="Chen, D D" uniqKey="Chen D" first="D. D." last="Chen">D. D. Chen</name>
<name sortKey="Qian, Q" sort="Qian, Q" uniqKey="Qian Q" first="Q." last="Qian">Q. Qian</name>
<name sortKey="Shi, D M" sort="Shi, D M" uniqKey="Shi D" first="D. M." last="Shi">D. M. Shi</name>
<name sortKey="Zhang, Q Y" sort="Zhang, Q Y" uniqKey="Zhang Q" first="Q. Y." last="Zhang">Q. Y. Zhang</name>
<name sortKey="Zhao, Y G" sort="Zhao, Y G" uniqKey="Zhao Y" first="Y. G." last="Zhao">Y. G. Zhao</name>
</country>
</tree>
</affiliations>
</record>

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