Triethylene glycol complexes of the early lanthanide(III) chlorides
Identifieur interne : 003740 ( Main/Curation ); précédent : 003739; suivant : 003741Triethylene glycol complexes of the early lanthanide(III) chlorides
Auteurs : R. D. Rogers [États-Unis] ; R. D. Etzenhouser ; J. S. MurdochSource :
- Inorganica chimica acta [ 0020-1693 ] ; 1992.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
The completation of triethylene glycol (EON) with the earlier lanthanide(III) chlorides has been investigated in 1/1 and 10/1 stoichiometries and with the addition of LiCl. Two well resolved crystalline forms of La3+ and Ce3+ have been isolated and structurally characterized: (MCl(OH2)(EO3)2]Cl2 and [MCl2(OH2)2(EO3)]2Cl2 (M=La, Ce).
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Pascal:92-0581709Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Triethylene glycol complexes of the early lanthanide(III) chlorides</title>
<author><name sortKey="Rogers, R D" sort="Rogers, R D" uniqKey="Rogers R" first="R. D." last="Rogers">R. D. Rogers</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Northern Illinois univ., dep. chemistry</s1>
<s2>DeKalb IL 60115</s2>
<s3>USA</s3>
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<country>États-Unis</country>
<wicri:noRegion>DeKalb IL 60115</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Etzenhouser, R D" sort="Etzenhouser, R D" uniqKey="Etzenhouser R" first="R. D." last="Etzenhouser">R. D. Etzenhouser</name>
</author>
<author><name sortKey="Murdoch, J S" sort="Murdoch, J S" uniqKey="Murdoch J" first="J. S." last="Murdoch">J. S. Murdoch</name>
</author>
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<publicationStmt><idno type="wicri:source">INIST</idno>
<idno type="inist">92-0581709</idno>
<date when="1992">1992</date>
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<idno type="wicri:doubleKey">0020-1693:1992:Rogers R:triethylene:glycol:complexes</idno>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Triethylene glycol complexes of the early lanthanide(III) chlorides</title>
<author><name sortKey="Rogers, R D" sort="Rogers, R D" uniqKey="Rogers R" first="R. D." last="Rogers">R. D. Rogers</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Northern Illinois univ., dep. chemistry</s1>
<s2>DeKalb IL 60115</s2>
<s3>USA</s3>
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<country>États-Unis</country>
<wicri:noRegion>DeKalb IL 60115</wicri:noRegion>
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<author><name sortKey="Etzenhouser, R D" sort="Etzenhouser, R D" uniqKey="Etzenhouser R" first="R. D." last="Etzenhouser">R. D. Etzenhouser</name>
</author>
<author><name sortKey="Murdoch, J S" sort="Murdoch, J S" uniqKey="Murdoch J" first="J. S." last="Murdoch">J. S. Murdoch</name>
</author>
</analytic>
<series><title level="j" type="main">Inorganica chimica acta</title>
<title level="j" type="abbreviated">Inorg. chim. acta</title>
<idno type="ISSN">0020-1693</idno>
<imprint><date when="1992">1992</date>
</imprint>
</series>
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<seriesStmt><title level="j" type="main">Inorganica chimica acta</title>
<title level="j" type="abbreviated">Inorg. chim. acta</title>
<idno type="ISSN">0020-1693</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Addition reaction</term>
<term>Cationic complex</term>
<term>Cerium III Complexes</term>
<term>Crystalline structure</term>
<term>Experimental study</term>
<term>Glycol</term>
<term>Hydroxo complex</term>
<term>Lanthanum III Complexes</term>
<term>Molecular structure</term>
<term>Organic ligand</term>
<term>Thulium III Complexes</term>
<term>X ray diffraction</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Coordinat organique</term>
<term>Glycol</term>
<term>Addition chimique</term>
<term>Complexe cationique</term>
<term>Complexe hydroxo</term>
<term>Lanthane III Complexe</term>
<term>Cérium III Complexe</term>
<term>Thulium III Complexe</term>
<term>Triéhtylèneglycol</term>
<term>Structure cristalline</term>
<term>Diffraction RX</term>
<term>Etude expérimentale</term>
<term>Structure moléculaire</term>
</keywords>
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<front><div type="abstract" xml:lang="en">The completation of triethylene glycol (EON) with the earlier lanthanide(III) chlorides has been investigated in 1/1 and 10/1 stoichiometries and with the addition of LiCl. Two well resolved crystalline forms of La<sup>3+</sup>
and Ce<sup>3+</sup>
have been isolated and structurally characterized: (MCl(OH<sub>2</sub>
)(EO3)<sub>2</sub>
]Cl<sub>2</sub>
and [MCl<sub>2</sub>
(OH<sub>2</sub>
)<sub>2</sub>
(EO3)]<sub>2</sub>
Cl<sub>2</sub>
(M=La, Ce).</div>
</front>
</TEI>
</record>
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