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2.7 μm Emission from Transparent Er3+,Tm3+ Codoped Yttrium Aluminum Garnet (Y3Al5O12) Nanocrystals-Tellurate Glass Composites by Novel Comelting Technology

Identifieur interne : 000928 ( Main/Exploration ); précédent : 000927; suivant : 000929

2.7 μm Emission from Transparent Er3+,Tm3+ Codoped Yttrium Aluminum Garnet (Y3Al5O12) Nanocrystals-Tellurate Glass Composites by Novel Comelting Technology

Auteurs : GUANQI CHAI [République populaire de Chine] ; GUOPING DONG [République populaire de Chine] ; JIANRONG QIU [République populaire de Chine] ; QINYUAN ZHANG [République populaire de Chine] ; ZHONGMIN YANG [République populaire de Chine]

Source :

RBID : Pascal:12-0404437

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English descriptors

Abstract

Yttrium aluminum garnet Y3Al5O12 (YA-G):Er3+,Tm3+ phosphor powders with preferable luminescent properties and nanocrystals with better morphology were synthesized by the solid-state reaction method and coprecipitation method, respectively. The composition and morphology were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM), which showed that the nanocrystals were pseudomonodispersed with the particle size of ∼30 nm. Photoluminescence (PL) spectra indicated the 2.7 μm emission of Er3+ was remarkably enhanced via Tm3+ sensitization, and a novel circulatory energy transfer mechanism was proposed. A novel dehydration method was used to decrease the contents of the hydroxyl group (OH-) confirmed by photoluminescence spectra and Fourier transform infrared spectra (FTIR). YAG crystallites were introduced into tellurate glass and formed to glass composites with good optical performance. These nanocrystals-glass composites open a brand new field for the research of mid-infrared laser materials.


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Le document en format XML

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<sup>3+</sup>
,Tm
<sup>3+</sup>
Codoped Yttrium Aluminum Garnet (Y
<sub>3</sub>
Al
<sub>5</sub>
O
<sub>12</sub>
) Nanocrystals-Tellurate Glass Composites by Novel Comelting Technology</title>
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<title xml:lang="en" level="a">2.7 μm Emission from Transparent Er
<sup>3+</sup>
,Tm
<sup>3+</sup>
Codoped Yttrium Aluminum Garnet (Y
<sub>3</sub>
Al
<sub>5</sub>
O
<sub>12</sub>
) Nanocrystals-Tellurate Glass Composites by Novel Comelting Technology</title>
<author>
<name sortKey="Guanqi Chai" sort="Guanqi Chai" uniqKey="Guanqi Chai" last="Guanqi Chai">GUANQI CHAI</name>
<affiliation wicri:level="1">
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<s1>State Key Laboratory of Luminescent Materials and Devices, and Institute of Optical Communication Materials, South China University of Technology</s1>
<s2>Guangzhou 510641</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
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<country>République populaire de Chine</country>
<placeName>
<settlement type="city">Jiangmen</settlement>
<region type="province">Guangdong</region>
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<author>
<name sortKey="Guoping Dong" sort="Guoping Dong" uniqKey="Guoping Dong" last="Guoping Dong">GUOPING DONG</name>
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<country>République populaire de Chine</country>
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<region type="province">Guangdong</region>
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<name sortKey="Jianrong Qiu" sort="Jianrong Qiu" uniqKey="Jianrong Qiu" last="Jianrong Qiu">JIANRONG QIU</name>
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<name sortKey="Qinyuan Zhang" sort="Qinyuan Zhang" uniqKey="Qinyuan Zhang" last="Qinyuan Zhang">QINYUAN ZHANG</name>
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<name sortKey="Zhongmin Yang" sort="Zhongmin Yang" uniqKey="Zhongmin Yang" last="Zhongmin Yang">ZHONGMIN YANG</name>
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<inist:fA14 i1="01">
<s1>State Key Laboratory of Luminescent Materials and Devices, and Institute of Optical Communication Materials, South China University of Technology</s1>
<s2>Guangzhou 510641</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<keywords scheme="KwdEn" xml:lang="en">
<term>Codoping</term>
<term>Composite materials</term>
<term>Coprecipitation</term>
<term>Energy transfer</term>
<term>Energy-level transitions</term>
<term>Erbium additions</term>
<term>Fourier-transformed infrared spectrometry</term>
<term>Frequency conversion</term>
<term>Glass</term>
<term>Impurity states</term>
<term>Laser materials</term>
<term>Microstructure</term>
<term>Nanocomposites</term>
<term>Nanocrystal</term>
<term>Particle size</term>
<term>Photoluminescence</term>
<term>Tellurates</term>
<term>Thulium additions</term>
<term>YAG</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Codopage</term>
<term>Spectrométrie FTIR</term>
<term>Microstructure</term>
<term>Addition erbium</term>
<term>Coprécipitation</term>
<term>Addition thulium</term>
<term>Transition niveau énergie</term>
<term>Etat impureté</term>
<term>Dimension particule</term>
<term>Photoluminescence</term>
<term>Transfert énergie</term>
<term>Conversion fréquence</term>
<term>Grenat aluminium yttrium</term>
<term>Nanocristal</term>
<term>Tellurate</term>
<term>Verre</term>
<term>Matériau composite</term>
<term>Nanocomposite</term>
<term>Matériau laser</term>
<term>Y3Al5O12</term>
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<term>Verre</term>
<term>Matériau composite</term>
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<front>
<div type="abstract" xml:lang="en">Yttrium aluminum garnet Y
<sub>3</sub>
Al
<sub>5</sub>
O
<sub>12</sub>
(YA-G):Er
<sup>3+</sup>
,Tm
<sup>3+</sup>
phosphor powders with preferable luminescent properties and nanocrystals with better morphology were synthesized by the solid-state reaction method and coprecipitation method, respectively. The composition and morphology were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM), which showed that the nanocrystals were pseudomonodispersed with the particle size of ∼30 nm. Photoluminescence (PL) spectra indicated the 2.7 μm emission of Er
<sup>3+</sup>
was remarkably enhanced via Tm
<sup>3+</sup>
sensitization, and a novel circulatory energy transfer mechanism was proposed. A novel dehydration method was used to decrease the contents of the hydroxyl group (OH
<sup>-</sup>
) confirmed by photoluminescence spectra and Fourier transform infrared spectra (FTIR). YAG crystallites were introduced into tellurate glass and formed to glass composites with good optical performance. These nanocrystals-glass composites open a brand new field for the research of mid-infrared laser materials.</div>
</front>
</TEI>
<affiliations>
<list>
<country>
<li>République populaire de Chine</li>
</country>
<region>
<li>Guangdong</li>
</region>
<settlement>
<li>Jiangmen</li>
</settlement>
</list>
<tree>
<country name="République populaire de Chine">
<region name="Guangdong">
<name sortKey="Guanqi Chai" sort="Guanqi Chai" uniqKey="Guanqi Chai" last="Guanqi Chai">GUANQI CHAI</name>
</region>
<name sortKey="Guoping Dong" sort="Guoping Dong" uniqKey="Guoping Dong" last="Guoping Dong">GUOPING DONG</name>
<name sortKey="Jianrong Qiu" sort="Jianrong Qiu" uniqKey="Jianrong Qiu" last="Jianrong Qiu">JIANRONG QIU</name>
<name sortKey="Qinyuan Zhang" sort="Qinyuan Zhang" uniqKey="Qinyuan Zhang" last="Qinyuan Zhang">QINYUAN ZHANG</name>
<name sortKey="Zhongmin Yang" sort="Zhongmin Yang" uniqKey="Zhongmin Yang" last="Zhongmin Yang">ZHONGMIN YANG</name>
</country>
</tree>
</affiliations>
</record>

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